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Title:Introducing EIS circuit elements in SPICE simulator environment
Authors:ID Kunaver, Matevž (Author)
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URL URL - Source URL, visit https://ojs.midem-drustvo.si/index.php/InfMIDEM/article/view/2144
 
URL URL - Source URL, visit https://ojs.midem-drustvo.si/index.php/InfMIDEM/article/view/2144
 
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Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo MIDEM - Society for Microelectronics, Electronic Components and Materials
Abstract:This study introduces hypothetical circuit elements, specifically the Constant Phase Element (CPE) and Zeroth-Order Approximation of a RC Circuit (ZARC), into the SPICE circuit simulation environment to enhance Electrochemical Impedance Spectroscopy (EIS) analysis. EIS, a critical method for understanding electrochemical processes in fields such as fuel cell analysis, corrosion studies, and biomaterials, relies on fitting measured impedance curves to Equivalent Electrical Circuit (EEC) models. However, existing approaches require expert knowledge and significant mathematical effort, limiting automation. By integrating CPE and ZARC into SPICE, this work bridges the gap between EIS analysis and advanced automatic circuit design methodologies, enabling efficient model selection and parameter determination. Experimental results demonstrate the accuracy of the implemented elements through a series of case studies, evaluated using Sheppard’s criteria function. This integration marks a significant step toward automated EIS model fitting and optimization, with potential implications for advancing electrochemical and materials research.
Keywords:electrochemical impedance spectroscopy, circuit simulators, hypothetical circuit elements, equivalent electronic circuits
Publication status:Published
Publication version:Version of Record
Publication date:01.01.2025
Year of publishing:2025
Number of pages:str. 95-102
Numbering:Vol. 55, no. 2
PID:20.500.12556/DiRROS-30224 New window
UDC:004.43
ISSN on article:0352-9045
DOI:10.33180/InfMIDEM2025.203 New window
COBISS.SI-ID:247998211 New window
Note:Besedilo v angl.;
Publication date in DiRROS:18.06.2026
Views:140
Downloads:155
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Record is a part of a journal

Title:Informacije MIDEM : časopis za mikroelektroniko, elektronske sestavne dele in materiale
Shortened title:Inf. MIDEM
Publisher:Strokovno društvo za mikroelektroniko, elektronske sestavne dele in materiale
ISSN:0352-9045
COBISS.SI-ID:1220612 New window

Document is financed by a project

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P2-0246-2019
Name:ICT4QoL - Informacijsko komunikacijske tehnologije za kakovostno življenje

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Title:Vpeljava elemementov EIS v SPICE simlator vezij
Abstract:Ta študija uvaja hipotetične vezne elemente, specifično konstantnofazni element (CPE) in ničelni red približka RC vezja (ZARC), v simulacijsko okolje SPICE za izboljšanje analize elektrokemijske impedančne spektroskopije (EIS). EIS, ključna metoda za razumevanje elektrokemijskih procesov na področjih, kot so analiza gorivnih celic, študije korozije in biomateriali, temelji na ujemanju izmerjenih impedančnih krivulj z modeli ekvivalentnih električnih vezij (EEC). Obstoječi pristopi zahtevajo strokovno znanje in znatno matematično delo, kar omejuje avtomatizacijo. Z integracijo CPE in ZARC v SPICE to delo premošča vrzel med analizo EIS in naprednimi metodologijami samodejne zasnove vezij, kar omogoča učinkovito izbiro modelov in določanje parametrov. Eksperimentalni rezultati potrjujejo natančnost implementiranih elementov skozi serijo študij primerov, ocenjenih s pomočjo Sheppardove funkcije kriterijev. Ta integracija predstavlja pomemben korak proti avtomatiziranemu prilagajanju in optimizaciji modelov EIS, z možnimi vplivi na napredek raziskav na področju elektrokemije in materialov
Keywords:elektrokemična impedančna spektroskopija, simulatorji vezij, hipotetični elementi vezja, ekvivalentna električna vezja


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