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22. Hydrothermal synthesis of rare-earth modified titania : influence on phase composition, optical properties, and photocatalytic activityNejc Rozman, David Maria Tobaldi, Uroš Cvelbar, Harinarayanan Puliyalil, Joao Antonio Labrincha, Andraž Legat, Andrijana Sever Škapin, 2019, izvirni znanstveni članek Povzetek: In order to expand the use of titania indoor as well as to increase its overall performance, narrowing the band gap is one of the possibilities to achieve this. Modifying with rare earths (REs) has been relatively unexplored, especially the modification of rutile with rare earth cations. The aim of this study was to find the influence of the modification of TiO2 with rare earths on its structural, optical, morphological, and photocatalytic properties. Titania was synthesized using TiOSO4 as the source of titanium via hydrothermal synthesis procedure at low temperature (200 °C) and modified with selected rare earth elements, namely, Ce, La, and Gd. Structural properties of samples were determined by X-ray powder diffraction (XRD), and the phase ratio was calculated using the Rietveld method. Optical properties were analyzed by ultraviolet and visible light (UV-Vis) spectroscopy. Field emission scanning electron microscope (FE-SEM) was used to determine the morphological properties of samples and to estimate the size of primary crystals. X-ray photoelectron spectroscopy (XPS) was used to determine the chemical bonding properties of samples. Photocatalytic activity of the prepared photocatalysts as well as the titania available on the market (P25) was measured in three different setups, assessing volatile organic compound (VOC) degradation, NOx abatement, and water purification. It was found out that modification with rare earth elements slows down the transformation of anatase and brookite to rutile. Whereas the unmodified sample was composed of only rutile, La- and Gd-modified samples contained anatase and rutile, and Ce-modified samples consisted of anatase, brookite, and rutile. Modification with rare earth metals has turned out to be detrimental to photocatalytic activity. In all cases, pure TiO2 outperformed the modified samples. Cerium-modified TiO2 was the least active sample, despite having a light absorption tail up to 585 nm wavelength. La- and Gd-modified samples did not show a significant shift in light absorption when compared to the pure TiO2 sample. The reason for the lower activity of modified samples was attributed to a greater Ti3+/Ti4+ ratio and a large amount of hydroxyl oxygen found in pure TiO2. All the modified samples had a smaller Ti3+/Ti4+ ratio and less hydroxyl oxygen
Ključne besede: TiO2, photocatalytic activity, rare earths, modification, visible light activity
Objavljeno v DiRROS: 22.11.2023; Ogledov: 273; Prenosov: 143
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23. Closing data gaps and paving the way for pan-European fire safety efforts : Terminology of fire statistical variablesMartina Manes, Ana Sauca, Mohamad El Houssami, Petra Andersson, Colin McIntyre, Richard Campbell, David Rush, Anja Hofmann, Peter Wagner, Sergei Sokolov, Mindel Leene, Margrethe Kobes, Dirk Oberhagemann, Nicola Rupp, Grunde Jomaas, Friedrich Grone, Eric Guillaume, 2023, izvirni znanstveni članek Povzetek: A well-defined terminology of fire-related variables is important for correct analyses and supporting knowledge-based decisions regarding the evaluation of building fires at the European level. After developing an overview of current practices for fire statistics in Part I, the terminology used and the data collected by the EU Member States and eight other countries regarding fire incidents, property damage and human losses were mapped to increase awareness of their practice and support a comprehensive assessment of several fire statistical datasets. A questionnaire was distributed to relevant authorities responsible for the collection, elaboration/analysis, and fire statistical data publications to define and select the essential variables for an appropriate fire assessment and fire incident description. Based on the results of the questionnaire able to identify the essential fire statistical variables and a detailed analysis of current definitions adopted in the fire statistics of the EU Member States and other countries, a common terminology is proposed to collect the necessary data in the EU Member States and obtain meaningful datasets based on standardised terms and definitions. The results will generate essential outputs to move towards harmonised fire statistics at the EU level and contribute to an appropriate analysis able to improve fire prevention and fire mitigation in building fires.
Ključne besede: fire statistics, fire incidents, building fires, fire statistical variables, terminology
Objavljeno v DiRROS: 13.11.2023; Ogledov: 305; Prenosov: 152
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24. Closing data gaps and paving the way for pan-European fire safety efforts : Part IMartina Manes, Mohamad El Houssami, Richard Campbell, Ana Sauca, David Rush, Anja Hofmann, Petra Andersson, Peter Wagner, Sergei Sokolov, Johanna Veeneklaas, Margrethe Kobes, Dirk Oberhagemann, Nicola Rupp, Grunde Jomaas, Friedrich Grone, Patrick van Hees, Eric Guillaume, 2023, izvirni znanstveni članek Povzetek: The analysis of the current state of fire statistics and data collection in Europe and other countries is needed to increase awareness of how fire incidents affect buildings and to support pan-European fire prevention and fire mitigation mea- sures. The terminology and data collected regarding fire incidents in buildings in the EU Member States were mapped to obtain meaningful datasets to determine common terminology, collection methodology, and data interpretation system. An extensive literature review showed that fire data collection systems have been instrumental in informing firefighting strategies, evidence-based planning, prevention, and educational programmes. Differences and similarities between fire data collection systems were also investigated. The amount and quality of the information in fire statistical recording systems appear to be influenced by the complexity and structure with which the data are collected. The analysis also examined the existing fire statistics in the EU Member States and a few other countries. Finally, a detailed investigation of the number of fires, fire deaths, and injuries from 2009 to 2018 in several countries was examined based on data from a report by CTIF. The trends showed differences attributable to the existing fire statistical practices in terms of terminology and data collection, and interpretation. Part II proposes a common terminology for selected fire statistical variables. The results provide relevant information regarding fire safety at the European level and should be used to guide the development of more uniform fire statistics across Europe.
Ključne besede: fire statistics, fire incidents, fire statistical variable, terminology, data collection, data interpretation
Objavljeno v DiRROS: 13.11.2023; Ogledov: 382; Prenosov: 111
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25. Flame spread behaviour of Polydimethylsiloxane (PDMS) membranes in 1 g and µg environmentsWilson Ulises Rojas Alva, Frederik Møller-Poulsen, Sze Lok Man, Cameron Creamer, David Hanna, Grunde Jomaas, 2022, izvirni znanstveni članek Povzetek: Diffusion flame behaviour and silica ash (SiO2) production were experimentally studied for various Polydimethylsiloxane (PDMS) membrane thicknesses (0.125 mm to 1.0 mm) in normal gravity and during microgravity flight experiments. The flames were established on vertical samples (300 mm in length) and subjected to either opposed or concurrent forced flows (both laminar and turbulent), assimilating the NASA Test 1 that is in use for spacecraft material selection. The opposed flame spread rate was observed to be steady and could be estimated using classical theory. Under concurrent flow, the flame spread rate was only steady for very high forced flows. The opposed flame-spread rate ranged from 0.5 to 1.5 mm/s, while the concurrent case ranged between 0.1 and 12 mm/s. The transport of silica ash (SiO2) was found to affect the heat balance of the concurrent flame spread in a manner that resulted in unsteady flame spread. For opposed flame spread, on the other hand, the transport of silica ash showed to be irrelevant. The extinction behaviour for the concurrent flame spread was heavily dominated by the transport of silica-ash, while for opposed flames, extinction was due to kinetics (at high forced flows). In microgravity environments, the transport and deposition of silica ash is anticipated to dominate flame spread and near-limit as well. These results suggest that silica-based products might be less flammable in microgravity than other similar materials such as common thermoplastics (PP or PE) used as wire jackets.
Ključne besede: silicone burning, spacecraft fire safety, flame spread, near-limit, silica-ash
Objavljeno v DiRROS: 13.11.2023; Ogledov: 321; Prenosov: 84
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27. Cost-benefit analysis in fire safety engineering : state-of-the-art and reference methodologyRuben Van Coile, Andrea Lucherini, Ranjit Kumar Chaudhary, Shuna Ni, David Unobe, Thomas Gernay, 2023, izvirni znanstveni članek Povzetek: Cost-effectiveness is a key consideration within fire safety engineering. Currently, different approaches are being applied in literature. These approaches differ in how cost-effectiveness is evaluated, which costs are considered, and how the preferred design solution is defined. Recognizing this issue, the Fire Protection Research Foundation enrolled an international team of researchers, supported by a broad stakeholder panel, to develop a reference methodology. In this paper, this reference methodology for cost-benefit analysis in fire safety engineering is presented following an extensive literature review. The methodology clarifies the minimum requirements for assessing cost-effectiveness, and highlights that only a present net value evaluation can be used to compare design alternatives. Commonly used cost-benefit ratios should only be used when deciding on the effectiveness of a single package of fire safety measures. An illustrative case study demonstrates the application of the meth- odology and shows how designs based on cost-benefit ratios can be sub-optimal when evaluating multiple possible fire safety measures.
Ključne besede: cost-benefit analysis, fire safety, investment, maintenance, loss, statistics, reliability
Objavljeno v DiRROS: 23.10.2023; Ogledov: 339; Prenosov: 77
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29. Social innovation to address sustainability challenges and enlarge the opportunities provided by forests for a green and just transition of marginalised mountain areasMaria Nijnik, Simo Sarkki, Mariana Melnykovych, David Miller, 2023, objavljeni znanstveni prispevek na konferenci (vabljeno predavanje) Ključne besede: natural capital, ecosystem services, woodlands, communities, stakeholder engagement, sustainability, resilience
Objavljeno v DiRROS: 04.10.2023; Ogledov: 342; Prenosov: 103
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30. Developing and assessing surveillance methodologies for Agrilus beetles : EuphrescoDavid Williams, Abigail Enston, Joseph A. Francese, Damon Crook, Gernot Hoch, Maarten De Groot, 2023, končno poročilo o rezultatih raziskav Ključne besede: Agrilus, beetles, developing surveillance, assessing surveillance
Objavljeno v DiRROS: 18.09.2023; Ogledov: 431; Prenosov: 138
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