1. Effect of chemical and physico-chemical activation on the properties of 3D printed concrete with a low-cement multicomponent binderEvaldas Šerelis, Vitoldas Vaitkevicius, Lidija Korat Bensa, Vesna Zalar Serjun, Maris Šinka, Diana Bajare, Audrius Grinys Grinys, Karolina Butkute, 2026, izvirni znanstveni članek Povzetek: This research proposes an alternative low-cement multicomponent binder for extrusion-based 3D concrete printing to reduce CO2 emissions associated with high Portland cement content. Due to the extremely low Portland cement content (100 kg/m3), the proposed mixture presents several limitations, making it unsuitable for 3D printing without additional activation. To overcome these limitations, chemical and physico-chemical activation methods were applied to promote rapid early-age structuration, partly associated with accelerated ettringite formation, thereby improving compliance with the printing process requirements. The results demonstrate that both activation methods positively affect Portland cement hydration and improve printing-related properties. The research focuses primarily on the hardened properties of 3D-printed concrete, showing that activation reduces macroscopic porosity and increases density and compressive strength. The applied activation methods also increase overall shrinkage compared to the nonactivated low-cement mixture. However, the absolute shrinkage remains approximately 25–30 % lower than that of a conventional reference mortar with a high Portland cement content. The suitability of the components used in the multicomponent binder was evaluated through pozzolanic activity testing. In contrast, the effects of chemical and physico-chemical activation on binder phase composition were investigated by X-ray diffraction, and the hardened properties of concrete were assessed using X-ray computed tomography, mercury intrusion porosimetry, shrinkage measurements, density, and compressive strength testing. The results demonstrate that chemical and physico-chemical activation enables the effective use of low-cement multicomponent binders in extrusion-based 3D concrete printing, providing a more sustainable alternative to conventional high-cement mixtures. Ključne besede: 3D-tiskanje betona, večkomponentno vezivo z nizko vsebnostjo cementa, kemična aktivacija, fizikalno-kemična aktivacija, krčenje, 3D concrete printing, low-cement multicomponent binder, chemical activation, physico-chemical activation, shrinkage Objavljeno v DiRROS: 15.05.2026; Ogledov: 164; Prenosov: 122
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2. Mechanical properties of 3D printed concrete : a RILEM 304‑ADC interlaboratory study – flexural and tensile strengthRob Wolfs, Jelle Versteege, Manu Santhanam, Shantanu Bhattacherjee, Freek Bos, Annika Robens-Radermacher, Shravan Muthukrishnan, Costantino Menna, Katarina Šter, Aljoša Šajna, 2025, izvirni znanstveni članek Povzetek: This paper discusses the flexural and tensile strength properties of 3D printed concrete, based on the results of a RILEM TC 304-ADC interlaboratory study on mechanical properties. These properties are determined using different testing techniques, including 3- and 4-point flexural tests, splitting tests, and uniaxial tension tests, on specimens extracted from large 3D printed elements in accordance with a prescribed study plan. The relationship between compressive and flexural or tensile strengths, cast or printed samples, different types of tests, and different loading orientations, are analysed to understand the influence of 3D printing. As expected, the strength can reduce significantly when the main tensile stress is acting perpendicular to the interface between layers. The role of deviations from the standard study procedure, in terms of the time interval between the placing of subsequent layers, or the adoption of a different curing strategy, are also assessed. While the increased time interval significantly impacts the strength in the critical direction, the use of variable curing conditions does not seem to have a clear-cut effect on the strength ratios of the printed to cast specimens. Additionally, the paper looks at the variability in the results for the printed specimens, in order to emphasize the need for multiple replicates for obtaining a proper result. An extensive insight into the aspects affecting the variability is presented in the paper. Finally, with the limited dataset available for specimens tested at a larger scale, it is difficult to arrive at a clear understanding of the role of specimen size (i.e., greater number of layers). Ključne besede: 3D concrete printing, digital fabrication, flexural strength, tensile strength, interlayer bond strength Objavljeno v DiRROS: 12.01.2026; Ogledov: 488; Prenosov: 852
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3. Establishing benchmark properties for 3D-printed concrete : a study of printability, strength, and durabilityAlise Sapata, Maris Šinka, Genadijs Šahmenko, Lidija Korat Bensa, Lucija Hanžič, Katarina Šter, Sandris Rucevskis, Diana Bajare, Fred P. Bosselman, 2025, izvirni znanstveni članek Povzetek: This study investigates the fresh state and hardened state mechanical and durability properties of 3D-printed concrete. The mechanical tests focused on its anisotropic behavior in response to different load orientations. Compressive, flexural, and splitting tensile strengths were evaluated relative to the print layers orientation. Results showed that compressive strength varied significantly, achieving 85% of cast sample strength when the load was applied parallel to the print layers ([u] direction), 71% when the load was applied perpendicular to the print object’s side plane ([v] direction), while only reaching 59% when applied perpendicular to the top plane ([w] direction). Similar trends were observed for flexural strength, with average values reaching 75% of cast sample strength when the load was applied perpendicular to the print layers ([v.u] and [w.u] directions), but decreasing to 53% when the load was applied parallel to print layers ([u.w] direction), underscoring the weaknesses at interlayer interfaces. The splitting tensile strength remained relatively consistent across print orientations, reaching 90% of the cast sample strength. Durability assessment tests revealed that 3D-printed concrete exhibits reduced resistance to environmental factors, particularly at the layer interfaces where the cold joint was formed, which are prone to moisture penetration and crack formation. These findings contribute valuable insights into the mechanical and durability properties of 3D-printed concrete, emphasizing the importance of print orientation and interlayer bonding in its performance. This understanding helps guide the optimal use of 3D-printed elements in real-life applications by aligning load or exposure to environmental factors with the material’s strength and durability characteristics. Ključne besede: civil engineering, 3D-printing, concrete, additive manufacturing Objavljeno v DiRROS: 11.02.2025; Ogledov: 3604; Prenosov: 770
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4. Collision milling of oil shale ash as constituent pretreatment in concrete 3D printingLucija Hanžič, Mateja Štefančič, Katarina Šter, Vesna Zalar Serjun, Maris Šinka, Alise Sapata, Genadijs Šahmenko, Evaldas Šerelis, Baiba Migliniece, Lidija Korat Bensa, 2025, izvirni znanstveni članek Povzetek: Concrete is an essential construction material, and infrastructures, such as bridges, tunnels, and power plants, consume large quantities of it. Future infrastructure demands and sustainability issues necessitate the adoption of non-conventional supplementary cementitious materials (SCMs). At the same time, global labor shortages are compelling the conservative construction sector to implement autonomous and digital fabrication methods, such as 3D printing. This paper thus investigates the feasibility of using oil shale ash (OSA) as an SCM in concrete suitable for 3D printing, and collision milling is examined as a possible ash pretreatment. OSA from four different sources was collected and analyzed for its physical, chemical, and mineralogical composition. Concrete formulations containing ash were tested for mechanical performance, and the two best-performing formulations were assessed for printability. It was found that ash extracted from flue gases by the novel integrated desulfurizer has the greatest potential as an SCM due to globular particles that contain β-calcium silicate. The 56-day compression strength of concrete containing this type of ash is ~60 MPa, the same as in the reference composition. Overall, collision milling is effective in reducing the size of particles larger than 10 μm but does not seem beneficial for ash extracted from flue gasses. However, milling bottom ash may unlock its potential as an SCM, with the optimal milling frequency being ~100 Hz. Ključne besede: digital concrete, 3D printing, oil shale ash, supplementary cementitious material, collision milling Objavljeno v DiRROS: 30.01.2025; Ogledov: 1085; Prenosov: 905
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