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Povzetek: Mineral CO2 sequestration is a promising carbon capture and storage approach based on the chemical reaction of CO2 with alkaline materials containing Ca- and Mg-rich (hydr)oxides and silicates. This results in the formation of relatively insoluble and storable carbonates. This study investigates six ashes of different origins and chemical compositions to assess their CO2 sequestration potential and leaching behavior, offering insights into their environmental impact and potential risks. The carbonation experiments were conducted under controlled laboratory conditions and the CO2 sequestration capacity was quantified using a pressure calcimeter, supported by thermogravimetric analysis. Wood ashes and ash from the co-combustion of biomass from a paper mill showed the highest carbonation potential, with CO2 sequestration capacities between 344.8 and 432.3 g CO2 per kg of ash and carbonation efficiencies between 82.4 % and 94.4 %. In addition to the high sequestration capacity of the ashes, carbonation was found to affect the leaching behavior of the ash in the environment by changing its mineralogical composition. The process consistently reduced pH and generally decreased the leaching of certain trace elements, except for Mo, and Cr. Nevertheless, the reduction in the leachability of several elements suggests a partial environmental benefit of carbonation. The findings highlight the dual functionality of the carbonation: it provides a viable route for the permanent binding of CO2 and can enhance the stabilization of industrial residues. However, the persistence of metal leaching indicates that its overall effectiveness in mitigating environmental risks associated with residue disposal or reuse remains material-dependent.
Ključne besede: enforced carbonation, maximum sequestration capacity, leaching, heavy metals, mineralogy, bio-based ash
Objavljeno v DiRROS: 13.01.2026; Ogledov: 310; Prenosov: 284
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Povzetek: The dataset supports the data presented in the tables and figures of the scientific article Sequestration capacity of bio-based ashes and influence of carbonation on the leaching behavior depending on their mineralogical composition (doi: 10.1016/j.ceramint.2025.11.229). It includes calcimetric measurements, XRF, TGA, and XRD analysis data, as well as calculations of CO2 uptake and CO2 sequestration capacity for the analyzed samples. Additionally, it contains original FTIR measurement data, which are not included in the article and serve as supplementary material.
Ključne besede: enforced carbonation, maximum sequestration capacity, leaching, heavy metals, mineralogy, bio-based ash
Objavljeno v DiRROS: 21.10.2025; Ogledov: 483; Prenosov: 223
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Povzetek: The dataset supports the data in the tables and figures in the conference article Mineral waste into alkali-activated pavements (doi: www.doi.org/10.18690/um.fkkt.1.2025.11). It contains measurements of mechanical properties, original data of the XRD analyses as well as results of leaching tests.
Ključne besede: alkali-activation, pavement slabs, mineral waste, recycling
Objavljeno v DiRROS: 09.04.2025; Ogledov: 1082; Prenosov: 581
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Povzetek: Two synthesis pathways (one- and two-part) in alkali-activated binders were compared using ground granulated blast furnace slag (GGBFS), mineral wool (MW) activated using dry and liquid alkali activators with similar Na2O/SiO2 modulus. The effect of activator type on reaction kinetics, strength development, setting times, and durability shows that one-part synthesis does not only improve early strength, but also provide better durability properties. While the highest compressive strength (56 MPa, 90 days) was achieved for the one-part mix (DM), the reaction products (presence of Mg–Al layered double hydroxide and C–S–H-like phases) observed for both mortar mixes were similar. The DM mortars showed better resistance to sulfate attack than two-part mix (WM) mortars and sets faster. The results highlight the significance of the one-part pathways in the synthesis of alkali-activated materials.
Ključne besede: recycling, alkali activated material, mineral wool
Objavljeno v DiRROS: 11.03.2024; Ogledov: 1950; Prenosov: 1229
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Povzetek: Mineral wool, i.e. rock and glass wool, represents considerable challenge after its functional-time runs out due to its small density leading to large volume consumption during transport and in landfills where it usually ends. Because rock wool is mineralogically and chemically a promising precursor material for alkali-activation, it was milled from few centimetres-decimeters long fibres to micron-sized fibres. Since fibres in alkali-activated materials generally show an increase in mechanical strength, especially the bending strength, 1 m% of additional fibres (basalt, cellulose (2 types), glass, polypropylene, polyvinyl alcohol and steel fibres) was used in the alkali mixture, that was curred at 40 °C for 3 days. Time dependence of the mechanical strengths of alkali- activated materials with and without additional fibres was followed. Maximal increase of compressive and bending strength after 28 days was reached with polypropylene fibres, i.e. it was 20% and 30% higher than compressive and bending strength of alkali- activated material without additional fibres respectively.
Ključne besede: secondary raw material, alkali activated material, foaming, homogenization, mechanical strength
Objavljeno v DiRROS: 21.12.2023; Ogledov: 1550; Prenosov: 784
Celotno besedilo (8,39 MB)
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