| Title: | A general-purpose adsorption isotherm for improved estimation of standard adsorption free energy |
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| Authors: | ID Kokalj, Anton, Institut "Jožef Stefan" (Author) |
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| Files: |  URL - Source URL, visit https://www.sciencedirect.com/science/article/pii/S0010938X2300166X?via%3Dihub
 PDF - Presentation file, download (2,52 MB)
MD5: 6C8164F2ADA56DDB3C9C7B2398E826F7
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| Language: | English |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: |  IJS - Jožef Stefan Institute
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| Abstract: | A new general-purpose Type–I adsorption isotherm is proposed to improve standard adsorption Gibbs energy estimation. This new isotherm stems from considering a functional dependence of various adsorption models on the �∕� vs. � plot, where � is the fractional surface coverage and � the concentration. It can accurately describe many adsorption isotherms, implying that it is flexible enough to describe various adsorption scenarios. Among the tested adsorption models that the new isotherm can describe are those that consider lateral inter-adsorbate interactions, molecular size, surface heterogeneity, and mobile adsorption. |
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| Keywords: | standard adsorption free energy, corrosion inhibitors, adsorption isotherms |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Submitted for review: | 22.12.2022 |
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| Article acceptance date: | 21.03.2023 |
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| Publication date: | 28.03.2023 |
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| Publisher: | Elsevier |
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| Year of publishing: | 2023 |
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| Number of pages: | str. 1-7 |
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| Numbering: | Vol. 217, [article no.] 111124 |
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| Source: | Nizozemska |
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| PID: | 20.500.12556/DiRROS-22125  |
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| UDC: | 620.1/.2 |
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| ISSN on article: | 1879-0496 |
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| DOI: | 10.1016/j.corsci.2023.111124 |
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| COBISS.SI-ID: | 147900163 |
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| Copyright: | © 2023 The Author(s). |
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| Note: | Nasl. z nasl. zaslona;
Opis vira z dne 5. 4. 2023;
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| Publication date in DiRROS: | 29.04.2025 |
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| Views: | 572 |
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| Downloads: | 294 |
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