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1.
Isotopic composition of carbon (▫$\delta$▫13C) and nitrogen (▫$\delta$▫15N) of petrologically different tertiary lignites and coals
Tjaša Kanduč, Miloš Markič, 2024, original scientific article

Abstract: This study investigates the carbon (δ13Corg) and nitrogen (δ15N) isotopic composition of tertiary lignites and coals from six sedimentary basins: Velenje, Mura-Zala, and Zasavje in Slovenia; Sokolov in Czech Republic, Barito in Indonesia; and Istria in Croatia. The aim is to investigate the correlation between the fine detrital (fD) component and δ13C and δ15N in Velenje lignite samples. Additionally, we aim to evaluate the biogeochemical processes of organic substances during their deposition in all analyzed samples, calculate their δ13CCO2 values and compare the analyzed values of δ13C and δ15N to those reported in the literature. Thirty-two samples were analyzed, predominantly from the Velenje ortho-lignite (Pliocene), with additional lignites and coals from the Pannonian to Paleocene epochs for comparison. Carbon isotopic composition (δ13Corg) ranged from -27.9 to -23.6 ‰, and nitrogen isotopic composition (δ15N) ranged from 1.8 to 7.4 ‰. The fine-detrital lithotypes of the Velenje ortho-lignite exhibited the most negative δ13Corg values due to anaerobic bacterial activity in an intramontane alkaline lake environment influenced by the carbonate hinterland. Moreover, gelification processes affected fine-detrital organic matter more than larger wooden pieces. Terbegovci, Hrastnik meta-lignites, and Barito sub-bituminous coal also displayed low δ13Corg values, indicating limited gelification, while variations in the δ15N values suggested differences in mineralization. The Velenje xylitic lithotypes have higher δ15N values, indicating a more intense mineralization under aerobic conditions. Raša ortho-bituminous coal, deposited in a brackish environment, displayed the highest δ13Corg values and a wide range of δ15N values due to fluctuating water tables in a paralic carbonate platform environment. The lowest δ15N value was observed in the Sokolov Basin lignite coal, indicating minimal mineralization and low bacterial activity. The isotopic composition of CO2 in air (δ13Cair), which was calculated using the δ13C values in lignites and coal, ranged from -8.4 to -3.4 ‰, with Velenje lignite displaying the minimum value and Raša coal showing the maximum value. The determined δ13C and δ15N values of the coal and lignite samples in this research fall within the typical range of world coals.
Keywords: lignite, coal, petrography, C and N isotopic composition, gelification, mineralization
Published in DiRROS: 09.07.2024; Views: 11; Downloads: 3
.pdf Full text (20,60 MB)

2.
Methodology for evaluating the CO2 sequestration capacity of waste ashes
Sara Tominc, Vilma Ducman, 2023, original scientific article

Abstract: The concentration of CO2 in the atmosphere is constantly increasing, leading to an increase in the average global temperature and, thus, affecting climate change. Hence, various initiatives have been proposed to mitigate this process, among which CO2 sequestration is a technically simple and efficient approach. The spontaneous carbonation of ashes with atmospheric CO2 is very slow, and this is why accelerated carbonation is encouraged. However, not all ashes are equally suitable for this process, so a methodology to evaluate their potential should be developed. Such a methodology involves a combination of techniques, from theoretical calculations to XRF, XRD, DTA-TG, and the calcimetric determination of the CaCO3 content. The present study followed the approach of exposing ashes to accelerated carbonation conditions (4% v/v CO2, 50–55% and 80–85% RH, 20 ◦C) in a closed carbonation chamber for different periods of time until the maximum CO2 uptake is reached. The amount of sequestered CO2 was quantified by thermogravimetry. The results show that the highest CO2 sequestration capacity (33.8%) and carbonation efficiency (67.9%) were obtained for wood biomass bottom ash. This method was applied to eight combustion ashes and could serve to evaluate other ashes or comparable carbon storage materials.
Keywords: CO2 sequestration, carbonation efficiency, coal ash, wood biomass ash, co-combustion ash, DTA-TG analysis
Published in DiRROS: 08.08.2023; Views: 500; Downloads: 224
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3.
Dataset for the article Methodology for evaluating the CO2 sequestration capacity of waste ashes
Vilma Ducman, Sara Tominc, 2023, complete scientific database of research data

Abstract: The dataset supports the data in the tables and figures in the article Methodology for evaluating the CO2 sequestration capacity of waste ashes (doi: 10.3390/ma16155284). It contains the original masses of waste ash before and during carbonation treatment, the sequestered CO2 masses after carbonation treatment, mass uptake calculations, calcimetric measurements, calculations of theoretical maximum sequestered CO2 (based on XRF results) and carbonation efficiency (CE), original results of DTA/TG analysis of individual ashes, original results of XRF measurement and data from XRD analyses supported by X-ray diffractograms not published in the article.
Keywords: CO2 sequestration, carbonation efficiency, coal ash, wood biomass ash, co-combustion ash, DTA-TG analysis
Published in DiRROS: 14.07.2023; Views: 763; Downloads: 326
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