1. Susceptibility of X17CrNi16-2 martensitic stainless steel to hydrogen embrittlement after conventional and deep cryogenic heat treatmentMirjam Bajt Leban, Bojan Zajec, Bojan Podgornik, Črtomir Donik, Patricia Jovičević Klug, Miha Hren, Andraž Legat, 2024, original scientific article Abstract: A low carbon/ high chromium martensitic stainless steel, X17CrNi16-2, was heat treated using two different hardening and tempering regimes (1050 ◦ C/480 ◦ C or 980 ◦C/600 ◦C) — promoting either a high strength or high toughness state, respectively and further combined with deep cryogenic treatment (DCT) at 196 ◦C for 24 h. Over recent years DCT has been recognized as a promising technique to improve the properties of steel, predominantly with respect to its tensile strength, toughness and wear resistance. The influence of DCT on the hydrogen embrittlement resistance of martensitic stainless steel has not yet, however, been reported.
A slow strain rate tensile test (SSRT) with simultaneous cathodic hydrogen charging was selected as the method to assess potential susceptibility to hydrogen embrittlement (HE). Relatively low-intensity hydrogen charging, utilizing a constant current density of 0.1 mA/cm2, in a non-corrosive, slightly alkaline buffer solution, led to a clear reduction in the ultimate tensile stress. This reduction, and therefore the HE susceptibility, was more pronounced in the steel with a higher strength (i.e. that subject to the 1050 ◦C/ 480 ◦C heat treatment condition). Furthermore, DCT did not appear to have any impact on the steel’s mechanical properties in the presence of hydrogen. Fractographic analysis showed clear evidence of HE in the hydrogen-charged specimens.
This paper presents results of the SSRT tests and further fractography results, and discusses the impact of conventional and deep cryogenic treatment on HE susceptibility. Keywords: martensitic stainless steel, deep cryogenic treatment, hydrogen embrittlement, slow strain rate tensile test Published in DiRROS: 23.05.2024; Views: 350; Downloads: 331 Full text (17,73 MB) This document has many files! More... |
2. Tuning the long-term corrosion behaviour of biodegradable WE43 magnesium alloy by PEO coatingJulia Nachtsheim, Songyun Ma, Jaka Burja, Barbara Šetina, Bernd Markert, 2023, original scientific article Keywords: long-term degradation, in vitro corrosion mechanisms: biodegradable, magnesium, DMEM fluid, hydrogen evolution, PEO coating Published in DiRROS: 20.05.2024; Views: 321; Downloads: 151 Link to file |
3. Using stable isotopes and major ions to identify recharge characteristics of the Alpine groundwater-flow dominated Triglavska Bistrica RiverLuka Serianz, Sonja Cerar, Polona Vreča, 2021, original scientific article Abstract: Triglavska Bistrica is a typical Alpine river in the north-western part of Slovenia. Its recharge area includes some of the highest peaks in the Julian Alps. The hydrogeological conditions and flow of the river depend largely on groundwater exchange between the karstified aquifer in the carbonate rocks and the intergranular aquifer in the glaciofluvial deposits. The average volume of the river flow is up to several m3/s. In this study, water samples from different locations along the river were analysed for stable isotope ratios of oxygen and hydrogen, major ions, and concentration of tritium activity. The correlation of major ions suggests that the recharge area consists of both limestone and dolomite rocks. The δ18O and δ2H values decrease downstream, implying that the average recharge elevation increases. At the downstream sampling site V-5, located approx. 300 m upstream from the confluence of the Sava Dolinka River, the calculated mean recharge altitude is estimated to be 1,996 m. Keywords: groundwater, oxygen and hydrogen isotopes, hydrogeochemistry, recharge area, Alpine aquifer, Slovenia Published in DiRROS: 09.03.2022; Views: 1147; Downloads: 387 Full text (3,01 MB) |
4. Surface structure-activity relationships of Cu/ZnGaO [sub] x catalysts in low temperature water-gas shift (WGS) reaction for production of hydrogen fuelVenkata D. B. C. Dasireddy, Karmina Rubin, Andrej Pohar, Blaž Likozar, 2020, original scientific article Keywords: syngas, hydrogen, ▫$Cu/ZnGaO_x$▫ catalyst, water-gas shift, WGS, steam reforming reactions, fuel cell systems Published in DiRROS: 12.03.2020; Views: 2220; Downloads: 904 Full text (2,50 MB) This document has many files! More... |