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1.
Monitoring copper corrosion in bentonite by means of a coupled multi-electrode array
Tadeja Kosec, Miha Hren, Andraž Legat, 2017, original scientific article

Abstract: This work focuses in monitoring the corrosion processes on copper in a slightly saline environment under oxic conditions, which simulated the first part of high-radioactive waste disposal in bentonite. Besides coupled multi-electrode arrays (CMEA), also electrochemical impedance spectroscopy measurements were implemented. It was expected that this combination of methods would define the general corrosion rate, as well as the spatio-temporal evolution of anodic and cathodic processes. Anodic currents measured by CMEA showed that the corrosion rates decreased with time. Since maximum anodic activity switched between the electrodes, this situation was not individually valid for all the electrodes. At the end of exposure, different spectroscopic techniques were applied in order to identify the modes of corrosion and types of corrosion products. Uneven general corrosion without evident pits was indicated.
Keywords: copper, bentonite, saline groundwater, coupled multi electrode array, corrosion
Published in DiRROS: 14.08.2024; Views: 50; Downloads: 74
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2.
Groundwater is a hidden global keystone ecosystem
Mattia Saccò, Stefano Mammola, Florian Altermatt, Roman Alther, Rossano Bolpagni, Anton Brancelj, David Brankovits, Cene Fišer, Vasilis Gerovasileiou, Špela Borko, Maja Zagmajster, 2024, review article

Abstract: Groundwater is a vital ecosystem of the global water cycle, hosting unique biodiversity and providing essential services to societies. Despite being the largest unfrozen freshwater resource, in a period of depletion by extraction and pollution, groundwater environments have been repeatedly overlooked in global biodiversity conservation agendas. Disregarding the importance of groundwater as an ecosystem ignores its critical role in preserving surface biomes. To foster timely global conservation of groundwater, we propose elevating the concept of keystone species into the realm of ecosystems, claiming groundwater as a keystone ecosystem that influences the integrity of many dependent ecosystems. Our global analysis shows that over half of land surface areas (52.6%) has a medium-to-high interaction with groundwater, reaching up to 74.9% when deserts and high mountains are excluded. We postulate that the intrinsic transboundary features of groundwater are critical for shifting perspectives towards more holistic approaches in aquatic ecology and beyond. Furthermore, we propose eight key themes to develop a science-policy integrated groundwater conservation agenda. Given ecosystems above and below the ground intersect at many levels, considering groundwater as an essential component of planetary health is pivotal to reduce biodiversity loss and buffer against climate change.
Keywords: groundwater, keystone ecosystem, surface-subterranean connectivity
Published in DiRROS: 07.08.2024; Views: 108; Downloads: 109
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3.
A new genus and two new species of cave-dwelling cyclopoids (Crustacea, Copepoda) from the epikarst zone of Thailand and up-to-date keys to genera and subgenera of the Bryocyclops and Microcyclops groups
Chaichat Boonyanusith, La-orsri Sanoamuang, Anton Brancelj, 2018, original scientific article

Abstract: Two obligate cave-dwelling species of cyclopoid copepods (Copepoda, Cyclopoida) were discovered inside caves in central Thailand. Siamcyclops cavernicolus gen. et sp. nov. was recognised as a member of a new genus. It resembles Bryocyclops jankowskajae Monchenko, 1972 from Uzbekistan (part of the former USSR). It differs from it by (1) lack of pointed triangular prominences on the intercoxal sclerite of the fourth swimming leg, (2) mandibular palp with three setae, (3) spine and setal formulae of swimming legs 3.3.3.2 and 5.5.5.5, respectively, and (4) specific shape of spermatophore. Metacyclops thailandicus sp. nov. resembles M. cushae Reid, 1991 from Louisiana (USA). It differs from it by (1) distal segment of the endopod of the fourth swimming leg with one apical spine, (2) the fifth swimming legs with one broad segment, (3) the spine formula of the distal segment of the exopod of the swimming legs 3.4.3.3, and (4) well developed anal operculum reaching articulation with caudal rami. Detailed descriptions of the habitats of the new species and up-to-date keys to the genera and subgenera of the Bryocyclops and Microcyclops groups are provided, along with an updated list of obligate groundwater species of Copepoda in Southeast Asia.
Keywords: Siamcyclops cavernicolus gen. et sp. nov., Metacyclops thailandicus sp. nov., stygobionts, groundwater environment, epikarstic drip
Published in DiRROS: 01.08.2024; Views: 110; Downloads: 139
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4.
Patterns in invertebrate drift from an alpine karst aquifer over a one year period
Maja Opalički, 2015, original scientific article

Abstract: Patterns in invertebrate drift in the alpine karst Lipnik spring (Julian Alps, Slovenia) were investigated over a one year period. Monthly samplings of one permanent and two temporary springs, and one sampling of a spring brook benthos, yielded 23 Copepoda and Ostracoda species. More species (12) were found in the permanent than in the temporary springs (8 and 7), Elaphoidella phreatica (Sars, 1862) being the most frequent in all of them. No correlation was observed between precipitation and drift densities or the numbers of species in the permanent spring. In the temporary springs there were correlations between precipitation and the Shannon diversity index, equitability and changes in community composition. Conductivity of the water was the only physical parameter in the springs that correlated with precipitation. Species accumulation curves reached the asymptotes in all the springs but not for benthos. 
Keywords: alpine karst aquifer, groundwater, drift
Published in DiRROS: 29.07.2024; Views: 122; Downloads: 67
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5.
The groundwater invertebrate fauna of the Channel Islands
Anton Brancelj, Lee R. F. D. Knight, Bernd Hänfling, Colin Cheney, 2015, original scientific article

Abstract: The Channel Islands are a small archipelago of British dependencies just off the coast of Normandy at the western end of the English Channel. There were only three records for stygobitic Crustacea [Niphargus fontanus Bate, 1859 and N. kochianus Bate, 1859 from Jersey and N. aquilex Schiődte, 1855 from Guernsey] from the archipelago and no systematic survey has been carried out of the islands for their groundwater fauna till present. Recently sampling was carried out in wells, boreholes and springs on the four largest islands, Jersey, Guernsey, Alderney and Sark during February 2012. Niphargus aquilex was widespread across all four islands and did not appear to be restricted to any particular geology. Niphargus ladmiraulti was present in large numbers in a single borehole on Jersey, the first record of this species from the archipelago. Niphargus kochianus was collected from two sites on Alderney and the syncarid Antrobathynella stammeri (Jakobi, 1954) from two sites on the west coast of Jersey. The records for A. stammeri are new for the Channel Islands and possibly represent the first records of this species from the French bio-geographical area. The presence of N. fontanus on the islands was not confirmed. Several species of stygophilic Cyclopoida were also recorded during the survey along with epigean freshwater invertebrate taxa, which were mostly present in springs and shallow wells close to surface streams.
Keywords: fauna, groundwater, stygobitic
Published in DiRROS: 26.07.2024; Views: 135; Downloads: 102
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6.
Two new species of parastenocaris (Copepoda, Harpacticoida) from a hyporheic zone and overview of the present knowledge on Stygobiotic Copepoda in Vietnam : historical overview and new data
Ngoc-Son Tran, Mau Trinh-Dang, Anton Brancelj, 2021, original scientific article

Abstract: The number of freshwater species belonging to the genus Parastenocaris reported from ten countries of Southeast Asia is quite limited. Only two species have been reported so far from freshwater habitats there, compared to over 290 described species of the family Parastenocarididae worldwide. During the first study of the hyporheic zone of two small rivers in central Vietnam, two new species of the family Parastenocarididae were collected, Parastenocaris sontraensis sp. nov. and Parastencaris vugiaensis sp. nov. Both were collected from the gravel bar along the rivers (Suoi Da and Vu Gia river) using the Karaman–Chappuis method. Both the new species belong to the brevipes group of the genus Parastenocaris Kessler, 1913 sensu Lang (1948), and Reid (1995). Parastenocaris sontraensis sp. nov. is similar to P. hinumaensis Kikuchi, 1970 and Parastenocaris jane Karanovic, 2006 in the brevipes-group. Parastenocaris sontraensis sp. nov. differs from both Parastenocaris species by (i) Exp P3 with three segments in the male, (ii) caudal rami with seven setae, and (iii) caudal rami about 2.4 times as long as wide. Parastencaris vugiaensis sp. nov. can be distinguished from its congeners by the unique combination of the following characters: (i) the elliptical shape of caudal rami, (ii) apical seta (V) with bulbous base, and (iii) anal operculum extends beyond the end of anal somite. Until now, 14 stygobiotic species of Copepoda have been recorded in Vietnam (including two new species in this paper), which is relatively few compared with nearby Thailand with 25 species. Short comments on other stygobiotic Copepoda from Vietnam are added.
Keywords: Southeast Asia, groundwater fauna, hyporheic zone, Copepoda, new species, taxonomy
Published in DiRROS: 19.07.2024; Views: 116; Downloads: 97
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7.
A new obligate groundwater species of Asellus (Isopoda, Asellidae) from Iran
Mohammad Javad Malek-Hosseini, Jure Jugovic, Yaser Fatemi, Matjaž Kuntner, Rok Kostanjšek, Christophe J. Douady, Florian Malard, 2022, original scientific article

Abstract: With only 43 described stygobionts and only two isopod species the obligate groundwater fauna of Iran, a vast country with over 10% of limestone surface, is inadequately known. Here, we report the discovery of Asellus ismailsezarii sp. nov. from Zagros mountains, the first eyeless and depigmented asellid isopod from Iran. The new species is morphologically similar to Asellus monticola Birstein, 1932, but it is eyeless and fully depigmented, has a slightly curved pereopod IV and does not bear any setae on proximal margins of exopodite of pleopods IV and V. Species phylogenetic relationships using original and datamined mitochondrial DNA and nuclear rDNA, and estimation of molecular divergences with other Asellus species, suggest that A. ismailsezarii sp. nov. is sister to a larger clade that also contains the European A. aquaticus species complex. Surface populations of Asellus have colonized groundwater at multiple occasions and localities, both in Europe and Asia, giving rise to species and subspecies that have evolved troglomorphisms, such as depigmentation and loss of eyes. Of the 37 formally described species and subspecies of Asellus, 15 are from groundwater, including A. ismailsezarii sp. nov. We predict that many more obligate groundwater Asellus taxa are yet to be discovered in Asia.
Keywords: Asia, groundwater, molecular phylogeny, taxonomy, troglomorphy
Published in DiRROS: 16.07.2024; Views: 156; Downloads: 130
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8.
Hydrogeochemical and isotopic characterisation of the Učja Aquifer, NW Slovenia
Petra Žvab Rožič, 2024, original scientific article

Abstract: The groundwater characteristics of the Učja aquifer were investigated using geochemical and isotopic data. The water discharge and physico-chemical properties of the groundwater and the Učja River reflect the climate that is characteristic of the area. The mixed snow/rainfall regime is characteristic for the Učja Valley, with the highest discharges appearing during the spring snowmelt and autumn precipitation, and the lowest discharges in the winter and especially summer months. The temperature of the groundwater and the Učja River is lower in winter and higher in summer. The specific electrical conductivity values indicate a very permeable carbonate aquifer. Higher conductivity values were observed in spring and autumn at all sampling sites, which is related to snowy and rainy periods. The groundwater from the Učja aquifer indicates a uniform type of water (Ca-Mg-HCO3), w it h Ca2+, Mg2+ and HCO3– the most abundant ions. Differences in Ca2+ and Mg2+ concentrations and in the Mg2+/Ca2+molar ratio between sampling sites were observed. Those springs with lower Mg2+ and lower Mg2+/Ca2+ molar ratios indicate limestone recharge areas, and those springs with higher Mg2+ and molar ratios indicate interaction with the dolomite hinterland. The pH values confirm alkaline waters characteristic of carbonate aquifers. The hydrogen (δ2H) and oxygen (δ18O) isotope values suggest the main source of water is from precipitation from a complex mixing of maritime and continental air masses. An altitude isotopic effect is observed with minor δ18O and δ2H depletion at higher altitude sampling sites compared to those springs at lower altitudes. The altitude isotopic effect is most prominent in spring. The δ13CDIC values indicate the dissolution of carbonates and the degradation of organic matter.
Keywords: groundwater, hydrogeochemistry, isotopes, cross-border aquifer, Učja Valley
Published in DiRROS: 09.07.2024; Views: 142; Downloads: 103
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9.
Two new species of Elaphoidella (Copepoda, Harpacticoida) from subterranean waters in Northeast Thailand, with a record of a gynandromorphic specimen and an up-to-date key to Elaphoidella species from Southeast Asia
Chaichat Boonyanusith, Anton Brancelj, La-orsri Sanoamuang, 2024, original scientific article

Abstract: Two new species of copepods of the genus Elaphoidella Chappuis, 1929 were discovered in a cave and a spring in northeastern Thailand. The first species, E. phuphamanensis sp. nov., belongs to species-group VII sensu Lang. It is most similar to E. turgisetosa Petkovski, 1980 in the armament of the male third exopod of the fourth swimming leg and the shape and armament of the fifth swimming leg in both sexes. However, it is easily distinguished from other congeners by the segmentation of the first swimming leg, the endopod of the fourth swimming leg, and the armature of the third exopod of swimming legs 2–4 in both sexes. The second species, E. propecabezasi sp. nov., is located in species-group I sensu Lang, where the male does not have a transformed seta on the third exopod of the fourth swimming leg and the female fifth swimming leg has four baseoendopodal robust setae, unequal in length. It is most similar to E. cabezasi Petkovski, 1982 and E. paraaffinis Watiroyram, Sanoamuang and Brancelj, 2017 in having the same armature formula as endopods 1–2 of female swimming legs 1–4. However, the ornamentation of the anal operculum, the shape of the caudal ramus, and the armature of the fifth swimming leg in both sexes distinguish them from each other. A rare gynandromorphic specimen of E. propecabezasi sp. nov. was recorded, and a revised key to Elaphoidella species in Southeast Asia is provided.
Keywords: cave-dwelling copepods, endemic distribution, groundwater habitats, intersex, morphology, zoology, Southeast Asia
Published in DiRROS: 17.05.2024; Views: 295; Downloads: 425
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10.
Microplastics in groundwater: pathways, occurrence, and monitoring challenges
Elvira Colmenarejo Calero, Manca Kovač Viršek, Nina Mali, 2024, original scientific article

Abstract: Microplastics (MPs), defined as plastic particles measuring less than 5 mm, are considered an emerging pollutant. Their presence in the water cycle and their interaction with ecological processes pose a significant environmental threat. As groundwater (GW) represents the primary source of drinking water, monitoring MPs in GW and investigating their potential sources and pathways is of urgent importance. This article offers a comprehensive overview of the primary contamination pathways of MPs from surface water, seawater, and soil into the GW. Moreover, it presents an examination of the occurrence of MPs in GW and identifies the challenges associated with their monitoring in GW. This study also discusses the difficulties associated with comparing research results related to MPs in GW, as well as indicating the need for implementing standardised techniques for their sampling and detection. On the basis of our experience and the literature review, we highlight the importance of understanding the specific hydrogeological and hydrogeographic conditions, collecting representative samples, using sampling devices with comparable specifications and comparable laboratory techniques for MP identification, and preventing contamination at all stages of the monitoring process. This review offers valuable insights and practical guidelines on how to improve the reliability and comparability of results between studies monitoring MPs in GW.
Keywords: microplastics, groundwater, sampling, monitoring, aquifer, borehole
Published in DiRROS: 15.05.2024; Views: 243; Downloads: 199
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