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1.
Bio-solution for global sand crisis and sustainable organic agriculture in desert states
Darina Štyriaková, Iveta Štyriakova, Jaroslav Šuba, Felix Föhre, 2022, published scientific conference contribution

Abstract: Sand is an important component of many everyday items, and currently sand is the second most extracted resource on earth after water, but it is not sustainable: we are running out of sand! The black market is booming, and the sand mafia is mining sand at any price. Desert sand is unusable, even Dubai must import it. The smooth surface and iron impurities prevent its industrial use. In this study, bacteria in the bioleaching test attacked the surface of the mineral grains and dissolved impurities including iron through organic acids. Furthermore, the liquid residue containing dissolved iron, organic acids and bacteria stimulated the growth plant what can be a valuable biofertilizer and biostimulant for organic agriculture. Desert states have fertility problems. Despite this, Qatar, for example, is aiming for self-sufficiency in vegetables “in five years”. Results showed that bioleaching combined with magnetic separation resulted in iron removal of 73.23%. The sand after treatment can be suitable to produce clear flat glass, coloured container glass, insulating glass fibres or ceramics. The integrated technology based ecological study revealed overall as utilization potential of the desert sand and the liquid residue could support glass and food production in desert states.
Keywords: materials, sand, bioleaching, sustainable organic agriculture, desert states
Published in DiRROS: 31.01.2024; Views: 191; Downloads: 109
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2.
Bioleaching process for copper extraction from waste in alkaline and acid medium
Ivica Ristović, Darina Štyriaková, Iveta Štyriakova, Jaroslav Šuba, Emilija Širadović, 2022, original scientific article

Abstract: Flotation wastes are becoming a valuable secondary raw material and source of many metals and semimetals worldwide with the possibilities of industrial recycling. The flotation tailings contain oxide and sulfide minerals that have not been sufficiently stabilized and form acidic mine waters, which in turn contaminate groundwater, rivers, and reservoi6sediments. An effective way to recycle these mine wastes is to recover the metals through leaching. While the focus is on acid bioleaching by iron- and sulfur-oxidizing bacteria, alkaline leaching, and the removal of iron- containing surface coatings on sulfide minerals contribute significantly to the overall environmental efficiency of leaching. For this study, static and percolate bioleaching of copper from flotation waste at the Bor copper mine in Serbia was investigated in alkaline and then acidic environments. The aim of the study was to verify the effect of alkaline pH and nutrient stimulation on the bioleaching process and element extraction. A sample was taken from a mine waste site, which was characterized by XRF analyses. The concentration of leached copper was increased when copper oxide minerals dissolved during alkaline bioleaching. The highest copper yield during alkaline bioleaching was achieved after 9 days and reached 67%. The addition of nutrients in acidic medium enhanced the degradation of sulfide minerals and increased Cu recovery to 74%, while Fe and Ag recoveries were not significantly affected. Combined bioleaching with alkaline media and iron- and sulfur-oxidizing bacteria in acidic media should be a good reference for ecological Cu recovery from copper oxide and sulfide wastes.
Keywords: copper, alkaline, acidic bioleaching, secondary raw materials, open access
Published in DiRROS: 05.05.2023; Views: 304; Downloads: 154
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