| Title: | Alkali-activated materials from diverse solid precursors : structural, mechanical and radiological properties |
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| Authors: | ID Mladenović Nikolić, Nataša (Author)
ID Ivanović, Marija (Author)
ID Nenadović, Snežana B. (Author)
ID Potočnik, Jelena (Author)
ID Dolenec, Sabina (Author)
ID Bučevac, Dušan (Author)
ID Kandić, Aleksandar (Author)
ID Kljajević, Ljiljana (Author) |
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| Files: |  URL - Source URL, visit https://doi.org/10.3390/gels12030200
 PDF - Presentation file, download (13,63 MB)
MD5: A18239F62498D3696F977AEA927AF317
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| Language: | English |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: |  ZAG - Slovenian National Building and Civil Engineering Institute
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| Abstract: | This study investigates the gel characteristics of alkali-activated materials (AAMs) synthesized using wood ash (WA), and metakaolin (MK) as solid precursors. The research explores the influence of precursor type and sodium hydroxide (NaOH) concentrations in the alkali activator solution on the resulting physicochemical, microstructural, mechanical, and radiological properties of gels. The alkaline activators were prepared by mixing sodium hydroxide solutions (6 M and 12 M) with a sodium silicate (water glass) solution at a volume ratio of 1.5. The physicochemical characteristics of raw materials and AAMs were thoroughly analyzed using X-ray fluorescence (XRF), Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM) with EDS elemental mapping. FTIR analysis confirmed the formation of an amorphous gels geopolymer network. XRD revealed the presence of characteristic crystalline phases (quartz, calcite) within an amorphous matrix. Mechanical properties, such as compressive strength, depended on precursor type and alkali molarity: metakaolin (12 M) reached ~14 MPa, while wood ash showed ~4 MPa (6 M) and ~0.5 MPa (12 M) due to high CaO, low Si and Al, and unfavorable SiO2/Al2O3 (5.71) and Na2O/Al2O3 (3.19) ratios. Furthermore, this research estimates radiological doses by quantifying radionuclide content via gamma-spectrometry. Alkali activation significantly reduced radiological haz- ard parameters, with radium equivalent activity (Raeq) decreasing to 238.0 Bq/kg and the external hazard index (Hex) to 0.643 for A12MK, while the annual effective dose rate for A12WA was only 0.265 nSv/y-all values remaining well below the recommended safety limit of 370 Bq/kg (≤1 mSv/y). The decrease in activity concentration index (Iγ), Raeq, and Hex with increasing NaOH concentration indicates effective radionuclide immobilization within the geopolymer matrix, confirming the suitability of these alkali-activated materials for safe use in construction from a radiation protection perspective. |
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| Keywords: | wood ash, metakaolin, alkali-activated materials, radionuclides |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Publication date: | 27.02.2026 |
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| Publisher: | MDPI AG |
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| Year of publishing: | 2026 |
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| Number of pages: | str. 1-24 |
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| Numbering: | Vol. 12, issue 3, [article no.] 200 |
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| PID: | 20.500.12556/DiRROS-28579  |
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| UDC: | 620.1/.2 |
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| ISSN on article: | 2310-2861 |
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| DOI: | 10.3390/gels12030200 |
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| COBISS.SI-ID: | 270957315 |
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| Copyright: | © 2026 by the authors |
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| Note: |
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| Publication date in DiRROS: | 24.03.2026 |
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| Views: | 78 |
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| Downloads: | 68 |
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