| Title: | Experimental study and thermodynamic modelling of the temperature effect on the hydration of belite-ye’elimite-ferrite cements |
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| Authors: | ID Mrak, Maruša (Author)
ID Winnefeld, Frank (Author)
ID Lothenbach, Barbara (Author)
ID Legat, Andraž (Author)
ID Dolenec, Sabina (Author) |
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| Files: |  URL - Source URL, visit https://www.sciencedirect.com/science/article/pii/S0950061823039788?via%3Dihub
 PDF - Presentation file, download (9,96 MB)
MD5: 6C7B0DEC070541FC4EB736C0F8C72DD9
 DOCX - Supplement, download (568,89 KB)
MD5: F583FBFD4374EF8CC8C4F0754096876D
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| Language: | English |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: |  ZAG - Slovenian National Building and Civil Engineering Institute
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| Abstract: | This study focuses on the kinetics of hydration, phase assemblage, microstructure and mechanical properties after various hydration times of two different BCSA cements at 5, 20, 40 and 60 ◦C and compares experimental data with thermodynamic modelling. Different curing temperatures change the type of hydrates and their amounts. Ye’elimite and gypsum in belite-ye’elimite-ferrite cements are almost fully reacted after 24 h of hydration at 20, 40 and 60 ◦C, while not at 5 ◦C. The hydration of belite is slower than the one of ye’elimite, but reaches a high degree of hydration after 150 days which is increasing with temperature. Less ettringite is present at elevated temperatures due to its increasing solubility, while more monosulfate is observed. Furthermore, with increasing temperature siliceous hydrogarnet forms at the expenses of strätlingite as well as more C S H is found as more belite reacts resulting in higher compressive strength. Dense and homogenous microstructure is observed at 5 ◦C, while it is more heterogeneous at higher temperatures. The presence of more ye’elimite resulted in higher ettringite and str¨atlingite formation and a higher compressive strength, while more belite yields more C S H in the hydrates and lower compressive strength. |
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| Keywords: | belite-ye’elimite-ferrite cement, temperature, hydration, thermodynamic modelling |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Publication date: | 25.11.2023 |
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| Publisher: | Elsevier |
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| Year of publishing: | 2024 |
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| Number of pages: | str. 1-17 |
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| Numbering: | Vol. 411, [article no.] 134260 |
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| PID: | 20.500.12556/DiRROS-17491  |
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| UDC: | 620.1/.2 |
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| ISSN on article: | 1879-0526 |
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| DOI: | 10.1016/j.conbuildmat.2023.134260 |
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| COBISS.SI-ID: | 174572291 |
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| Copyright: | © 2023 The Author(s). Published by Elsevier Ltd. |
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| Publication date in DiRROS: | 11.12.2023 |
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| Views: | 546 |
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| Downloads: | 420 |
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