Digitalni repozitorij raziskovalnih organizacij Slovenije

Iskanje po repozitoriju
A+ | A- | Pomoč | SLO | ENG

Iskalni niz: išči po
išči po
išči po
išči po

Možnosti:
  Ponastavi


Iskalni niz: "avtor" (Marijan Nečemer) .

1 - 10 / 10
Na začetekNa prejšnjo stran1Na naslednjo stranNa konec
1.
2.
Physicochemical and thermal properties of aluminosilicate gels based on metakaolin doped with different amounts of samarium(III)-oxide
Sanja Knežević, Marija M. Ivanović, Snežana S. Nenadović, Dorota Korte, Mohanachandran Nair Sindhu Swapna, Marijan Nečemer, Miloš Nenadović, 2026, izvirni znanstveni članek

Povzetek: Aluminosilicate materials, known for their high strength, corrosion resistance, and thermal stability, are synthesized through the alkali activation of metakaolin, incorporating Sm2O3 to investigate the impact on their physicochemical properties. This study takes a look at the synthesis and physicochemical characterization of aluminosilicate gels doped with samarium(III)-oxide (Sm2O3), focusing on their potential as thermal insulators due to their enhanced thermal conductivity and absorption properties. Two samples with 1% and 5% Sm2O3 by weight were investigated, referred to as S1 and S2, respectively. Characterization techniques such as energy-dispersive X-ray fluorescence spectrometry (EDXRF), diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), scanning electron microscopy (SEM), and photothermal beam deflection (PBD) were employed for the physicochemical characterization of aluminosilicate materials. The structural analysis shows an integration of Sm2O3, which did not significantly affect the gel’s density or porosity but enhanced its thermal conductivity. This study shows the potential of Sm2O3-doped aluminosilicates in applications requiring improved thermal management and stability, positioning them as potentially suitable materials for insulation.
Ključne besede: metakaolin, samarium(III) oxide
Objavljeno v DiRROS: 20.05.2026; Ogledov: 271; Prenosov: 225
.pdf Celotno besedilo (2,61 MB)
Gradivo ima več datotek! Več...

3.
Additive manufacturing of polymer-derived SiOC(Fe) ceramic composites as a catalyst support exhibiting magnetic heating capability
Milan Vukšić, Thomas Konegger, Martin Schwentenwein, Sašo Gyergyek, Anja Sedminek, Sandra Drev, Marijan Nečemer, Andraž Kocjan, Aljaž Iveković, 2026, izvirni znanstveni članek

Povzetek: Additive manufacturing (AM) of advanced functional ceramics using preceramic polymers (PCPs) is gaining attention due to its processability and tailorable properties. A photosensitive resin with iron-modified polysiloxanes was developed for vat photopolymerization (VPP) to create porous SiOC(Fe) catalytic supports with magnetic heating capability. Ferric acetylacetonate and ferrocene were examined as iron precursors, leading to the formation of Fe-based magnetic particles (α-Fe, Fe3C, FexSiy) within the silicon oxycarbide (SiOC) ceramic matrix after pyrolysis at 800 to 1500 °C. Depending on the Fe-based precursor used and the applied pyrolysis temperature, the obtained monoliths exhibited magnetic nanoparticle (MNP) contents ranging from 0.9 to 7.9 wt%, with particle sizes from 17 to 96 nm. The monolithic catalyst supports fabricated from ferric acetylacetonate modified PCP-based resin formulations, pyrolyzed at 900 °C, exhibited the highest specific absorption rate and resulted in magnetic heating up to 200 °C at an applied external magnetic field of 60 kA·m−1. While catalyst supports fabricated from ferrocene modified PCP-based resin formulations had lower heating capabilities, they offered better printability and higher ceramic yield. In situ formed MNPs impart magnetic properties advantageous for catalyst support heating, highlighting AM’s design flexibility and PCPs’ role in creating tailored, lightweight structures with controlled porosity.
Ključne besede: preceramic polymers, magnetic nanoparticles, ceramic nanocomposite, induction/magnetic heating, advanced functional ceramics
Objavljeno v DiRROS: 20.05.2026; Ogledov: 430; Prenosov: 394
.pdf Celotno besedilo (13,76 MB)
Gradivo ima več datotek! Več...

4.
Naravoslovne preiskave kovinskega gradiva z grobišča Pezdirčeva njiva v Podzemlju
Nataša Nemeček, Mitja Petrič, Peter Fajfar, Barbara Šetina, Marijan Nečemer, 2025, samostojni znanstveni sestavek ali poglavje v monografski publikaciji

Objavljeno v DiRROS: 23.03.2026; Ogledov: 465; Prenosov: 306
.pdf Celotno besedilo (11,03 MB)
Gradivo ima več datotek! Več...

5.
Radiological characterization of alkali-activated material doped with Sm[sub]2O[sub]3 and its polymerization products
Sanja Knežević, Marija M. Ivanović, Snežana S. Nenadović, Milica Rajačić, Marijan Nečemer, Jelena Potočnik, Miloš Nenadović, 2024, izvirni znanstveni članek

Povzetek: The aim of this study was determination of radiological characterization of alkali-activated material with Sm2O3 and its polymerization products. Alkali-activated materials with 1 wt.% and 5 wt.% addition of Sm2O3 were synthesized and their natural radioactivity was determined. Energy dispersive X-ray fluorescence showed changes in the phase composition, or the formation of stable compounds, at higher temperatures. All samples demonstrated good pozzolanic activity, while the percentage of Sm2O3 was slightly changed. The X-ray photoelectron spectroscopy confirmed that the obtained material has a very low carbon content making it environmentally friendly, due to its low carbon content. A detailed analysis of the oxygen peak indicates variations in the stoichiometry of the oxides, which may affect the changes of natural radioactivity. Scanning electron microscopy confirmed that with the increase in the temperature of the thermal treatment, the opening of the pores in the alkali-activated material occurs, as well as further propagation of reaction that increased porosity and crystallization. Radiological measurement confirmed that examined alkali-activated material is safe for usage and exploitation. It should be emphasized that the presence of artificial radionuclide cesium 137Cs was not detected.
Ključne besede: alkali-activated material, energy dispersive X-ray fluorescence, X-ray photoelectron spectroscopy, samarium oxide
Objavljeno v DiRROS: 15.01.2026; Ogledov: 599; Prenosov: 330
.pdf Celotno besedilo (1,37 MB)
Gradivo ima več datotek! Več...

6.
7.
8.
9.
10.
Iskanje izvedeno v 8.2 sek.
Na vrh