1. Growth manipulation in electrodeposition of compact and mesoporous electron transport layers for enhanced efficiency and stability in carbon-based perovskite solar cellsTecush Mohammadi, Dimitris A. Chalkias, Nigel Willy Van de Velde, Andrej Race, Elias Stathatos, Boštjan Genorio, Blaž Likozar, Ivan Jerman, 2025, izvirni znanstveni članek Ključne besede: perovskite solar cell, electron transport layer, TiO2 electrodeposition, compact layer, mesoporous layer, photovoltaic performance
Objavljeno v DiRROS: 03.03.2025; Ogledov: 50; Prenosov: 35
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2. Practical insights and advances in concrete pumpingDaniil Mikhalev, Ana Brunčič, 2024, izvirni znanstveni članek Povzetek: This technical letter gives a concise overview of the state-of-the-art in concrete pumping. It outlines the different pump systems, briefly describes the general flow behavior of concrete in pipes, and addresses the main challenges of pumping. It also elaborates upon factors influencing the pumping behavior and how to control the pumping process.
Ključne besede: rheology, quality control, pressure, concrete, pumping, lubrication layer
Objavljeno v DiRROS: 18.02.2025; Ogledov: 120; Prenosov: 52
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4. Predicting the effective char depth in timber elements exposed to natural fires, including the cooling phaseAndrea Lucherini, Daniela Šejnová Pitelková, Vladimír Mózer, 2023, objavljeni znanstveni prispevek na konferenci Povzetek: This paper presents a numerical study on the effect of the heating and cooling phases on the reduction of the effective cross-section of timber elements, in particular on the evolution of the char depth (300°C isotherm) and zero- strength layer. An advanced calculation method based a finite-difference heat transfer model is compared to the simplified approach suggested by Eurocode 5. For the heating phase, defined as the standard fire curve (ISO 834), the simplified Eurocode 5 method generally provides more conservative char depths, while the zero-strength layer is under-predicted. Nevertheless, the values of effective char depth are comparable. Including the cooling phase evidences that, during this phase, the heat wave penetration leads to a significant increase in the char depth and zero-strength layer. Particularly, this increase directly depends on the fire cooling rate: a slower cooling phase further reduces the effective cross-section of timber members. As a result, this research highlights how the heat wave penetration during the fire cooling phase can significantly reduce the load-bearing capacity of timber elements.
Ključne besede: timber structures, fire safety, heat transfer, charring, zero-strength layer, cooling
Objavljeno v DiRROS: 14.01.2025; Ogledov: 136; Prenosov: 87
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5. Estimating the effective char depth in structural timber elements exposed to natural fires, considering the heating and cooling phaseAndrea Lucherini, Daniela Šejnová Pitelková, Vladimír Mózer, 2025, izvirni znanstveni članek Povzetek: This research study investigates the effect of different heating and cooling regimes on the effective cross-section of timber elements exposed to natural fires. An advanced calculation method based on a 1D finite-difference heat transfer model and effective thermo-physical properties is adopted to analyse the heat penetration and the consequent reduction in mechanical properties. In particular, the research focuses on the evolution and penetration speed of the char depth (300 ◦C isotherm) and zero-strength layer (determined through in-depth temperatures and reduced mechanical properties). Results reveal how the char depth mainly develops during the heating phase, with non-negligible contributions from the cooling phase. In contrast, the zero-strength layer increases throughout the whole fire exposure, particularly during cooling and, possibly, after the end of the cooling phase. In general, the heating phase contributes about 2/3 to the total effective char depth, while the cooling phase about 1/3. The most challenging conditions were found for the fires of the longest durations (heating and overall), corresponding to low ventilation and high fuel load density conditions. The study emphasises the necessity of incorporating the cooling phase in performance-based methodologies for fire-safe timber structures to avoid under-estimating heat penetration effects.
Ključne besede: timber structures, fire safety, charring, zero-strength layer, natural fire, heating, cooling, structural fire engineering, performance-based design
Objavljeno v DiRROS: 22.11.2024; Ogledov: 242; Prenosov: 470
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6. Three decades of understorey vegetation change in Quercus-dominated forests as a result of increasing canopy mortality and global change symptomsJanez Kermavnar, Lado Kutnar, 2024, izvirni znanstveni članek Povzetek: Questions The long-term response of understorey vegetation to increasing tree mortality has rarely been addressed in resurvey studies. For two Quercus-dominated forest types, we asked: (a) How did overstorey alterations, induced by canopy mortality, affect understorey diversity and composition? (b) Is there a signal of global change effects on understorey communities? (c) Are these assemblages experiencing a homogenization process? Location Five sites in Quercus robur (QR) and four sites in Q. petraea (QP) forests, Slovenia. Methods We studied changes in vascular plants in the understorey layer from 1992/1993 to 2023 across 45 permanent 20 m × 20 m plots in QR and QP forests, respectively. Vegetation surveys were carried out following the standard Braun-Blanquet method. We compared original surveys with recent resurveys using multivariate analysis, ecological indicator values (EIV), plant traits and methods that quantify changes in individual species. Results Since the early 1990s, tree layer cover decreased from 95% to an average of 55% in QR, whereas it remained relatively high (77%) in QP plots. This resulted in denser understorey vegetation and a significant increase in plot-level species richness in QR forests, but a slight decrease in QP forests. The extensive loss of canopy cover and disturbance effects in QR forests caused significant changes in species composition. Species turnover in QR was driven by colonization of new disturbance-tolerant taxa characterized by ruderal traits, whereas the compositional shift in QP was to a greater extent due to species losses. We detected a process of vegetation thermophilization (increase in EIV-temperature), suggesting an effect of rapid climatic warming. Understorey communities are now more similar to each other than 30 years ago, indicating a decrease in beta-diversity (floristic homogenization). Conclusions Despite some common trends, vegetation responses were forest type-specific. Our study presents evidence of understorey vegetation changes triggered by increased canopy mortality (a strong local driver particularly in QR plots) and also points to the signal of global change symptoms (thermophilization, homogenization), which acted rather independently from the observed decline in tree layer cover.
Ključne besede: floristic homogenization, forest disturbances, permanent vegetation plots, Quercus robur, Quercus petraea, resurvey study, Slovenia, thermophilization, tree layer cover
Objavljeno v DiRROS: 11.11.2024; Ogledov: 259; Prenosov: 243
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7. Thin-layer boilover of large-scale diesel pool fires at sub-atmospheric pressureJinlong Zhao, Qingyuan Zhang, Zhenqi Hu, Rongxue Kang, Grunde Jomaas, Rui Yang, 2024, izvirni znanstveni članek Povzetek: As thin-layer burning of fuels on water are often followed by thin-layer boilover fires, particularly during the firefighting process, an experimental and numerical study was undertaken to address key aspects of such fires, especially in plateau areas (i.e., sub-atmospheric pressure). In the thin-layer boilover experiments at sub-atmospheric pressure (69 kPa), diesel was used as the fuel in five circular steel trays (ranging from 0.4 m to 1.2 m in diameter) and a square steel tray (side length of 2.5 m). The burning process, and especially the continuous boilover stage, was presented and the corresponding boilover intensity, time to boilover onset and boilover time interval were measured and analyzed. The results show that the flame height increased sharply at the initial boilover, while this increasing range gradually became weak for the subsequent boilovers. The initial boilover intensity showed a linear dependency on the fuel layer thickness at the time of boilover, and the slope of the boilover intensity line decreased with increasing pan area. Eventually, the effect of pan area on boilover intensity became limit. Moreover, a predictive model for the boilover intensity was established based on dimensionless analysis. The initial boilover onset time under the sub-atmospheric pressure was delayed compared with that under atmospheric pressure. The corresponding predictive correlation (for 69 kPa) with different diameter and fuel thickness was developed based on the one-dimension two-layer conduction model. In the end, the boilover time interval decreased with the boilover times, closing to uninterrupted boilover eventually. This work enriches the thin-layer boilover behavior experimental data at sub-atmospheric pressure and provides guidance for the fuel storage safety.
Ključne besede: thin-layer boilover, boilover intensity, time to boilover onset, boilover time interval, sub-atmospheric fires
Objavljeno v DiRROS: 16.01.2024; Ogledov: 798; Prenosov: 154
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8. Mechanistic study of fast performance decay of PtCu alloy-based catalyst layers for polymer electrolyte fuel cells through electrochemical impedance spectroscopyMaximilian Grandi, Matija Gatalo, Ana Rebeka Kamšek, Gregor Kapun, Kurt Mayer, Francisco Ruiz-Zepeda, Martin Šala, Bernhard Marius, Marjan Bele, Nejc Hodnik, Merit Bodner, Miran Gaberšček, Viktor Hacker, 2023, izvirni znanstveni članek Ključne besede: PEFC, catalyst layer, platinum–copper, degradation, ionomer, electrochemical impedance spectroscopy, membrane electrode assembly
Objavljeno v DiRROS: 23.06.2023; Ogledov: 998; Prenosov: 435
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9. Properties of the fluoroacrylate and methacryloxypropyl-trimethoxysilane applied to a layer of Cu2O on bronze as either single or multi-component coatingsLuka Škrlep, Tadeja Kosec, Matjaž Finšgar, Andrijana Sever Škapin, Erika Švara Fabjan, 2023, izvirni znanstveni članek Povzetek: Various coatings have been developed and explored to protect bronze surfaces against the uncontrolled formation of different corrosion products when exposed to outdoor environments.
In this research, the surfaces of artificially-formed oxidized bronze patinas (OB), consisting of Cu2O, were covered with either a single-component (fluoroacrylate, FA or methacryloxypropyl-trimethoxysilane, MS) or multi-component (a mixture of FA and MS, FA-MS) fluoropolymer coating and investigated. Variations in the concentration of each component in the coating were studied. Electrochemical tests were performed to determine the corrosion protection efficiency, followed by detailed surface analyses of the OBs, both uncoated and covered with single and multi-component coatings. A variety of investigative methods were used, including focused ion beam scanning electron microscopy (FIB-SEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and time-of-flight secondary ion mass spectrometry (ToF-SIMS).
The coating made from a combination of FA and MS resulted in a very high protection efficiency. Despite the increased hydrophilicity of the single MS component, however, it was shown to efficiently protect the oxidized bronze surface. The FA-MS systems showed high hydrophobicity, but no improvement was measured in the efficiency of the corrosion protection when it was compared to the coating that contained 10% MS. According to XPS and ToF-SIMS imaging, the FA component of the FA-MS coating was not present only on the uppermost surface of the coating but throughout the whole coating, which could affect its corrosion protection efficiency.
Ključne besede: bronze, Cu2O layer on bronze, fluoropolymer coating, protection efficiency, surface spectroscopy
Objavljeno v DiRROS: 30.05.2023; Ogledov: 983; Prenosov: 450
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