1. Comparison of the mineralogy and microstructure of EAF stainless steel slags with reference to the cooling treatmentMojca Loncnar, Ana Mladenovič, Marija Zupančič, Peter Bukovec, 2017, original scientific article Abstract: TIn the present study the differences in the mineralogical composition and microstructure of various types of EAF stainless steel (EAF S) slag with regard to the cooling treatment, the operation practice in an EAF (electric arc furnace) and environmental ageing reactions were evaluated. It was shown that the mineralogy of the investigated EAF S slags varied from one slag to another, depending on the quality of the produced stainless steel. The production process of the treated steel also has a strong influence on the mineralogy of the slags. The conditions during water cooling treatment were not sufficient to prevent the crystallization of primary mineral phases, which occurs predominantly in air-cooled EAF S slags, probably due to the high basicity of the investigated slags. However, the water cooling treatment of hot slag leads to the absence of γ-CaSiO 4 and the formation of secondary mineral phases predominantly calcite, portlandite, ettringite, calcium aluminate hydrate and calcium silicate hydrate. It has been shown that during the environmental ageing test (down-flow column test) secondary mineral phases were formed, which were the same as those formed during the water cooling treatment. Keywords: electric arc furnace stainless steel slag, cooling path, microstructure, mineralogy Published in DiRROS: 14.08.2024; Views: 44; Downloads: 69
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2. Utilisation of reused steel and slag : analysing the circular economy benefits through three case studiesGenesis Camila Cervantes Puma, Adriana Salles, Janez Turk, Viorel Ungureanu, Luís Bragança, 2024, review article Abstract: This research explores sustainable construction practices focusing on material reuse, specifically reclaimed structural steel and slag. In general, the building stock is not designed for deconstruction, and material recovery for reuse at the end of life of buildings is complex and challenging. The study evaluates the benefits of content reuse through a thorough analysis of three case studies— BedZED eco-friendly housing, Angus Technopôle building, and the use of steel slag aggregate in road construction. It highlights the value of reclaimed structural steel and by-products like steel slag in waste reduction, energy conservation, and resource preservation. The BedZED case study showcases recycled steel’s cost-effectiveness and economic viability in construction, while the Angus Technopôle building exemplifies the adaptive reuse of an old steel frame building. Additionally, the third case study showcases the benefits of using Electric Arc Furnace C slag in asphalt-wearing courses, highlighting the reduction in greenhouse gas emissions and environmental impact. The versatility of reclaimed structural steel and slag is evident in integrating material reuse in building construction and road infrastructure. These case studies illustrate the potential for reusing steel and its by-products in various construction contexts, from eco-friendly housing to road development. Therefore, the study aims to demonstrate the feasibility and benefits of sustainable practices within the construction industry by showcasing the successful incorporation of reclaimed steel and slag in these projects. Considering the significant contributions of building construction to global greenhouse gas emissions, raw material extraction, and waste production, the study advocates for adopting circular economy (CE) principles within the construction industry. Finally, the analysis of case studies underscores the advantages of reclaimed structural steel and the valorisation of steel slag through the lens of CE and their contribution to sustainable development. Keywords: circular economy, reused steel, steel slag aggregate, reclaimed steel, steel members Published in DiRROS: 12.04.2024; Views: 309; Downloads: 144
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3. Particle size manipulation as an influential parameter in the development of mechanical properties in electric arc furnace slag-based AAMKatja Traven, Mark Češnovar, Vilma Ducman, 2019, original scientific article Abstract: Alkali-activated materials (AAM) have gained recognition as a promising alternative to technical ceramic and building materials owing to the lower energy demands for production and the potential to use slag as a precursor. In the present study, five sets of slag-based AAM pastes were prepared with different particle sizes (fractions d < 63, 63 < d < 90, and 90 < d < 125 μm in different mass ratios) under the same curing regime and using a fixed precursor to activator (water) mass ratio. Precursors and the hardened AAM are evaluated using BET, XRD, XRF, SEM, FTIR, reactivity of precursors by leaching, and mercury intrusion porosimetry (MIP). Chemical analysis indicated only marginal differences among the different-sized fractions of input materials, whereas the BET surface area and reactivity among the precursors differed significantly-smaller particles had the largest surface area, and thus, higher reactivity. The mineralogical differences between the precursors and hardened AAM were negligible. The results revealed that compressive strength was significantly influenced by particle size, i.e., a threefold increase in strength when the particle size was halved. Microstructural evaluation using MIP confirmed that the porosity was the lowest in AAM with the smallest particle size. The low porosity and high reactivity of the fine fractions led to the highest compressive strength, confirming that manipulation of particle size can significantly influence the mechanical properties. Keywords: alkalijsko aktivirani materiali, žlindra iz obločne peči, mehanska aktivacija, mehanske lastnosti, poroznost, alkali-activated materials (AAM), electric arc furnace steel slag, mechanical activation, mechanical properties, porosity Published in DiRROS: 22.11.2023; Views: 522; Downloads: 224
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4. The Incorporation of steel slag into belite-sulfoaluminate cement clinkersLea Žibret, Katarina Šter, Maruša Mrak, Mojca Loncnar, Sabina Dolenec, 2021, original scientific article Abstract: The potential use of steel slag from treated steel slag in belite-sulfoaluminate cements was investigated in this study. Cement clinkers with two phase compositions were synthesized, allowing the incorporation of different amounts of steel slag. The phase composition and microstructure of cement clinkers at three different sintering temperatures were studied by X-ray powder diffraction and the Rietveld method, as well as scanning electron microscopy with energy dispersive spectrometry. The results showed that the targeted phase composition of clinkers was achieved at a sintering temperature of 1250%C. However, a higher amount of perovskite instead of ferrite was detected in the clinker with a higher content of Ti-bearing bauxite. Apart from the main phases, such asbelite, calcium sulfoaluminate, and ferrite, several minor phases were identified, including mayenite, perovskite, periclase, and alkali sulfates. In both clinker mixtures, a higher content of MgO in the steelslags resulted in the formation of periclase. Furthermore, the hydration kinetics and compressive strength at 7 and 28 days were studied in two cements prepared from clinkers sintered at 1250%C. As evidenced by the results of isothermal calorimetry, the hydration kinetics were also influenced by the minor clinker phases. Cement with a higher content of calcium sulfoaluminate phase developed a higher compressive strength. Keywords: cements, BCSA, steel slag, secundary row materials, microstructure, clinker phase Published in DiRROS: 01.08.2023; Views: 431; Downloads: 217
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5. Mass concrete with EAF steel slag aggregate : workability, strength, temperature rise, and environmental performanceDavor Kvočka, Jakob Šušteršič, Alenka Mauko Pranjić, Ana Mladenovič, 2022, original scientific article Abstract: Temperature control is the primary concern during the design and construction process of mass concrete structures. As the concrete production has an enormous negative environmental impact, the development of green mass concretes will eventually become as important as the thermal characteristics. Therefore, this paper investigates the use of Electric Arc Furnace (EAF) steel slag aggregate for the partial replacement of the natural aggregate in the production of mass concrete. The impact of EAF steel aggregate on mass concrete workability, strength, and thermal behaviour was analysed. In addition, a cradle-to-gate LCA study was conducted to evaluate the environmental footprint and sustainability potential of the tested mass concrete mixtures. The study results suggest that the use of EAF steel slag aggregate in combination with a low-heat cement with a high content of blast furnace slag can significantly lower the temperature, reduce the environmental impact, and increase the sustainability potential of mass concrete, while at the same time providing sufficient workability and compressive strength. The study results indicate that EAF steel slag can be upcycled into an aggregate for the production of green mass concrete mixtures. Keywords: mass concrete, thermal stress, EAF steel slag, green concrete, LCA, sustainability, open access Published in DiRROS: 31.05.2023; Views: 505; Downloads: 328
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6. Leaching and geochemical modelling of an electric arc furnace (EAF) and ladle slag heapMojca Loncnar, Ana Mladenovič, Vesna Zalar Serjun, Marija Zupančič, Hans A. van der Sloot, 2022, original scientific article Abstract: Old metallurgical dumps across Europe represent a loss of valuable land and a potential threat to the environment, especially to groundwater (GW). The Javornik electric arc furnace (EAF) and ladle slag heap, situated in Slovenia, was investigated in this study. The environmental impact of the slag heap was evaluated by combining leaching characterization tests of landfill samples and geochemical modelling. It was shown that throughout the landfill the same minerals and sorptive phases control the leaching of elements of potential concern, despite variations in chemical composi- tion. Although carbonation of the disposed steel slags occurred (molar ratio CO3/(Ca+Mg) = 0.53) relative to fresh slag, it had a limited effect on the leaching behaviour of elements of potential concern. The leaching from the slag heaps had also a limited effect on the quality of the GW. A site-specific case, however, was that leachates from the slag heap were strongly diluted, since a rapid flow of GW fed from the nearby Sava River was observed in the landfill area. The sampling and testing approach applied provides a basis for assessing the long-term impact of release and is a good starting point for evaluating future management options, including beneficial uses for this type of slag. Keywords: EAF slag, field verification, geochemical modelling, ladle slag, leaching, release prediction, steel slag heap Published in DiRROS: 28.04.2023; Views: 645; Downloads: 293
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