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Abstract: Although multiple structural, mechanical, and molecular factors are definitely involved in osteoporosis, the assessment of subregional bone mineral density remains the most commonly used diagnostic index. In this study, we characterized bone quality in the femoral neck of one osteoporotic patients as compared to an age-matched control subject, and so used a multiscale and multimodal approach including X-ray computed microtomography at different spatial resolutions (pixel size: 51.0, 4.95 and 0.9 µm), microindentation and Fourier transform infrared spectroscopy. Our results showed abnormalities in the osteocytes lacunae volume (358.08 ± 165.00 for the osteoporotic sample vs. 287.10 ± 160.00 for the control), whereas a statistical difference was found neither for shape nor for density. The osteoporotic femoral head and great trochanter reported reduced elastic modulus (Es) and hardness (H) compared to the control reference (−48% (p < 0.0001) and −34% (p < 0.0001), respectively for Es and H in the femoral head and −29% (p < 0.01) and −22% (p < 0.05), respectively for Es and H in the great trochanter), whereas the corresponding values in the femoral neck were in the same range. The spectral analysis could distinguish neither subregional differences in the osteoporotic sample nor between the osteoporotic and healthy samples. Although, infrared spectroscopic measurements were comparable among subregions, and so regardless of the bone osteoporotic status, the trabecular mechanical properties were comparable only in the femoral neck. These results illustrate that bone remodeling in osteoporosis is a non-uniform process with different rates in different bone anatomical regions, hence showing the interest of a clear analysis of the bone microarchitecture in the case of patients’ osteoporotic evaluation
Keywords: synchrotron X-ray microtomography, bone, trabecular struicture, osteons, osteoporosis, phase-contrast imaging, open access
Published in DiRROS: 28.04.2023; Views: 408; Downloads: 193
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Abstract: Al(OH)3 nanoparticles (ATH NPs) and phosphorylated cellulose nanofibrils (PCNFs) were used as user-friendly and comfortable coating components on flame-retardant fabric to improve its thermophysiological comfort and high-intensive heat protection properties. The effect of the PCNF imprinting and its attachment after the post-printing of a hydrophobic polyacrylate (AP) on the same (back side) or the other (front) side of the fabric, with and without the addition of ATH NPs, was considered, to maintain the front side (facing the wearer) as hydrophilic while keeping the back side (facing the outside) hydrophobic. The amount of coatings applied and their patterning were studied, varied with the ATH NPs’ concentration (1.7, 3.3 and 6.7 wt%) and screen mesh size used (60 and 135), based on the coating’ mass, fabric’s air permeability, thickness and microstructure. The reduced moisture build-up (55%), increased the water vapour (13%) and heat (12%) transfer from the skin, were assessed by applying PCNF under the AP, being more pronounced in the case of using a 135 mesh-sized screen, given the smaller, more densely distributed, thinner and imprinted pattern coatings. These effects were further improved by the addition of nanoporous ATH NPs, which allowed more homogeneous spreading of the moisture and its faster transport. Such a treatment also shifted the fabric’s degradation temperature towards higher values (up to 15°C), retained up to 30% of high-heat flux (21 kW/m2), prolonged the time to ignition by 11 s and reduced the total heat released by up to 60%, thereby providing better protection when exposed to the heat, due to the presence of the phosphorous (PCNF) promoted generation of an Al2O3 char acting as a barrier layer, while also reducing the production of heat and generation of smoke by 75%.
Keywords: flame-retardant textile, Al(OH)3 nanoparticles, phosphorylated cellulose nanofibrils, screen-printing, thermophysiological comfort, heat protection
Published in DiRROS: 28.04.2023; Views: 452; Downloads: 127
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Abstract: Mortar specimens were exposed to either a 3% NaCl solution or a 3% NaCl+KOH solution for up to 180 days. Exposure to the NaCl solution provoked much more leaching than the NaCl+KOH exposure. Leaching strongly impacted the chloride ingress profiles. The extended leaching led to a maximum total chloride content almost three times higher and a deeper chloride penetration than exposure with limited leaching after 180 days. The higher maximum chloride content seems to be linked to the enhanced binding capacity of the C-S-H and AFm phases upon moderate leaching as determined by SEM-EDS. The total chloride profile appears to be governed by multi-ion transport and the interaction of chloride with the hydration phases. Service life prediction and performance testing both rely on total chloride profiles and therefore ought to take these interactions into account.
Keywords: chloride binding, Friedel's salt, Kuzel's salt, ph, GEMS, thermodynamic modelling, open access
Published in DiRROS: 26.04.2023; Views: 332; Downloads: 275
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Abstract: The results of phase 1 of an interlaboratory test, coordinated by the RILEM TC 267-TRM “Tests for Reactivity of Supplementary Cementitious Materials” showed that the R3 (rapid, relevant, reliable) test method, by measurement of heat release or bound water, provided the most reliable and relevant determination of the chemical reactivity of supplementary cementitious materials (SCMs), compared to other test methods. The phase 2 work, described in this paper aimed to improve the robustness of the test procedure and to develop precision statements for the consolidated test procedure. The effect of the pre-mixing and mixing conditions, and the impact of the mix design on the test method robustness were assessed and fixed for optimal conditions to carry out the R3 heat release test. The effect of the drying step was evaluated to define the R3 bound water test procedure in more detail. Finally, the robustness of the consolidated final test methods was determined by an interlaboratory study to define the precision statements.
Keywords: supplementary cementitious materials, reactivity test, bound water
Published in DiRROS: 26.04.2023; Views: 319; Downloads: 130
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Abstract: With the development of computer technology, artificial neural networks are becoming increasingly useful in the field of engineering geology and geotechnics. With artificial neural networks, the geomechanical properties of rocks or their behaviour could be predicted under different stress conditions. Slope failures or underground excavations in rocks mostly occurred through joints, which are essential for the stability of geotechnical structures. This is why the peak shear strength of a rock joint is the most important parameter for a rock mass stability. Testing of the shear characteristics of joints is often time consuming and suitable specimens for testing are difficult to obtain during the research phase. The roughness of the joint surface, tensile strength and vertical load have a great influence on the peak shear strength of the rock joint. In the presented paper, the surface roughness of joints was measured with a photogrammetric scanner, and the peak shear strength was determined by the Robertson direct shear test. Based on six input characteristics of the rock joints, the artificial neural network, using a backpropagation learning algorithm, successfully learned to predict the peak shear strength of the rock joint. The trained artificial neural network predicted the peak shear strength for similar lithological and geological conditions with average estimation error of 6%. The results of the calculation with artificial neural networks were compared with the Grasselli experimental model, which showed a higher error in comparison with the artificial neural network model.
Keywords: artificial neural network, camera-type 3D scanner, rock mechanics, rock joint, joint roughness
Published in DiRROS: 18.01.2023; Views: 362; Downloads: 187
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