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21.
Application of multivariate statistical methods for determining geochemical trends of elements on the territory of Slovenia
Robert Šajn, Mateja Gosar, Jasminka Alijagić, Tamara Teršič, 2024, izvirni znanstveni članek

Povzetek: The main objective of this study is to map multi-element geochemical anomalies in soil on a regional scale. We aimed to determine and evaluate the baseline geochemical values and main geochemical trends in soil that may serve as reference values against any future changes. A total of 817 topsoil samples (0–10 cm) were collected in a 5 × 5 km grid and analyzed for 35 elements using ICP-ES after multi-acid digestions (HClO4/HNO3/HCl/HF) and 53 elements using ICP-MS after modified aqua regia digestion (HCl/HNO3/H2O). The analytical results for the two different digestion methods (multi-acid digestion vs. aqua regia) were also compared for each chemical element. Multivariate statistical methods were applied to identify the geochemical trends and main sources of trace elements over the territory of Slovenia. Based on these results, seven natural and one mixed natural/anthropogenic geochemical association were established. The contents and trends of the determined factors are presented according to 8 natural units, 4 drainage areas, and geological units characteristic of Slovenia. The identified anthropogenic geochemical association combines toxic elements (Ag, Bi, Cd, Hg, P, Pb, S, Sn, and Zn). Increased values of these elements can be found in mining areas and metallurgic centers, in Quaternary sediments of the Sava River, and Adriatic Basin as the consequence of past mining activities and in the Julian Alps, where their origin could be connected to the atmospheric deposition.
Ključne besede: soil, geochemical mapping, distribution of geochemical elements, factor analysis, cluster analysis
Objavljeno v DiRROS: 04.01.2024; Ogledov: 207; Prenosov: 54
.pdf Celotno besedilo (9,92 MB)

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Cost-benefit analysis of fire protection in buildings : application of a present net value approach
Thomas Gernay, Shuna Ni, David Unobe, Andrea Lucherini, Ranjit Kumar Chaudhary, Ruben Van Coile, 2023, izvirni znanstveni članek

Povzetek: In fire safety engineering, cost–benefit analysis provides a systematic method to assess whether the projected benefits from a fire safety measure outweigh its costs. However, there remains a wide discrepancy between methods used in the field for cost–benefit analysis, as well as a lack of quantitative data on the costs and economic impact of fire protection in buildings. In a recent research project, a reference methodology was proposed based on Present Net Value evaluation and on a combination of specialized construction database, fire statistics, and numerical modeling for estimation of the cost components. This paper presents the application of the methodology to four case studies. The case studies allow describing the methodology, the collection of data, fire statistics, and loss estimation, as well as illustrating how the methodology can support decision-making when multiple alternatives are compared. Under the assumptions adopted for the single-family house and the residential timber building case studies, it is found that for every 1\$, invested in sprinklers, \$1.06 is saved. This benefit–cost ratio increases with increasing valuation of indirect losses and statistical value of life. Sensitivity analyses are provided to explore the robustness of the investment recommendations. The results of evaluations, adapted from the presented case studies with project-specific inputs, can support decision making for policy makers, insurance companies, and individual building owners.
Ključne besede: fire safety, cost-benefit analysis, fire protection, fire statistics, sprinklers, compartmentation
Objavljeno v DiRROS: 29.11.2023; Ogledov: 259; Prenosov: 32
.pdf Celotno besedilo (758,66 KB)
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Monitoring the galvanic corrosion of copper–steel coupling in bentonite slurry during the early oxic phase using coupled multielectrode arrays
Tadeja Kosec, Miha Hren, Klara Prijatelj, Bojan Zajec, Nina Gartner, Andraž Legat, 2023, izvirni znanstveni članek

Povzetek: In the case of a two-part container for spent nuclear fuel, consisting of an iron-based inner structure with a copper coating, the potential perforation of copper through minor damage may result in intensive galvanic corrosion between copper and steel. The present work focuses on the corrosion of steel galvanically coupled to copper and exposed to a slightly saline environment under oxic conditions. The electrochemical processes on individual electrodes were monitored by coupled multielectrode arrays (CMEAs). The CMEAs were either in contact with groundwater saturated with bentonite or immersed in groundwater only. Very high galvanic corrosion currents were detected between carbon steel and pure copper in the early oxic phase. Additionally, the use of CMEAs further made it possible to monitor the distribution of cathodic currents around the steel electrode, which behaved anodically. Various microscopy and spectroscopy techniques were applied to identify the modes of corrosion and the type of corrosion products present at the end of the period of exposure.
Ključne besede: copper, steel, bentonite, Aspö groundwater, coupled multi electrode array, electrochemical properties, Raman analysis, corrosion
Objavljeno v DiRROS: 16.11.2023; Ogledov: 360; Prenosov: 60
.pdf Celotno besedilo (1,66 MB)
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25.
Cost-benefit analysis in fire safety engineering : state-of-the-art and reference methodology
Ruben Van Coile, Andrea Lucherini, Ranjit Kumar Chaudhary, Shuna Ni, David Unobe, Thomas Gernay, 2023, izvirni znanstveni članek

Povzetek: Cost-effectiveness is a key consideration within fire safety engineering. Currently, different approaches are being applied in literature. These approaches differ in how cost-effectiveness is evaluated, which costs are considered, and how the preferred design solution is defined. Recognizing this issue, the Fire Protection Research Foundation enrolled an international team of researchers, supported by a broad stakeholder panel, to develop a reference methodology. In this paper, this reference methodology for cost-benefit analysis in fire safety engineering is presented following an extensive literature review. The methodology clarifies the minimum requirements for assessing cost-effectiveness, and highlights that only a present net value evaluation can be used to compare design alternatives. Commonly used cost-benefit ratios should only be used when deciding on the effectiveness of a single package of fire safety measures. An illustrative case study demonstrates the application of the meth- odology and shows how designs based on cost-benefit ratios can be sub-optimal when evaluating multiple possible fire safety measures.
Ključne besede: cost-benefit analysis, fire safety, investment, maintenance, loss, statistics, reliability
Objavljeno v DiRROS: 23.10.2023; Ogledov: 339; Prenosov: 77
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26.
Projections of the European Green Deal into national strategic documents in the Czech Republic : the case of forestry
Petra Palátová, 2023, objavljeni znanstveni prispevek na konferenci

Ključne besede: circular economy, forestry, sustainability, bioeconomy, content analysis
Objavljeno v DiRROS: 06.10.2023; Ogledov: 261; Prenosov: 103
.pdf Celotno besedilo (114,50 KB)

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Effects of specific parameters on simulations of energy use and air temperatures in offices equipped with radiant heating/cooling panels
Sabina Jordan, Jože Hafner, Martina Zbašnik-Senegačnik, Andraž Legat, 2019, izvirni znanstveni članek

Povzetek: When creating a simulation model to assess the performance of buildings, there is usually a lack of feedback information. Only in the case of measurements of a real building is a direct comparison of the measured values and simulated results possible. Parameter data related to users’ behavior or other events can also be obtained. Their evaluated frequency, magnitude and duration, along with boundary conditions, are crucial for the results. It is clear that none of them can be predicted very accurately. Most of them, however, are needed for computer modeling. In this paper we analyzed the well-defined TRNSYS simulation model of offices equipped with radiant ceiling panels for heating and cooling. The model was based on real case offices and was validated based on measurements for 1 year. The analysis included simulations in order to define what effect the parameters related mainly to users have on the energy use and the indoor air temperatures. The study confirmed that specific human activities influence the annual energy use to a relatively small degree and that their effects often counteract. It also confirmed the even more important fact that although small, these activities can influence the thermal comfort of users. It is believed that despite the fact that this research was based on an analysis of offices equipped with radiant ceiling panels, most of the results could be applied generally.
Ključne besede: measurements, modeling, simulation, validation, analysis, energy use, temperature
Objavljeno v DiRROS: 15.09.2023; Ogledov: 299; Prenosov: 145
.pdf Celotno besedilo (1,83 MB)
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30.
Methodology for evaluating the CO2 sequestration capacity of waste ashes
Sara Tominc, Vilma Ducman, 2023, izvirni znanstveni članek

Povzetek: The concentration of CO2 in the atmosphere is constantly increasing, leading to an increase in the average global temperature and, thus, affecting climate change. Hence, various initiatives have been proposed to mitigate this process, among which CO2 sequestration is a technically simple and efficient approach. The spontaneous carbonation of ashes with atmospheric CO2 is very slow, and this is why accelerated carbonation is encouraged. However, not all ashes are equally suitable for this process, so a methodology to evaluate their potential should be developed. Such a methodology involves a combination of techniques, from theoretical calculations to XRF, XRD, DTA-TG, and the calcimetric determination of the CaCO3 content. The present study followed the approach of exposing ashes to accelerated carbonation conditions (4% v/v CO2, 50–55% and 80–85% RH, 20 ◦C) in a closed carbonation chamber for different periods of time until the maximum CO2 uptake is reached. The amount of sequestered CO2 was quantified by thermogravimetry. The results show that the highest CO2 sequestration capacity (33.8%) and carbonation efficiency (67.9%) were obtained for wood biomass bottom ash. This method was applied to eight combustion ashes and could serve to evaluate other ashes or comparable carbon storage materials.
Ključne besede: CO2 sequestration, carbonation efficiency, coal ash, wood biomass ash, co-combustion ash, DTA-TG analysis
Objavljeno v DiRROS: 08.08.2023; Ogledov: 371; Prenosov: 157
.pdf Celotno besedilo (3,73 MB)
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