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Title:The effect of side chain length on the mesomorphic properties of ferroelectric nematogens
Authors:ID Podoliak, Natalia (Author)
ID Cigl, Martin (Author)
ID Golub, Pavlo (Author)
ID Sterle, Anej (Author)
ID Lavrič, Marta, Institut "Jožef Stefan" (Author)
ID Sebastián Ugarteche, Nerea, Institut "Jožef Stefan" (Author)
ID Mertelj, Alenka, Institut "Jožef Stefan" (Author)
ID Cordoyiannis, George, Institut "Jožef Stefan" (Author)
ID Novotná, Vladimíra (Author)
Files:URL URL - Source URL, visit https://pubs.rsc.org/ma/article/doi/10.1039/d6ma00897f/1291952/The-effect-of-side-chain-length-on-the-mesomorphic
 
.pdf PDF - Presentation file, download (2,67 MB)
MD5: 93B4EED2295CF28A79248003B6019B33
 
Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo IJS - Jožef Stefan Institute
Abstract:The discovery of ferroelectric nematic phase opened new directions in the field of soft matter chemistry and physics. In this paper, we have modified a previously reported ferroelectric nematogen based on molecular structure with dimethylamino-terminated part. We have prepared two new homologues by prolonging a side chain and investigated the effect of its length on the mesomorphic properties. While previously reported homologues exhibited a direct phase transition from the isotropic (Iso) to the ferroelectric nematic phase (NF), for prolonged alkyl chain there is a narrow nematic phase (N) in between. For new compounds, we have established their mesomorphic and material properties. We have confirmed ferroelectricity of the NF phase by the polarization, SHG signal and permittivity. Finally, we have compared these parameters with respect to the side-chain length and discussed new effects, discovered for prolonged homologues due to the presence of an additional N phase.
Keywords:ferroelectricity, nematic phase, nematogens
Publication status:Published
Publication version:Version of Record
Submitted for review:17.06.2026
Article acceptance date:10.08.2026
Publication date:11.08.2026
Publisher:The Royal Society of Chemistry
Year of publishing:2026
Number of pages:str. 1-11
Numbering:Vol. 7, iss. 16
Source:Združeno kraljestvo
PID:20.500.12556/DiRROS-32341 New window
UDC:53
ISSN on article:2633-5409
DOI:10.1039/d6ma00897f New window
COBISS.SI-ID:289116419 New window
Copyright:© 2026 The Author(s).
Note:Nasl. z nasl. zaslona; Soavtorji iz Slovenije: Anej Sterle, Marta Lavrič, Alenka Mertelj; Opis vira z dne 27. 8. 2026;
Pub. date in DiRROS:07.09.2026
Views:36
Downloads:17
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Record is a part of a journal

Title:Materials advances
Publisher:Royal Society of Chemistry
ISSN:2633-5409
COBISS.SI-ID:56274691 New window

Document is financed by a project

Funder:Czech Science Foundation
Project number:24-10247K

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P1-0192-2022
Name:Svetloba in snov

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P1-0125-2022
Name:Fizika kvantnih in funkcionalnih materialov

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:L1-70060-2026
Name:Napredni oblikovno programabilni aktuatorji na osnovi polimerno-dispergiranih tekočekristalnih elastomerov

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:N2-0367-2024
Name:Večnamenski hibridni materiali s kontroliranimi feroičnimi lastnostmi

Funder:Other - Other funder or multiple funders
Project number:IT1979-26
Name:Basque Government Project

Funder:Ministerio de Ciencia, Innovacion y Universidades
Project number:PID2023-150255NB-I00

Licences

License:CC BY-NC 4.0, Creative Commons Attribution-NonCommercial 4.0 International
Link:http://creativecommons.org/licenses/by-nc/4.0/
Description:A creative commons license that bans commercial use, but the users don’t have to license their derivative works on the same terms.
Licensing start date:11.08.2026
Applies to:VoR

Secondary language

Language:Slovenian
Keywords:feroelektričnost, nematska faza, nematogeni


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