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Title:
Linear thermal expansion of ▫$0.5Ba(Zr_{0.2}Ti_{0.8})O_3-0.5(Ba_{0.7}Ca_{0.3})TiO_3$▫ bulk ceramic
Authors:
ID
Konsago, Sabi William
, Institut "Jožef Stefan" (
Author
)
ID
Debevec, Andrej
, Institut "Jožef Stefan" (
Author
)
ID
Cilenšek, Jena
, Institut "Jožef Stefan" (
Author
)
ID
Kmet, Brigita
, Institut "Jožef Stefan" (
Author
)
ID
Malič, Barbara
, Institut "Jožef Stefan" (
Author
)
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URL - Source URL, visit
https://www.midem-drustvo.si/journal_papers/MIDEM_53(2023)4p3.pdf
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https://www.midem-drustvo.si/journal_papers/MIDEM_53(2023)4p3.pdf
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Language:
English
Typology:
1.01 - Original Scientific Article
Organization:
IJS - Jožef Stefan Institute
Abstract:
We report the linear thermal expansion coefficient of lead-free ferroelectric ceramic barium zirconate titanate - barium calcium titanate 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT). The material was prepared by solid-state synthesis and consolidated by sintering at 1450 °C. BZT-BCT crystallizes in the perovskite phase. The microstructure of the ceramic with about 95 % relative density consists of about 10 mm-sized grains. The contact dilatometry of the ceramic specimen reveals the change of slope of the linear thermal expansion curve at 84 °C. This is in good agreement with the peak of the dielectric permittivity versus temperature at about 85 °C indicating the transition from the low-temperature polar ferroelectric phase to a high-temperature nonpolar phase or Curie temperature. The thermal expansion coefficients of the polar tetragonal and nonpolar cubic phases of BZT-BCT are 7.69×10-6 K-1 (40°C – 80°C) and 12.39×10-6 K-1 (100°C – 600°C), respectively. The thermal expansion data are among the material data needed in the design of thin- and thick-film structures for energy-harvesting and energy-storage applications.
Keywords:
lead-free
,
ferroelectric ceramic
,
linear thermal expansion
Publication status:
Published
Publication version:
Version of Record
Submitted for review:
09.01.2024
Article acceptance date:
13.02.2024
Publisher:
Strokovno društvo za mikroelektroniko, elektronske sestavne dele in materiale
Year of publishing:
2023
Number of pages:
str. 233-238
Numbering:
Vol. 53, no. 4
Source:
Slovenija
PID:
20.500.12556/DiRROS-25332
UDC:
620.1/.2
ISSN on article:
0352-9045
DOI:
10.33180/InfMIDEM2023.403
COBISS.SI-ID:
187559427
Copyright:
Copyright © 2023 by the Authors.
Note:
Besedilo v angl.;
Publication date in DiRROS:
16.01.2026
Views:
476
Downloads:
174
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Record is a part of a journal
Title:
Informacije MIDEM : časopis za mikroelektroniko, elektronske sestavne dele in materiale
Shortened title:
Inf. MIDEM
Publisher:
Strokovno društvo za mikroelektroniko, elektronske sestavne dele in materiale
ISSN:
0352-9045
COBISS.SI-ID:
1220612
Document is financed by a project
Funder:
ARIS - Slovenian Research and Innovation Agency
Project number:
P2-0105-2022
Name:
Multifunkcijski materiali in naprave: od kvantnega do makro nivoja
Licences
License:
CC BY 4.0, Creative Commons Attribution 4.0 International
Link:
http://creativecommons.org/licenses/by/4.0/
Description:
This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:
16.01.2026
Applies to:
VoR
Secondary language
Language:
Slovenian
Title:
Linearni temperaturni raztezek volumenske keramike ▫$0.5Ba(Zr_{0.2}Ti_{0.8})O_3-0.5(Ba_{0.7}Ca_{0.3})TiO_3$▫ bulk ceramic
Keywords:
brez svinca
,
feroelektrična keramika
,
linearni temperaturni raztezek
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