| Title: | Acetylacetone : metal complexes and keto-enol tautomerism – which tautomer is more/less stable? |
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| Authors: | ID Ponikvar-Svet, Maja, Institut "Jožef Stefan" (Author)
ID Edwards, Kathleen F. (Author)
ID Liebman, Joel F. (Author) |
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| Files: |  URL - Source URL, visit https://acsi-journal.eu/index.php/ACSi/article/view/8870
 PDF - Presentation file, download (415,95 KB)
MD5: B5F8AA2FAF63A74420D02D83834F2596
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| Language: | English |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: |  IJS - Jožef Stefan Institute
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| Abstract: | Tautomerism is a fundamental concept that studies the transfer of a proton between two constitutional isomers, i.e. keto and enol tautomers, where the enol tautomers are usually less stable than the corresponding carbonyl compound. However, this is not the case with acetylacetone. This article discusses two rapidly inter-converting tautomeric forms of acetylacetone, the archetypal (and now textbook) example of tautomerism in organic chemistry from a thermochemical perspective. |
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| Keywords: | keto-enol, acetylacetone |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Submitted for review: | 28.06.2024 |
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| Publication date: | 13.03.2025 |
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| Publisher: | Slovensko kemijsko društvo |
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| Year of publishing: | 2026 |
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| Number of pages: | str. 31-38 |
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| Numbering: | Vol. 73, no. 1 |
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| Source: | Slovenija |
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| PID: | 20.500.12556/DiRROS-29108  |
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| UDC: | 54 |
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| ISSN on article: | 1580-3155 |
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| DOI: | 10.17344/acsi.2024.8870 |
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| COBISS.SI-ID: | 275841283 |
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| Copyright: | Copyright (c) 2025 Maja Ponikvar-Svet, Kathleen F. Edwards, Joel F. Liebman |
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| Note: | Nasl. z nasl. zaslona;
Opis vira z dne 20. 4. 2026;
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| Publication date in DiRROS: | 21.04.2026 |
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| Views: | 67 |
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| Downloads: | 45 |
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