| Title: | SBA-15 mesoporous particles with adsorbed cresol red dye and functionalized with 3-aminopropyl groups : materials properties and dye release studies |
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| Authors: | ID Švara Fabjan, Erika (Author)
ID Cerc Korošec, Romana (Author)
ID Šifrer, Klara (Author)
ID Sever Škapin, Andrijana (Author)
ID Martinez Manez, Ramon (Author) |
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| Files: |  URL - Source URL, visit https://www.sciencedirect.com/science/article/pii/S1387181124000301
 PDF - Presentation file, download (10,52 MB)
MD5: A41E058C85C09962A3C60FF6E4CC9E07
 DOCX - Supplement, download (882,69 KB)
MD5: 30E2DD936983F39A59F45CDAF356D6F5
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| Language: | English |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: |  ZAG - Slovenian National Building and Civil Engineering Institute
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| Abstract: | Research in the field of sensing has focused on tailoring the responsiveness of materials through the variation in materials properties achieved via functionalization of the mesoporous matrix. pH indicator dyes capable of protonation/deprotonation reactions are known to display different forms, resulting in changes in colour. This research focused on the preparation of mesoporous substrates SBA-15 with integrated pH indicator dye o-cresolsulphonephtalein (cresol red) grafted with (3-aminopropy) trimethoxysilane (gaining functionalized-SBA-15 material) in order to gain a colour change response following release of the dye. UV-Vis reflectance and absorbance spectra were used to evaluate forms of cresol red. The textural properties, including specific surface area, pore size distribution and pore volume were evaluated using nitrogen sorption, and XRD analysis was conducted to evaluate crystallinity of the material and pore ordering. The presence of 3-aminopropyl groups was determined by thermal decomposition using TGA–DSC/MS. The functionalized SBA-15 materials loaded with cresol red mostly retained ordering of the pores and showed a slight reduction in surface area. Functionalization changed the surface properties of the material. In the non-functionalized SBA-15, cresol red was present in both double (H2L) and single (HL−) protonated forms, whereas in the functionalized SBA-15 the deprotonated L2−form prevailed. Through desorption experiments cresol red was successfully desorbed from selected sample to different media. The change of colour caused by alterations in the form of the dye once released from the mesoporous silica material into the medium was confirmed. The form of cresol red released was determined by the pH of the medium. |
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| Keywords: | mezoporozni materiali, SBA-15, funkcionalizacija, uravnavanje odzivnosti, zaznavanje |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Publication date: | 23.01.2024 |
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| Publisher: | Elsevier |
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| Year of publishing: | 2024 |
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| Number of pages: | str. 1-12 |
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| Numbering: | Vol. 368, [article no.] 113008 |
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| PID: | 20.500.12556/DiRROS-18143  |
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| UDC: | 54 |
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| ISSN on article: | 1873-3093 |
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| DOI: | 10.1016/j.micromeso.2024.113008 |
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| COBISS.SI-ID: | 182066435 |
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| Note: | Received 18 October 2023, Revised 19 January 2024, Accepted 21 January 2024, Available online 23 January 2024;
Nasl. z nasl. zaslona;
Opis vira z dne 23.1. 2024;
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| Publication date in DiRROS: | 13.02.2024 |
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| Views: | 552 |
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| Downloads: | 433 |
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