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Title:Study of thermal decomposition of ▫$(Ba_{0.7}Ca_{0.3})TiO_3 and Ba(Zr_{0.2}Ti_{0.8})O_3$▫ xerogels and thin films
Authors:ID Konsago, Sabi William, Institut "Jožef Stefan" (Author)
ID Birmančević, Dean, Institut "Jožef Stefan" (Author)
ID Cilenšek, Jena, Institut "Jožef Stefan" (Author)
ID Kmet, Brigita, Institut "Jožef Stefan" (Author)
ID Žiberna, Katarina, Institut "Jožef Stefan" (Author)
ID Malič, Barbara, Institut "Jožef Stefan" (Author)
Files:URL URL - Source URL, visit https://acsi-journal.eu/index.php/ACSi/article/view/9607
 
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MD5: 6B4A097437939B56FE580BDE306A628C
 
Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo IJS - Jožef Stefan Institute
Abstract:Understanding the thermal decomposition and perovskite phase crystallization enables the design of the desired microstructure of BaTiO3-based thin films prepared by chemical solution deposition. We prepared xerogels from (Ba0.7Ca0.3)TiO3 (BCT) and Ba(Zr0.2Ti0.8)O3 (BZT) coating solutions, as well as BCT and BZT thin films, to investigate their thermal decomposition. The oxycarbonates, formed during the heating of BCT and BZT xerogels, are fully decomposed at 780 °C and 720 °C, respectively. The thermal decomposition of carbonate residues in BCT and BZT thin films is completed at 750 °C and 700 °C, respectively. The approximately 120 nm thick BCT and BZT films annealed at 850 °C crystallize in the perovskite phase.
Keywords:thermal decomposition, thin films, xerogels
Publication status:Published
Publication version:Version of Record
Submitted for review:08.11.2025
Publication date:22.02.2026
Publisher:Slovensko kemijsko društvo
Year of publishing:2026
Number of pages:str. 54-61
Numbering:Vol. 73, no. 1
Source:Slovenija
PID:20.500.12556/DiRROS-28631 New window
UDC:620.1/.2
ISSN on article:1580-3155
DOI:10.17344/acsi.2025.9607 New window
COBISS.SI-ID:273144579 New window
Copyright:Copyright (c) 2026 Sabi William Konsago, Dean Birmančević, Jena Cilenšek, Brigita Kmet, Katarina Žiberna, Barbara Malič
Note:Nasl. z nasl. zaslona; Opis vira z dne 23. 3. 2026;
Publication date in DiRROS:26.03.2026
Views:170
Downloads:91
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Record is a part of a journal

Title:Acta chimica slovenica
Shortened title:Acta chim. slov.
Publisher:Slovensko kemijsko društvo, = Slovenian Chemical Society
ISSN:1580-3155
COBISS.SI-ID:21870085 New window

Document is financed by a project

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P2-0105-2022
Name:Multifunkcijski materiali in naprave: od kvantnega do makro nivoja

Funder:ARIS - Slovenian Research and Innovation Agency
Funding programme:Young Researcher program

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:22.02.2026
Applies to:VoR

Secondary language

Language:Slovenian
Abstract:Razumevanje termičnega razpada in kristalizacije perovskitne faze omogoča načrtovanje mikrostrukture tankih plasti na osnovi BaTiO3, pripravljenih s sintezo v raztopini. Iz raztopin prekurzorjev (Ba0.7Ca0.3)TiO3 (BCT) in Ba(Zr0.2Ti0.8)O3 (BZT) smo pripravili ustrezna kserogela s sušenjem pri 200 °C in tanke plasti BCT in BZT z nanašanjem na podlage z metodo vrtenja. Termični razpad organskih skupin v kserogelih poteče preko oksikarbonatnih skupin, ki razpadejo šele po segrevanju pri temperaturah 780 °C (BCT) oziroma 720 °C (BZT). V tankih plasteh BCT in BZT po segrevanju pri 750 °C oziroma 700 °C na zaznamo več sledov ogljikovih faz. Približno 120 nm debele plasti BCT in BZT kristalizirajo v perovskitni fazi po segrevanju pri 850 °C.
Keywords:termični razpad, tanke plasti, kserogeli


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