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Title:Pesticidi v vodonosniku Krško-Brežiškega polja
Authors:ID Mali, Nina (Author)
ID Koroša, Anja (Author)
ID Urbanc, Janko (Author)
Files:.pdf PDF - Presentation file, download (11,46 MB)
MD5: 9789E7365EC4B282E53FDB6008479B82
 
Language:Slovenian
Typology:1.01 - Original Scientific Article
Organization:Logo GeoZS - Geological Survey of Slovenia
Abstract:Onesnaženje podzemne vode s pesticidi je splošno razširjen problem, tako v svetu kot tudi v Sloveniji. Glede na pretekle velike obremenitve podzemne vode s pesticidi, je bil namen predstavljene raziskave ugotoviti razširjenost pesticidov v podzemni vodi Krško-Brežiškega polja v obdobju 2018 - 2019 in pri tem preveriti uporabnost metode vzorčenja vode s pasivnimi vzorčevalniki. Skupno smo odvzeli 21 vzorcev podzemne vode na enajstih lokacijah in po dva vzorca v rekah Sava in Krka. V vodi smo določili 15 različnih pesticidov in njihovih razgradnih produktov. V vzorcih podzemne vode sta bila največkrat določena atrazin in njegov razgradni produkt desetilatrazin. Sledijo pesticidi desetilterbutilazin, terbutilazin, metolaklor ter simazin. V površinski vodi smo zaznali atrazin, desetilatrazin, klortoluron, metolaklor in terbutilazin. S kvalitativno metodo vzorčenja s pasivnimi vzorčevalniki smo v podzemni in površinski vodi odvzeli skupno 24 vzorcev. Izločili smo 8 pesticidov, ki se pojavljajo v dveh serijah. Pogostnost pojavljanja posameznih pesticidov je po obeh metodah primerljiva. Pasivno vzorčenje vode se je izkazalo za primerno metodo identifikacije prisotnosti pesticidov. Največje obremenitve s pesticidi na Krško-Brežiškem polju prihajajo s kmetijskih površin. Podzemna voda je bolj obremenjena s pesticidi v osrednjem delu polja v smeri toka od zahoda proti vzhodu. Atrazin in desetilatrazin sta še vedno, kljub dvajsetletni prepovedi, najpogosteje in v najvišjih koncentracijah zaznana pesticida v podzemni vodi Krško-Brežiškega polja.
Keywords:podzemna voda, vodonosnik Krško-Brežiško polje, pesticidi
Publication status:Published
Publication version:Version of Record
Publisher:Geološki zavod Slovenije
Year of publishing:2021
Number of pages:str. 267-288
Numbering:vol. 64, no . 2
PID:20.500.12556/DiRROS-14800 New window
UDC:556.3
ISSN on article:0016-7789
DOI:10.5474/geologija.2021.015 New window
COBISS.SI-ID:92547331 New window
Publication date in DiRROS:09.03.2022
Views:788
Downloads:316
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Record is a part of a journal

Title:Geologija
Publisher:Geološki zavod Slovenije
ISSN:0016-7789

Document is financed by a project

Funder:ARRS - Slovenian Research Agency
Project number:L4-8221
Name:Učinkovitejša raba vode in hranil v rastlinski pridelavi za varovanje in izboljšanje virov pitne vode - URAVIVO
Acronym:URAVIVO
Funder:ARRS - Slovenian Research Agency
Project number:Z1-2639
Name:Urabana hidrogeologija: Izboljšane metode za določanje pojava, transportnih procesov in izvora ostankov zdravil v virih podzemne vode
Funder:EC - European Commission
Funding programme:H2020
Project number:731166
Name:Establishing the European Geological Surveys Research Area to deliver a Geological Service for Europe
Acronym:GeoERA

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:28.12.2021

Secondary language

Language:English
Title:Prevalence of pesticides in Krško-Brežice polje aquifer
Abstract:Groundwater pollution with pesticides is a problem that occurs all over the world as well as in Slovenia. Considering the past high loads of groundwater with pesticides, the purpose of the presented research was to determine the presence of pesticides in the groundwater of Krško-Brežiško polje in the period 2018-2019 and to check the applicability of the passive sampling method. A total of 21 groundwater samples were taken at 11 locations and 2 samples each in the Sava and Krka rivers. We identified 15 pesticides and their degradation products. Atrazine and its degradation product desethylatrazine were most frequently determined in groundwater samples. They are followed by desethylterbutylazine, terbutylazine, metolachlor and simazine. Atrazine, desethylatrazine, chlortoluron, metolachlor and terbuthylazine were detected in surface water. A total of 24 samples were taken in groundwater and surface water using the qualitative passive sampling method. We singled out 8 pesticides that appear in two campaigns. The frequency and occurrence of individual pesticides by both methods are comparable. Passive sampling has proven to be an appropriate method of identifying the presence of pesticides. The highest loads in the Krško-Brežiško field arise from the agricultural land areas. Groundwater is more contaminated with pesticides in the central part of the field in the direction of groundwater flow from west to east. In the groundwater of the Krško-Brežice field, atrazine and desethylatrazine are still the most frequently detected pesticides with higher concentrations, despite a 20 years long ban on the use of atrazine-based plant protection products.
Keywords:groundwater, aquifer Krško-Brežice polje, pesticides


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