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Povzetek: Laser texturing with a dimple pattern was applied to modify a Ti6Al4V alloy at the micro level, aiming to improve its friction and wear resistance in combination with oil lubrication to optimize the performance in demanding industrial environments. The tribological analysis was performed on four different dimple-textured surfaces with varying dimple size and dimple-to-dimple distance and under lubrication with three different oils, i.e., T9, VG46, and VG100, to reflect the oil viscosity’s influence on the friction/wear of the laser-textured Ti6Al4V alloy. The results show that the surfaces with the highest texture density showed the most significant COF reduction of around 10% in a low-viscosity oil (T9). However, in high-viscosity oils (VG46 and VG100), the influence of the laser texturing on the COF was less pronounced. A wear analysis revealed that the laser texturing intensified the abrasive wear, especially on surfaces with a higher texture density. For low-texturing-density surfaces, less wear was observed for low- and medium-viscosity oils (T9 and VG46). For medium-to-high-texturing densities, the high-viscosity oil (VG100) provided the best contact conditions and wear results. Overall, reduced wear, even below the non-texturing case, was observed for sample 50–200 in VG100 lubrication, indicating the combined effect of oil reservoirs and increased oil-film thickness within the dimples due to the high viscosity.
Ključne besede: oil lubrication, surface modification, Ti-based alloy, tribology
Objavljeno v DiRROS: 01.02.2024; Ogledov: 188; Prenosov: 75
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Objavljeno v DiRROS: 31.01.2024; Ogledov: 154; Prenosov: 31
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Povzetek: As a surface-hardening technique, plasma nitriding is a common procedure for improving the properties of conventional Ni-based alloys. The diffusion of nitrogen hardens a layer on the surface of the alloy, leading to better wear resistance and a higher coefficient of friction, as well as a higher surface hardness. This study reports the effect of plasma nitriding on additive-manufactured (AM) Inconel 625 (IN625) compared to its conventional manufactured and nitrided counterparts. The samples produced with the laser powder-bed fusion (LPBF) process were subsequently plasma nitrided in the as-built condition, stress-relief annealed at 870 °C and solution treated at 1050 °C. The plasma nitridings were carried out at 430 °C and 500 °C for 15 h. The growth kinetics of the nitride layer of the AM samples depends on the prior heat treatments and is faster in the as-built state due to the specific cellular structure. The lower nitriding temperature leads to the formation of expanded austenite in the nitride layer, while at the higher nitriding temperature, the expanded austenite decomposes and CrN precipitation occurs. The XRD and SEM analyses confirmed the presence of two layers: the surface layer and the diffusion layer beneath. The lower nitriding temperature caused the formation of expanded austenite or a combination of expanded austenite and CrN. The higher nitriding temperature led to the decomposition of the expanded austenite and to the formation/precipitation of CrN. The higher nitriding temperature also decreased the corrosion resistance slightly due to the increased number of precipitated Cr-nitrides. On the other hand, the wear resistance was significantly improved after plasma nitriding and was much less influenced by the nitriding temperature.
Ključne besede: additive manufacturing, powder-bed fusion, plasma nitriding, expanded austenite, wear and corrosion resistance, Ni-based alloy
Objavljeno v DiRROS: 31.01.2024; Ogledov: 192; Prenosov: 80
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Povzetek: Background. The aim of the study was to emphasize the importance of surgical management of squamous cell carcinoma (SCC) in the head and neck to find the most important predictive factor for cervical lymph node metastasis and prognostic factor for survival. The use of multimodality therapy is being discussed as well. Patients and methods. From June 1st, 1992 to May 31st, 1998, 154 patients with oral cavity and oropharyngeal SCC were admitted to the Department of Otorhinolaryngology and Cervicofacial Surgery in the Teaching Hospital of Maribor. The criteria for inclusion into the study were met by 142 patients, but only 62/142 patients entered the multimodality protocol (surgery and postoperative radiotherapy). These 62/142 patients were treated surgically and 49 of them were postoperatively irradiated, while 13/62 declined postoperative radiotherapy. Surgical specimen was evaluated for positive or negative lymph nodes, tumor margins and the depth of invasion. Tumor cells were stained for Ki67 proliferative factor. Results. The depth of invasion was the most important predictive factor for the neck metastases in multivariate model including also the grade, pT and T. pN was found to be important in determining the overall survival using Cox regression model (p>0,05). A statistically important discrepancy between N and pN classification was found. In 23 cases N was overrated and in 3 cases underrated. The overall 5-year disease specific survival was 55%. Ki67 correlated with the grade of tumor differentiation. No statistically significant correlation was found with lymph node metastases. Conclusions. The depth of invasion is the most important determining the occurrence of the neck metastases whereas the N status determines the survival.
Objavljeno v DiRROS: 25.01.2024; Ogledov: 146; Prenosov: 38
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Povzetek: Današnje družbe si ni več mogoče predstavljati brez sodobne infrastrukture, ki temelji na uporabi različnih materialov ter zahteva veliko porabo energije. Vzporedno s proizvodnjo materialov, nastajajo ogromne količine različnih industrijskih in rudarskih ostankov (odpadki/stranski proizvodi), ki jih trenutno ne izkoriščamo, sama odlagališča pa so premalo raziskana. Cilj Evropske unije (EU) je povečati učinkovito rabo virov in ponudbo sekundarnih surovin z recikliranjem, popisom odpadkov iz rudarskih in drugih industrijskih dejavnosti ter njihova ponovna uporaba. Veliko industrijskih in rudarskih odpadkov je obogatenih z aluminijem (Al), zato lahko nadomeščajo naravne vire Al v mineralnih veznih, vendar njihova uporaba zahteva obsežno poznavanje njihovih kemijskih, mineraloških, radioloških in fizikalnih lastnosti. Priročnik, ki so ga pripravili partnerji projekta RIS-ALiCE obravnava zakonodajne vidike, ki urejajo uporabo sekundarnih surovin v gradbenih proizvodih, opis najpogostejših industrijskih in rudarskih ostankov, ki vsebujejo Al (nahajališča boksitov, rdeče blato, jeklarske žlindre, pepeli iz različnih industrij, itd.), potencial njihove ponovne uporabe in njihov ekonomski vidik, potencialne zahteve/ovire za uporabo sekundarnih surovin v cementni industriji in opis belitno-sulfoaluminatnih cementov, ki so obetavna rešitev za izvajanje krožnega gospodarstva z uporabo velikih količin odloženih industrijskih in rudarskih odpadkov, bogatih z Al.
Ključne besede: gradbeni proizvodi, ponovna uporaba, ekonomski vidik, industrija cementa, krožno gospodarstvo, industrijski odpadki, zakonodaja, elektronske knjige
Objavljeno v DiRROS: 22.01.2024; Ogledov: 214; Prenosov: 88
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