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Title:Development of the geoelectrical laboratory of the Geological Survey of Slovenia : complex electrical signatures of the Mežica Pb-Zn mine waste material and impacted stream sediments
Authors:ID Placencia-Gómez, Edmundo (Author)
ID Gaberšek, Martin (Author)
ID Maineult, Alexis (Author)
ID Bücker, Matthias (Author)
ID Leroy, Philippe (Author)
ID Gosar, Mateja (Author)
ID Novak, Andrej (Author)
ID Bizjak, Nejc (Author)
Files:.pdf PDF - Presentation file, download (10,98 MB)
MD5: AC59A17F5B5C36E889721E5E23004A96
 
Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo GeoZS - Geological Survey of Slovenia
Abstract:Environmental geophysical investigations require controlled laboratory experiments to better understand the relationships between the parameters measured in the field and complex physicochemical processes occurring in the subsurface. In this work, we introduce the Geoelectrical Laboratory (GEL) of the Geological Survey of Slovenia. A typical application of the spectral induced polarization (SIP) method, focussing on the detection of electron-conducting minerals disseminated in geologic material is presented. This is demonstrated by the close relationship between the polarization peak values (�′′�), and chargeability values associated with the second peak (�2) of polarization spectra estimated from a double Cole-Cole fit, and the metal content, either by the mass % concentration of the ore mineral or the chemical composition (Pb, Zn and Fe) estimated by XRF measurements. We illustrate this for synthetic mixtures of quartz sand and pure Pb-Zn ore particles from the Mežica mine (Slovenia), the Mežica Pb-Zn mine waste material (K-material) and sediments collected from streams near the waste deposits (S-material). These results evidence promising capabilities of the SIP method for in-situ detection of metallic particles, both within the mine waste deposits and sediments in the surrounding areas. However, further SIP investigations are needed in a larger number of material samples along with geochemical, mineralogical, and granulometric data to refine the links of polarization and chargeability to both the mass content of ore and the specific geochemical composition of the materials under investigation, as well as to determine the inf luence of the natural geological materials that constitute both the host rock of Pb-Zn ore and the surrounding sediments (e.g., carbonates).
Keywords:induced polarization, chargeability, mine waste, sediments, Mežica, Slovenia
Publication status:Published
Publication version:Version of Record
Publication date:25.02.2026
Year of publishing:2026
Number of pages:str. 7-34
Numbering:vol. 69, no. 1
UDC:504.5
ISSN on article:0016-7789
DOI:10.5474/geologija.2026.001 New window
COBISS.SI-ID:271410947 New window
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Publication date in DiRROS:06.07.2026
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Record is a part of a journal

Title:Geologija
Shortened title:Geologija
Publisher:Geološki zavod Slovenije
ISSN:0016-7789
COBISS.SI-ID:5636866 New window

Document is financed by a project

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P1-0020-2020
Name:Podzemne vode in geokemija

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P1-0011-2019
Name:Regionalna geologija

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:J7-60124-2025
Name:Celostni pristop k preučevanju vplivov ekstremnih vremenskih dogodkov na procese na Zemljinem površju (ExtremEarth)

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Title:Razvoj geoelektričnega laboratorija Geološkega zavoda Slovenije : kompleksni električni signali Pb-Zn odlagališč rudarskih odpadkov Mežiškega rudišča in potočnih sedimentov
Abstract:Okoljske geofizikalne raziskave je za boljše razumevanje odnosov med parametri, merjenimi na terenu, in kompleksnimi fizikalno-kemičnimi procesi v podpovršju treba dopolniti z laboratorijskimi eksperimenti. V prispevku predstavljamo Geoelektrični laboratorij (GEL) Geološkega zavoda Slovenije. Predstavljena je tipična uporaba spektralne inducirane polarizacije (SIP), ki se osredotoča na zaznavanje elektronsko-prevodnih mineralov, ki so razpršeni v geološkem materialu. To je prikazano s tesno povezavo med vrednostmi polarizacijskih viškov (�′′�) in vrednostmi mer polarizivnosti, povezanimi z drugim viškom (�2) polarizacijskega spektra, ocenjenega iz dvojnega Cole-Cole modela, ter vsebnostjo kovin, določeno kot masna koncentracija rudnega minerala ali kot kemična sestava (Pb, Zn in Fe), izmerjena z XRF. Tovrstne odnose prikazujemo za sintetične mešanice kremenovega peska in Pb-Zn rude iz Mežiškega rudnika (Slovenija), za Pb-Zn rudarske odpadke iz Mežiškega rudnika (K-material) in sedimente, vzorčene v potokih v neposredni bližini odlagališč (S-material). Rezultati kažejo obetavno možnost uporabe SIP metode za in-situ detekcijo kovinskih delcev, tako znotraj odlagališč rudarskih odpadkov kot v potočnih sedimentih v njihovi okolici. Za izboljšanje povezav med polarizacijo in mero polarizivnosti ter masnim deležem rudnih mineralov in specifično geokemično sestavo preiskovanega materiala, kot tudi za opredelitev vpliva naravnih geoloških materialov (npr. karbonatov), so potrebne nadaljnje SIP, geokemične, mineraloške in granulometrične raziskave večjega števila vzorcev.
Keywords:inducirana polarizacija, mera polarizivnosti, rudarski odpadki, sediment, Mežica, Slovenija


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