| Title: | Influence of the calcination duration of ▫$g-C_3N_4/TiO_2$▫ veggie-toast-like photocatalyst on the visible-light triggered photocatalytic oxidation of bisphenol A |
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| Authors: | ID Roškarič, Matevž (Author) ID Žerjav, Gregor (Author) ID Finšgar, Matjaž (Author) ID Zavašnik, Janez (Author) ID Pintar, Albin (Author) |
| Files: | URL - Source URL, visit https://www.sciencedirect.com/science/article/pii/S0925838823008885?via%3Dihub
PDF - Presentation file, download (3,13 MB) MD5: 5D541D9B397BCB45035B9514A6D1ED0F
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| Language: | English |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: | KI - National Institute of Chemistry
IJS - Jožef Stefan Institute
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| Abstract: | Two commercially available TiO2 (hexagonal-like and spherical-like particles) were used to investigate the effect of g-C3N4 “melting” on the photocatalytic properties of g-C3N4/TiO2 composites. Improvement in the contact between the components was observed when they were thermally treated at 350 °C for an extended period of time (between 2 and 72 h) due to the partial melting and phase fusion of g-C3N4. Consequently, the enhanced contact between the phases allows easier injection of photogenerated electrons from the conduction band of g-C3N4 into TiO2, improving charge carrier separation. The prepared composites were tested for bisphenol A degradation under visible-light illumination, which showed that the components that had been calcined for 24 h performed better due to the improved charge carrier separation. Superoxide anionic radicals and photogenerated holes were identified as active species in the photooxidation experiments conducted under visible-light illumination. |
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| Keywords: | titanium dioxide, photocatalyst, calcination time, photocatalysis under visible-light illumination, water remediation, bisphenol A |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Publication date: | 25.06.2023 |
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| Publisher: | Elsevier Science |
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| Year of publishing: | 2023 |
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| Number of pages: | str. 1-16 |
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| Numbering: | Vol. 947, article no. 169585 |
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| Source: | Journal of alloys and compounds |
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| PID: | 20.500.12556/DiRROS-16374  |
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| UDC: | 544.5/.6 |
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| ISSN on article: | 1873-4669 |
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| DOI: | 10.1016/j.jallcom.2023.169585  |
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| COBISS.SI-ID: | 144950275  |
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| Copyright: | © 2023 The Author(s). Published by Elsevier B.V. |
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| Note: | Nasl. z nasl. zaslona;
Soavtorji: Gregor Žerjav, Matjaž Finšgar, Janez Zavašnik, Albin Pintar;
Opis vira z dne 13. 3. 2023;
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| Publication date in DiRROS: | 17.03.2023 |
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| Views: | 2023 |
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| Downloads: | 878 |
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