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Iskalni niz: "ključne besede" (electrochemical corrosion techniques) .

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1.
Electrochemical corrosion tests on steel in alkali-activated materials
Nina Gartner, Miha Hren, Tadeja Kosec, Andraž Legat, 2021, objavljeni znanstveni prispevek na konferenci

Povzetek: One of the potential alternatives to Ordinary Portland Cement (OPC) are Alkali-Activated Materials (AAMs). The service life of reinforced concrete structures greatly depends on the corrosion resistance of embedded steel reinforcement. Due to the wide range of AAMs and their diverse properties, corrosion processes of steel in these materials are relatively unknown. Corrosion monitoring methods or their interpretations in certain cases cannot be directly transferred from the ones for OPC materials. The chemical compositions of pore solution in different AAMs influence the results of electrochemical measurements and their interpretations. Within this research, three different alkali-activated mortar mixes were prepared, based on fly ash, slag or metakaolin. Pore solutions were extracted from each mortar andchemical analysis was acquired. Different electrochemical corrosion measurements were performed on steel submerged to synthetic pore solutions. In parallel, ordinary carbon steel reinforcing bar was installed in the same types of alkali-activated mortar mixes. Specimens were exposed to wet/dry cycles with saline solution and periodic measurements of electrochemical impedance spectroscopy (EIS) were performed. Measured parameters in both systems were analysedand compared. It was concluded that electrochemical measurements in pore solutions can provide basic overview on corrosion behaviour in different AAMs environments. Periodic EIS measurements enabled monitoring of corrosion initiation and propagation on steel reinforcement in AAMs, although the information on the corrosion type is missing. Interpretation of results depends on visual analysis of corrosion damages after the end of exposure, providing information on corrosion type and intensity. The continuation of research on corrosion monitoring techniques will be performed by using Electrical Resistance (ER) sensors and Coupled Multi-Electrode Array (CMEA) sensors.
Ključne besede: corrosion, alkali-activated mortars, pore solution extraction, electrochemical corrosion techniques, visual analysis
Objavljeno v DiRROS: 22.01.2024; Ogledov: 223; Prenosov: 116
.pdf Celotno besedilo (9,29 MB)
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2.
The corrosion properties of steel in pore solutions obtained from alkali‐activated mortars
Nina Gartner, Tadeja Kosec, Stéphane Poyet, Andraž Legat, 2023, izvirni znanstveni članek

Povzetek: Alkali‐activated materials (AAMs) are considered a promising alternative to materials made from ordinary Portland cement (OPC). Other than considering the durability of the material itself, the use of AAMs for reinforced concrete elements also raises the question of steel corrosion processes in these materials, which are still relatively unknown. Three different alkali‐activated mortars were prepared for this study, based on either fly ash, slag, or metakaolin. Pore solutions were then extracted from each mortar and chemically analyzed. Electrochemical techniques were used to study the corrosion of steel in synthetic pore solutions containing varying concentrations of chlorides. In parallel, the same corrosion tests were performed in a generic pore solution representing OPC mortar. It was shown that the chemical composition differed in each pore solution tested, thus affecting the corrosion properties of the steel. The addition of chloride also had a varying effect on the corrosion properties of the steel in each type of pore solution tested. This study provided a basic overview of the corrosion behavior and mechanisms of the various AAM environments in comparison to that of OPC.
Ključne besede: alkali-aktivated materials, corrosion, electrochemical corrosion techniques, extracted pore solution
Objavljeno v DiRROS: 20.11.2023; Ogledov: 268; Prenosov: 48
.pdf Celotno besedilo (2,73 MB)
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