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Title:Statistical approach to interpretation of geochemical data of stream sediment in Pleše mining area
Authors:ID Jarc, Simona (Author)
Files:.pdf PDF - Presentation file, download (1,01 MB)
MD5: 99FD68D3F5EF1BBB3298410C9483E0F5
 
URL URL - Source URL, visit https://www.geologija-revija.si/index.php/geologija/article/view/1845/1910
 
Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo GeoZS - Geological Survey of Slovenia
Abstract:The Ba, Pb and Zn ore deposit Pleše near Ljubljana is one of the formerly productive mines. The stream sediments were sampled and analysed by XRF to establish the effect of grain size, mineralization, and downstream location of sampling sites on geochemical composition based on various statistical analyses. Statistical analyses of the geochemical data confirm the impact of mineralization. The parametric t-test, non-parametric Mann-Whitney test and cluster analysis showed only minor differences in the geochemical composition of the samples with different grain sizes (< 0.063 mm and 0.063-2 mm). The parametric and non-parametric correlation coefficients as well as cluster analysis indicate that the contents of Si, Al, K, Rb, and Fe are associated with weathered rock forming minerals such as micas, and clay minerals, whereas Nb and Zr are associated with minerals resistant to weathering. Ca and Mg are associated with carbonates. S, Ba, Sr, Pb, Zn, and Mn indicate local mineralization with sulphates and sulphides. The results of the t-test and analysis of variance, Mann-Whitney tests and Kruskal-Wallis ANOVA of the groups established by the cluster analysis confirm that the contents of Ba, Pb and Sr have a statistically significant influence on the classification of the cluster group - i.e., the influence of sediment mineralization. There are no differences in elemental contents in the sediment samples downstream. The statistical approach to evaluate the geochemical data has proven useful and provides a good basis for further interpretation.
Keywords:ANOVA, t-test, correlation, cluster analysis, XRF, mineralization
Publication status:Published
Publication version:Version of Record
Publication date:21.12.2022
Publisher:Geološki zavod Slovenije
Year of publishing:2022
Number of pages:str. 225-235
Numbering:vol. 65, no. 2
PID:20.500.12556/DiRROS-16016-940fd926-4943-1bcb-6a48-da7213c8e37b New window
UDC:504.5
ISSN on article:0016-7789
DOI:10.5474/geologija.2022.013 New window
COBISS.SI-ID:135905283 New window
Publication date in DiRROS:18.01.2023
Views:447
Downloads:206
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Record is a part of a journal

Title:Geologija
Shortened title:Geologija
Publisher:Geološki zavod Slovenije
ISSN:0016-7789
COBISS.SI-ID:5636866 New window

Document is financed by a project

Funder:ARRS - Slovenian Research Agency
Project number:P1-0195-2018
Name:Geookolje in geomateriali

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Title:Statistični pristop k interpretaciji geokemičnih podatkov potočnega sedimenta na območju rudišča Pleše
Abstract:V rudišču Pleše v okolici Ljubljane so v preteklosti pridobivali Ba, Pb in podrejeno Zn. Vpliv velikosti zrn, mineralizacije in lokacije vzorčevanih točk dolvodno na geokemično sestavo sem določala v vzorcih potočnega sedimenta, katerega geokemična sestava je bila določena z metodo XRF. Statistična analiza podatkov geokemične sestave je potrdila mineralizacijo vzorcev potočnega sedimenta. Rezultati parametričnega t-testa, neparametičnega Mann-Whitney-jevega testa in clustrske analize so pokazali, da se geokemični sestavi vzorcev frakcij <0,063 mm in 0,063-2 mm skoraj ne razlikujeta. Tako parametrični kot neparametrični korelacijski koeficienti ter clustrska analiza so pokazali, da prvine Si, Al, K, Rb in Fe kažejo na prisotnost preperelih kamninotvornih mineralov (npr. sljud, glinenih mineralov), Nb in Zr na minerale odporne na preperevanje, Ca in Mg sta značilna za karbonate. S, Ba, Sr, Pb, Zn in Mn kažejo na lokalno mineralizacijo s sulfati in sulfidi. Razlike med skupinami, ugotovljenimi s clustrsko analizo, sem testirala s parametričnim t-testom, analizo variance in Mann-Whitney-jevim testom ter Kruskall-Wallis ANOVO. Na uvrstitev v skupine nabolj vplivajo vsebnosti Ba, Pb in Sr, kar potrjuje vpliv mineralizacije sedimenta. Razlik v geokemični sestavi vzorcev sedimentov dolvodno testi niso zaznali. Statistični pristop k interpretaciji geokemičnih podatkov predstavlja dobro osnovo za nadaljnjo interpretacijo.
Keywords:ANOVA, t-test, korelacija, clustrska analiza, XRF, mineralizacija


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