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21 - 30 / 2000
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21.
Development and characterization of gelatin-based hydrogels containing triblock copolymer and phytic acid
Njomza Ajvazi, Ingrid Milošev, Romana Cerc Korošec, Peter Rodič, Bojan Đ. Božić, 2024, original scientific article

Abstract: In recent research, significant interest has been directed towards gelatin-based hydrogels due to their affordable price, extensive availability, and biocompatibility, making them promising candidates for various biomedical applications. The development and characterization of novel hydrogels formed from varying ratios of gelatin, triblock copolymer Pluronic F-127, and phytic acid have been presented. Swelling properties were examined at different pH levels. The morphology of hydrogels and their thermal properties were analyzed using scanning electron microscopy (SEM), thermogravimetric analysis (TG), and differential scanning calorimetry (DSC). Fourier-transform infrared (FTIR) analysis of the hydrogels was also performed. The introduction of phytic acid in the hydrogel plays a crucial role in enhancing the intermolecular interactions within gelatin-based hydrogels, contributing to a more stable, elastic, and robust network structure.
Keywords: hydrogels, phytic acid
Published in DiRROS: 17.04.2025; Views: 61; Downloads: 25
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22.
Bilateral acrylic hip mold arthroplasty in a child with a revision 60 years after implantation : Clinical case and chemical analysis of endoprosthetic material
Samo Roškar, Ingrid Milošev, Rene Mihalič, Ema Žagar, Rihard Trebše, 2024, original scientific article

Abstract: A 68-year-old man was referred due to bilateral hip pain and gradual deterioration of walking. He had mold arthroplasties on both hips at the age of 7 years and has been functioning well for more than 5 decades. However, the original data on operative report and the prostheses were missing. The radiological examination revealed bilateral broken prosthetic material. Thus, stage bilateral revision total hip arthroplasty was performed. A detailed chemical analysis of retrieved mold arthroplasty implants proved that the acrylic material was noted to be the same composition with the difference in appearance likely being related to different thermal treatments originally applied to the implants. As presented in our clinical case, even obsolete implants may have good survivorship. According to the case presented, total hip arthroplasty could be considered an effective option with the desired functional outcome when conservative and joint-preserving measures are exhausted
Published in DiRROS: 17.04.2025; Views: 78; Downloads: 11
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23.
Enhanced mechanical properties and environmental stability of polymer-bonded magnets using three-step surface wet chemical modifications of Nd–Fe–B magnetic powder
Ana Damnjanović, Ingrid Milošev, Nataša Kovačević, 2024, original scientific article

Abstract: This research focuses on the surface modification of Nd–Fe–B magnetic powder to enhance its thermal and oxidation resistance without compromising magnetic properties and to improve adhesion to the polymer binder for enhanced mechanical properties. A three-step surface modification process involving phosphatization treatment, tetraethyl orthosilicate (TEOS) application, and 3-aminopropyltriethoxysilane (APTES) grafting, was applied to the powder, which was then compounded with polyamide 12 and injection-moulded into cylinders and dog-bone-shaped tubes. The resulting magnets exhibited remanence (Br) of 487.6 mT, coercivity (Hci) of 727.7 kA/m, and energy product (BHmax) of 39.3 kJ/m3. The modified magnets demonstrated exceptional corrosion resistance and thermal stability, with less than 5% irreversible flux loss after exposure to hot water, temperature shock, and pressurised steam. Furthermore, the modified magnets displayed significantly higher tensile strength, elongation at break, and elastic modulus with improvements of 62%, 16.7%, and 19.9%, respectively, compared to the non-modified batch. Additionally, the modified batch showed a notable 52% increase in flexural stress during flexural testing. These findings underscore the potential of silane surface modifications in producing injection-moulded permanent magnets based on Nd–Fe–B alloy, extending their shelf life and enhancing their overall performance.
Published in DiRROS: 17.04.2025; Views: 43; Downloads: 8
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24.
Corrosion inhibition of aluminium alloys by molybdate ions : a critical review of the chemistry, mechanisms and applications
Ingrid Milošev, 2024, review article

Abstract: Molybdate anions are used as an individual inhibitor or in mixed synergistic combinations added directly to the solution, incorporated as fillers, pigments or nanocontainers into various coatings (sol-gel, anodised, plasma electrolytic, organic and layer double hydroxide coatings), as an agent in pre-treatments or post-treatments or as individual conversion coatings prepared to be exposed to aggressive media. The review addresses the action of molybdate on aluminium alloys in each of these applications. The general chemical characteristics of molybdenum are described with a particular emphasis on aqueous chemistry and the formation of monomer and polynuclear species.
Keywords: aluminium, molybdate, corrosion inhibition
Published in DiRROS: 17.04.2025; Views: 70; Downloads: 19
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26.
On regular graphs with Šoltés vertices
Nino Bašić, Martin Knor, Riste Škrekovski, 2025, original scientific article

Abstract: Let W(G) be the Wiener index of a graph G. We say that a vertex vV(G) is a Šoltés vertex in G if W(Gv)=W(G), i.e. the Wiener index does not change if the vertex v is removed. In 1991, Šoltés posed the problem of identifying all connected graphs G with the property that all vertices of G are Šoltés vertices. The only such graph known to this day is C11. As the original problem appears to be too challenging, several relaxations were studied: one may look for graphs with at least k Šoltés vertices; or one may look for α-Šoltés graphs, i.e. graphs where the ratio between the number of Šoltés vertices and the order of the graph is at least α. Note that the original problem is, in fact, to find all 1-Šoltés graphs. We intuitively believe that every 1-Šoltés graph has to be regular and has to possess a high degree of symmetry. Therefore, we are interested in regular graphs that contain one or more Šoltés vertices. In this paper, we present several partial results. For every r1 we describe a construction of an infinite family of cubic 2-connected graphs with at least 2r Šoltés vertices. Moreover, we report that a computer search on publicly available collections of vertex-transitive graphs did not reveal any 1-Šoltés graph. We are only able to provide examples of large 13-Šoltés graphs that are obtained by truncating certain cubic vertex-transitive graphs. This leads us to believe that no 1-Šoltés graph other than C11 exists.
Keywords: Šoltés problem, Wiener index, regular graphs, cubic graphs, Cayley graph, Šoltés vertex
Published in DiRROS: 17.04.2025; Views: 68; Downloads: 20
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