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Title:Carbon isotopic composition of methane and its origin in natural gas from the Petišovci-Dolina oil and gas field (Pannonian Basin System, NE Slovenia) – a preliminary study
Authors:ID Markič, Miloš (Author)
ID Kanduč, Tjaša (Author)
Files:.pdf PDF - Presentation file, download (724,51 KB)
MD5: EB68B46DAD3D7F0BD5E9B2BE7C54AC08
 
Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo GeoZS - Geological Survey of Slovenia
Abstract:The carbon isotopic composition of methane (δ13CCH4) in natural gas from the Petišovci-Dolina oil and gas field (NE Slovenia) was measured for the first time in August and September 2021. The gas samples from different depths were taken from three wells: Dolina-deep (Pg-6) from the depth interval 3102–3104 m, Petišovci-deep (Pg-5) from the depth interval 2772–2795 m, and Petišovci-shallow (D-5) from the depth interval 1212–1250 m. According to the available composition dataset of gas, available from the Petrol Geo d.o.o. documentation, the “deep” gases sampled from the Pg-6 and Pg-5 wells consist of 85 % methane (C1), 11 % hydrocarbons heavier than methane (C2–C6) and 4 % CO2. The “shallow” gas from well D-5 contains more than 89 % methane, up to 11 % C2–C6 gases, while the CO2 content is negligible. The “deep« gas from the Pg-6 and Pg-5 wells has δ13CCH4 -36.7 ‰ and -36.6 ‰, respectively, while the “shallow” gas from the D-5 well has the δ13CCH4 of -38.6 ‰. The methane from the “shallow” gas is slightly enriched in the lighter 12C isotope. δ13CCH4 in the range from -38.6 to -36.6 ‰ clearly indicates the thermogenic origin of methane formed during the catagenesis phase of gas formation.
Keywords:Petišovci-Dolina, gas, methane, isotopes, origin
Publication status:Published
Publication version:Version of Record
Publisher:Geološki zavod slovenije
Year of publishing:2022
Number of pages:str. 59-72
Numbering:vol. 65, no. 1
PID:20.500.12556/DiRROS-15332 New window
UDC:553
ISSN on article:0016-7789
DOI:10.5474/geologija.2022.004 New window
COBISS.SI-ID:116539907 New window
Publication date in DiRROS:26.07.2022
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Downloads:359
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Record is a part of a journal

Title:Geologija
Publisher:Geološki zavod Slovenije
ISSN:0016-7789

Document is financed by a project

Funder:ARRS - Slovenian Research Agency
Project number:P1-0025
Name:Mineralne surovine

Funder:ARRS - Slovenian Research Agency
Project number:P1-0143
Name:Kroženje snovi v okolju, snovna bilanca in modeliranje okoljskih procesov ter ocena tveganja

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:22.07.2022

Secondary language

Language:Slovenian
Title:Izotopska sestava ogljika v metanu in njegov izvor v naravnem plinu na območju nafto-plinskega polja Petišovci-Dolina (Panonski bazenski sistem, SV Slovenija) – preliminarna raziskava
Abstract:Izotopsko sestavo metana (δ13CCH4) v naravnem (zemeljskem) plinu naftno-plinskega polja Petišovci-Dolina (Ormoško-selniška antiklinala, NE Slovenija) smo prvič merili v avgustu in septembru 2021. Plinske vzorce smo vzorčili iz različnih globin iz treh plinskih vrtin: iz Petišovci-globoka (Pg-6) iz globine 3102–3104 m, iz Petišovci-globoka (Pg-5) iz globine 2772–2795 m in iz Dolina-plitva (D-5) iz globine 1212–1250 m. Glede na dostopne podatke o sestavi plina iz dokumentacije Petrol Geo d.o.o., so “globoki” plini iz vrtin Pg-6 in Pg-5 sestavljeni iz 85 % metana (C1), iz 11 % ogljikovodikov, težjih od metana (C2–C6) in 4 % CO2. “Plitvi” plin iz vrtine D-5 je sestavljen iz več kot 89 % metana in do 11 % C2–C6, medtem ko je koncentracija CO2 zanemarljiva. “Globoki” plin iz vrtin Pg-6 in Pg-5 ima δ13CCH4 vrednost od -36.7 do -36.6 ‰, medtem ko ima “plitvi” plin iz vrtine D-5 δ13CCH4 -38.6 ‰. “Plitvi”plin iz vrtine D-5 je obogaten na lažjem 12C izotopu. Razpon δ13CCH4 od -38.6 do -36.6 ‰ jasno kaže termogeni izvor metana, ki je nastal v fazi katageneze nastajanja plina.
Keywords:Petišovci-Dolina, plin, metan, izotopi, izvor


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  1. Geologija

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