11. Using stable isotopes and major ions to identify recharge characteristics of the Alpine groundwater-flow dominated Triglavska Bistrica RiverLuka Serianz, Sonja Cerar, Polona Vreča, 2021, original scientific article Abstract: Triglavska Bistrica is a typical Alpine river in the north-western part of Slovenia. Its recharge area includes some of the highest peaks in the Julian Alps. The hydrogeological conditions and flow of the river depend largely on groundwater exchange between the karstified aquifer in the carbonate rocks and the intergranular aquifer in the glaciofluvial deposits. The average volume of the river flow is up to several m3/s. In this study, water samples from different locations along the river were analysed for stable isotope ratios of oxygen and hydrogen, major ions, and concentration of tritium activity. The correlation of major ions suggests that the recharge area consists of both limestone and dolomite rocks. The δ18O and δ2H values decrease downstream, implying that the average recharge elevation increases. At the downstream sampling site V-5, located approx. 300 m upstream from the confluence of the Sava Dolinka River, the calculated mean recharge altitude is estimated to be 1,996 m.
Keywords: groundwater, oxygen and hydrogen isotopes, hydrogeochemistry, recharge area, Alpine aquifer, Slovenia
Published in DiRROS: 09.03.2022; Views: 875; Downloads: 294
 Full text (3,01 MB) |
12. Passive sampling with active carbon fibres in the determination of organic pollutants in groundwaterPrimož Auersperger, Anja Koroša, Nina Mali, Brigita Jamnik, 2022, original scientific article Abstract: Legislation addressing the quality of groundwater and increasing concerns over public health calls for the development of analytical methods that can produce accurate and precise results at the ppt level. Passive sampling has been recognised as a helpful tool in identifying various organic pollutants in groundwater, even when their presence had not yet been identified through conventional groundwater quality monitoring. The article presents an analytical method involving a simple and cost-effective passive sampling device using Zorflex® activated carbon fibres (ACFs) for the qualitative monitoring of a broad range of organic pollutants in water in a single run. The applicability of the method developed was tested in three hydrogeological studies. In the first case, we present a non-targeted qualitative screening and a list of 892 different contaminants detected in the groundwater in Slovenia. In the second case, we discuss the presence and origin of organic compounds in the groundwater from a pilot area of the urban aquifer, Ljubljansko polje. The third case presents a comparison of results between passive and grab sampling. Passive sampling with ACFs confirmed the presence of a pollutant, even when it had not been previously detected through a quantitative method.
Keywords: GC-MS, organic pollutants, qualitative analysis, passive sampling, groundwater
Published in DiRROS: 03.03.2022; Views: 696; Downloads: 297
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13. Emerging organic compounds in European groundwaterS. Y. Bunting, D. J. Lapworth, E. J. Crane, J. Grima-Olmedo, Anja Koroša, A. Kuczyńska, Nina Mali, L. Rosenqvist, M. E. van Vliet, A. Togola, B. Lopez, 2021, original scientific article Abstract: In Europe, emerging organic compounds (EOCs) in groundwater is a growing research area. Prioritisationfor monitoring EOCs in Europe was formalised in 2019 through the development of thefirst voluntarygroundwater watch list (GWWL). Despite this, groundwater occurrence data in the peer reviewedliterature for Europe has not been reviewed to date. Questions surrounding the effect, toxicity, move-ment in the subsurface and unsaturated zone make the process of regulating EOC use difficult. The aim inEurope is to develop a unified strategy for the classification, and prioritisation of EOCs to be monitored ingroundwater. This paper compiles evidence from the recent published studies from across Europe, since2012, when the last major literature global review of EOCs in groundwater took place. A total of 39studies were identified for review based on specific selection criteria (geography, publication date,sample size>10, inclusion of EOCs data). Data on specific compounds, and associated meta-data, arecompiled and reviewed. The two most frequently detected EOCs, carbamazepine and caffeine, occurredin groundwater at concentrations of up to 2.3 and 14.8mg/L, respectively.
Keywords: emerging organic chemicals, environmental exposure, groundwater contaminants, compounds of concern, groundwater hazards
Published in DiRROS: 13.01.2021; Views: 1482; Downloads: 705
Full text (1,90 MB) |
