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1651 - 1660 / 2000
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1651.
Selective glucose oxidation to glucaric acid using bimetallic catalysts : lattice expansion or electronic structure effect?
Žan Lavrič, Janvit Teržan, Ana Kroflič, Janez Zavašnik, Joanna E. Olszówka, Štefan Vajda, Matej Huš, Miha Grilc, Blaž Likozar, 2024, original scientific article

Abstract: Our study presents a comprehensive approach for the selective oxidation of glucose to glucaric acid (GA) by heterogeneous catalysis. We have synthesized and characterized Au/ZrO2, AuCu/ZrO2 and AuPt/ZrO2 catalysts using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and oxygen pulse chemisorption (OPS) techniques. Combining experimental observations with in-depth density functional theory (DFT) studies, we found that bimetallic catalysts form alloys, which exhibit different characteristics than monometallic counterparts for the given reaction. We performed batch reactions, varying temperature and oxygen pressure, and used the data to construct a predictive microkinetic model. As it turned out, AuPt/ZrO2 showed the highest selectivity, yielding 32 % of GA at 100 °C and 30 barg O2. Our results provide valuable insights for the developing of efficient catalysts and point out the bottlenecks for the oxidation of glucose to GA.
Keywords: glucaric acid, glucose oxidation, catalyst characterization, density functional theory, microkinetic modelling
Published in DiRROS: 06.12.2023; Views: 325; Downloads: 177
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1652.
Utilizing ablation volume for calibration in LA-ICP-MS mapping to address variations in ablation rates within and between matrices
Kristina Mervič, Johannes Teun van Elteren, Marjan Bele, Martin Šala, 2024, original scientific article

Published in DiRROS: 06.12.2023; Views: 281; Downloads: 176
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1653.
Šola rakov glave in vratu : Onkološki inštitut Ljubljana, 1. december 2023
2023, not set

Abstract: V zborniku je celostno predstavljena problematika rakov glave in vratu, kot jo dojemajo strokovnjaki, ki se vsakodnevno srečujejo z bolniki s temi raki. Osvetljeni so vzroki za nastanek rakov glave in vratu, incidenca, mortaliteta in sodobni epidemiološki trendi, znaki in simptomi, ki jih povzročajo, načela sodobne diagnostike in zdravljenja s posledično morbiditeto ter možnosti podporne terapije in rehabilitacije. Poseben poudarek je namenjen obravnavi teh rakov v slovenskem prostoru in nacionalnim smernicam.
Published in DiRROS: 06.12.2023; Views: 287; Downloads: 139
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1654.
Vloga histopatologa pri odkrivanju malignih tumorjev kože
Boštjan Luzar, Igor Bartenjev, 2006, published scientific conference contribution

Keywords: koža, kožne spremembe, novotvorbe, diagnostika, histopatologija
Published in DiRROS: 05.12.2023; Views: 301; Downloads: 86
.pdf Full text (1,02 MB)

1655.
Vloga dermoskopije v diagnostiki pigmentiranih sprememb kože
Igor Bartenjev, Boštjan Luzar, 2006, published professional conference contribution

Keywords: koža, kožne spremembe, nevusi, diagnostika, dermoskopija
Published in DiRROS: 05.12.2023; Views: 292; Downloads: 80
.pdf Full text (162,03 KB)

1656.
Klinična slika malignih tumorjev kože
Igor Bartenjev, 2006, published professional conference contribution

Keywords: kožni rak, rak (medicina), novotvorbe, diagnostika, klinična slika
Published in DiRROS: 05.12.2023; Views: 320; Downloads: 77
.pdf Full text (273,43 KB)

1657.
Zgodnje odkrivanje, zdravljenje in spremljanje bolnikov z rakom prostate
Ciril Oblak, 2006, not set

Keywords: rak (medicina), prostata, novotvorbe, diagnostika, zdravljenje
Published in DiRROS: 05.12.2023; Views: 283; Downloads: 70
.pdf Full text (568,38 KB)

1658.
New discoveries in prostate cancer pathogenesis
Gregor Mikuž, 2006, not set

Keywords: rak (medicina), prostata, novotvorbe, diagnostika
Published in DiRROS: 05.12.2023; Views: 246; Downloads: 81
.pdf Full text (500,60 KB)

1659.
Vloga patologa pri diagnostiki karcinoma prostate
Zdenka Ovčak, 2006, not set

Keywords: rak (medicina), prostata, novotvorbe, biopsija, diagnostika
Published in DiRROS: 05.12.2023; Views: 310; Downloads: 70
.pdf Full text (334,89 KB)

1660.
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