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Abstract: The surface, corrosion and wear properties of new and in vivo exposed nickel titanium (NiTi) and stainless steel (SS) archwires used in orthodontic treatment were investigated. Electrochemical and tribo-electrochemical tests in artificial saliva were performed in order to define corrosion properties and to estimate wear rate of new and in vivo exposed NiTi and SS archwires. The surface chemical analysis of the passive film on the NiTi and SS archwires before and after tribocorrosion tests was performed by Auger Electron Spectroscopy (AES). In vivo exposed NiTi and SS archwires had better electrochemical properties than new archwires due to the protective nature of oral deposits. Total wear and coefficients of friction were higher among in vivo exposed archwires and higher in NiTi archwires in comparison to SS archwires. The estimated thickness of the TiO2 passive film on as-received NiTi is 8 nm, while the passive Cr2O3 film on as-received SS is just 1–2 nm. On in vivo exposed NiTi archwire, a 60–80 nm thick organic film/dental plaque was observed, and on SS, it was thinner, at about 60 nm. This research shows the importance of combining AES with electrochemical testing, to characterize tribocorrosive properties of NiTi and SS orthodontic archwires.
Keywords: archwires, NiTi, stainless steel, wear
Published in DiRROS: 24.08.2023; Views: 278; Downloads: 122
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Abstract: Reinforced concrete structures require continuous monitoring and maintenance to prevent corrosion of the carbon steel reinforcement. In this work, concrete columns with carbon and stainless steel reinforcements were exposed to a real marine environment. In order to monitor the corrosion processes, two types of corrosion probes were embedded in these columns at different height levels. The results from the monitoring of the probes were compared to the actual corrosion damage in the different exposure zones. Electrical resistance (ER) probes and coupled multi-electrodes (CMEs) were shown to be promising methods for long-term corrosion monitoring in concrete. Correlations between the different exposure zones and the corrosion processes of the steel in the concrete were found. Macrocell corrosion properties and the distribution of the separated anodic/cathodic places on the steel in chloride-contaminated concrete were addressed as two of the key issues for understanding the corrosion mechanisms in such environments. The specific advantages and limitations of the tested measuring techniques for long-term corrosion monitoring were also indicated. The results of the measurements and the corrosion damage evaluation clearly confirmed that the tested stainless steels (AISI 304 and AISI 304L) in a chloride-contaminated environment behave significantly better than ordinary carbon steel, with corrosion rates from 110% to 9500% lower in the most severe (tidal) exposure conditions.
Keywords: corrosion in concrete, steel reinforcement, long-term exposure, field exposure, electrical resistance (ER) probes, coupled multi-electrodes
Published in DiRROS: 21.08.2023; Views: 288; Downloads: 168
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Abstract: Refurbishment is one of the most important measures for reducing the environmental impacts of the construction sector in the near future. According to the life cycle assessment (LCA) methodology for buildings, the environmental impacts of refurbishment measures should be assessed within the whole life cycle of the building and reflected in separate modules. However, in practice, refurbishment is often treated as the beginning of a new building life cycle. This leads to difficulties in correctly assessing the environmental impacts for the components that are reused or recycled after the refurbishment. The division of a building’s life cycle into two separate life cycles indicates that the environmental impacts must be divided between the life cycle before and the life cycle after the refurbishment for a correct assessment of the environmental impacts and a calculation of the residual value. We propose a newly developed methodology for calculating the environmental impacts and the residual value of refurbishment measures that also involves a division between life cycles. The new methodology is a combi-nation of already exiting methodologies that are innovatively combined and consists of four sequential steps. In the first step, the input, output and reuse flows between the life cycles before and after the refurbishment are defined. In the second step, the environmental impacts are assessed using the chosen allocation approach (i.e., the cut-off, cut-off with module D, avoided-burden, 50:50 and the product environmental footprint (PEF)). In the third step, a maintenance scenario is implemented according to the selected reference-service-life (RSL) database. In the fourth step, the residual value is estimated. The methodology was tested on selected building components. A sensitivity analysis for different allocation approaches and RSL databases was performed to show how the choice of these parameters can influence the results. The differences between the selected allocation approaches emerge if materials with recycled content are used or if the materials are being recycled or reused at the end of their life cycle. The developed methodology reliably estimates the environmental impacts as well as the residual value of the life cycle before and after the refurbishment. We expect that this research will stimulate practitioners to avoid the negligence of previous environmental flows, bringing scientific consistency to future assessments of refurbishment measures.
Keywords: Life cycle assessment (LCA), refurbishment, allocation approaches, residual value, reference service life (RSL)
Published in DiRROS: 28.07.2023; Views: 359; Downloads: 230
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Abstract: Equipment made of different stainless steels is often used in the hydrometallurgical processing industry. In this study, an electrical resistance sensor was developed for monitoring corrosion in acidic solutions at high temperature. Two types of stainless steel were used as the electrode materials, namely grade 316L stainless steel (EN 1.4404) and grade 2507 duplex stainless steel (EN 1.4410). The materials and sensors were exposed to a 10% H2SO4 solution containing 5000 mg/L of NaCl at various temperatures. Results from the sensors were verified using electrochemical techniques and postexposure examination. Results showed that the microstructure played an important role in the interpretation of corrosion rates, highlighting the importance of using an appropriate stainless steel for the production of sensors. Electrochemical tests and postexposure examination both showed that the grade 2507 had a significantly lower corrosion rate compared to the grade 316L. Under industrial‑process conditions, the results for the grade 2507 sensor were promising with respect to sensor durability and performance, despite the extremely harsh operating environment.
Keywords: stainless steel, hydrometallurgical industry, sulphuric acid, electrical resistance sensor, corrosion
Published in DiRROS: 05.07.2023; Views: 356; Downloads: 192
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Abstract: The responses of the current and the coupled potential to rapid depassivation have been studied on a three-electrode system under open-circuit conditions. Passivated AISI 304 stainless steel in low- and high-conductivity solutions of NaSO has been depassivated with a single, rapid scratch over the small fraction of surface of the working electrode (WE). Single- and dual-WE configurations have been implemented. Once the surface is scratched, the current and potential transients exhibit a delayed maximum and minimum, respectively, in contrast to the outcome of more common potentiostatic scratching experiments. A simple model based on the equivalent circuit has been developed to predict the observed transients and provides clear relations between the features of the transient and the parameters of the electrolyte and the electrodes. The interfacial capacitance of the electrodes’ passive surfaces proves crucial for the shapes of the observed potential and current transients. It is shown that this capacitance temporarily provides the majority of the charge for repassivation under open-circuit conditions. Possible sources of specific discrepancies between the model and the measured transients are indicated.
Keywords: repassivation, open circuit conditions, transient, modelling, interfacial capacitance
Published in DiRROS: 21.06.2023; Views: 354; Downloads: 163
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