1. Microstructure and properties of an AZ61 alloy after extrusion with a forward-backward oscillating die without preheating of the initial billetAnna Dobkowska, Aleksandra Zielińska, Irena Paulin, Črtomir Donik, Maciej Łojkowski, Milena Koralnik, Bogusława Adamczyk-Cieślak, Krystian Paradowski, Marek Tkocz, Dariusz Kuc, Jiří Kubásek, Matjaž Godec, Wojciech Święszkowski, 2023, original scientific article Keywords: magnesium alloys, severe plastic deformation, microstructure, mechanical properties, corrosion, extrusion, high deformation ratio
Published in DiRROS: 17.05.2024; Views: 31; Downloads: 22
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2. Bioresorbability dependence on microstructure of additivelly- manufactured and conventionally-produced Fe-Mn alloysMatjaž Godec, Jakob Kraner, Danijela Anica Skobir Balantič, Irena Paulin, Damjana Drobne, Veno Kononenko, Aleksandra Kocijan, Paul J. McGuiness, Črtomir Donik, 2024, original scientific article Keywords: Fe-Mn alloy, laser powder bed fusion, bioresorbable, microstructure, corrosion behaviour, biocompatibility
Published in DiRROS: 06.05.2024; Views: 80; Downloads: 61
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3. The impact of urban rain on the changes of bare and artificially patinated bronze during 9-year exposureTadeja Kosec, Mirjam Bajt Leban, Polonca Ropret, Matjaž Finšgar, 2024, original scientific article Abstract: Atmospheric pollutants in the air form acid rain which interacts with bronze surfaces exposed in urban outdoor environment. In this study, different types of patinas on bronze were investigated during and after 9 years of exposure to urban environment in moderately polluted continental city. Natural bronze patina and artificial brown sulphide, green chloride, and green–blue nitrate patinas were investigated. Visual assessment was carried out at defined periods. After 9 years of exposure, an electrochemical study was performed to investigate the electrochemical activity of the patinas in artificial urban rain. Additionally, the patinas were characterised using a variety of techniques, including metallographic examination, scanning electron microscopy/energy dispersive X-ray spectroscopy, Raman spectroscopy, X-ray diffraction analysis, X-ray-photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry to analyse the surface morphology, chemical composition, and stratigraphic features of the patinas. Evolution of the patinas was shown to be a result of both, the composition of the acid rain and the hydrophobicity of the patinated surfaces.
Keywords: bronze, bronze, corrosion, patina characterization
Published in DiRROS: 29.04.2024; Views: 92; Downloads: 387
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4. Bioresorbability dependence on microstructure of additivelly- manufactured and conventionally-produced Fe-Mn alloysMatjaž Godec, Jakob Kraner, Danijela Anica Skobir Balantič, Irena Paulin, Damjana Drobne, Veno Kononenko, Aleksandra Kocijan, Paul J. McGuiness, Črtomir Donik, 2024, complete scientific database of research data Abstract: The dataset supports the results shown in the tables and figures in the article entitled “Bioresorbability Dependence on Microstructure of Additivelly-Manufactured and Conventionally-Produced Fe-Mn Alloys” (doi.org/10.1016/j.jmrt.2024.04.097). It contains measurements of corrosion resistance of Fe-Mn samples, phase analysis of samples A, B and C, surface and depth profiling XPS, EDS measurements of a cross-section of Fe-Mn powder particles and viability measurements results.
Keywords: Fe-Mn alloy, laser powder bed fusion, bioresorbable, microstructure, corrosion behaviour, biocompatibility
Published in DiRROS: 12.04.2024; Views: 222; Downloads: 93
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6. Effect of post-treated low-temperature plasma nitriding on the wear and corrosion resistance of 316L stainless steel manufactured by laser powder-bed fusionMatjaž Godec, Črtomir Donik, Aleksandra Kocijan, Bojan Podgornik, Danijela Anica Skobir Balantič, 2020, original scientific article Keywords: austenitic stainless steel, powder bed fusion, low-temperature plasma nitriding, wear and corrosion behaviour, dislocation cell structure
Published in DiRROS: 25.03.2024; Views: 116; Downloads: 68
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7. Use of plasma nitriding to improve the wear and corrosion resistance of 18Ni-300 maraging steel manufactured by selective laser meltingMatjaž Godec, Bojan Podgornik, Aleksandra Kocijan, Črtomir Donik, Danijela Anica Skobir Balantič, 2021, original scientific article Keywords: selective laser melting, 18Ni-300 maraging steel, heat treatment, plasma nitriding, retained and reverted austenite, wear and corrosion behaviour
Published in DiRROS: 25.03.2024; Views: 131; Downloads: 65
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8. In vitro and in vivo degradation behavior of Mg-0.45Zn-0.45Ca (ZX00) screws for orthopedic applicationsDiana C. Martinez, Anna Dobkowska, Romy Marek, Hanna Ćwieka, Jakub Jaroszewicz, T. Plociński, Črtomir Donik, Heike Helmholz, Bérengère Luthringer-Feyerabend, Berit Zeller-Plumhoff, Regine Willumeit-Römer, Wojciech Święszkowski, 2023, original scientific article Keywords: magnesium alloys, biodegradable implants, microstructure, electron microscopy, corrosion layers
Published in DiRROS: 08.03.2024; Views: 123; Downloads: 115
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9. B-IMPACT project : eco-friendly and non-hazardous coatings for the protection of outdoor bronzesGiulia Masi, Maëlenn Aufray, A. Balbo, E. Bernardi, Maria Chiara Bignozzi, Cristina Chiavari, J. Esvan, Nina Gartner, V. Grassi, Claudie Josse, Tadeja Kosec, Carla Martini, Cecilia Monticelli, Luka Škrlep, W. Sperotto, Erika Švara Fabjan, E. Tedesco, F. Zanotto, Luc Robbiola, 2020, published scientific conference contribution Abstract: Application of protective coatings is the most widely used conservation treatment for outdoor bronzes. Eco-friendly and non-hazardous coatings are currently needed for conservation of outdoor bronze monuments. To fulfil this need, the M-ERA.NET European research project B-IMPACT (Bronze-IMproved non-hazardous PAtina CoaTings) aimed at assessing the protectiveness of innovative coatings for historical and modern bronze monuments exposed outdoors.
In this project, two bronze substrates (historical Cu-Sn-Zn-Pb and modern Cu-Si-Mn alloys) were artificially patinated, by acid rain solution using dropping test and by "liver of sulphur" procedure (K2S aqueous solution) to obtain black patina, respectively. Subsequently, the application of several newly developed protective coatings was carried out and their performance was investigated by preliminary electrochemical tests. In the following steps of the work, the assessment of the best-performing coatings was carried out and their performance was compared to Incralac, one of the most widely used protective coatings in conservation practice. A multi-analytical approach was adopted, considering artificial ageing (carried out in representative conditions, including exposure to rain runoff, stagnant rain and UV radiation) and metal release, as well as visual aspect (so as to include aesthetical impact among the coating selection parameters) and morphological and structural evolution of the coated surfaces due to simulated outdoor exposure. Lastly, also the health impact of selected coatings was assessed by occupational hazard tests. The removability and re-applicability of the best-performing coatings were also assessed. The best alternatives to the conventional Incralac exhibited were: (i) fluoroacrylate blended with methacryloxy-propyl-trimethoxy-silane (FA-MS) applied on patinated Cu-Sn-Zn-Pb bronze and (ii) 3-mercapto-propyl-trimethoxysilane (PropS-SH) applied on patinated Cu-Si-Mn bronze.
Keywords: bronze, patina, protective coatings, eco-friendly, corrosion, aging
Published in DiRROS: 01.03.2024; Views: 148; Downloads: 74
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10. A critical appraisal of the use and properties of nickel–titanium dental alloysPetra Močnik, Tadeja Kosec, 2021, review article Abstract: Nickel–titanium (NiTi) archwires are used in dentistry for orthodontic treatment. NiTi alloys have favourable mechanical characteristics, such as superelasticity and shape memory, and are also known as a corrosion-resistant alloy. In specific cases, an archwire could be attacked by certain types of corrosion or wear degradation, which can cause the leaching of metal ions and a hypersensitive response due to increased concentrations of Ni in the human body. A systematic search of the literature retrieved 102 relevant studies. The review paper focuses on three main fields: (i) electrochemical properties of NiTi wires and the effect of different environments on the properties of NiTi wires (fluoride and low pH); (ii) tribocorrosion, a combination of chemical and mechanical wear of the material, and (iii) the biocompatibility of NiTi alloy and its subsequent effect on the human body. The review showed that corrosion properties are affected by microstructure, pH of saliva and the presence of fluorides. A high variation in published results should be, therefore, interpreted with care. The release of nickel ions was assessed using the same unit, showing that the vast majority of metal ions were released in the first few days of exposure, then a stable, steady state was reached. In tribocorrosion studies, the increased concentrations of Ni ions were reported.
Keywords: NiTi alloy, archwires, corrosion, NI ion release
Published in DiRROS: 23.02.2024; Views: 224; Downloads: 69
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