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Title:
Silver particle-decorated carbon paste electrode based on ionic liquid for improved determination of nitrite
Authors:
ID
Menart, Eva
(Author)
ID
Jovanovski, Vasko
(Author)
ID
Hočevar, Samo B.
(Author)
Files:
URL - Source URL, visit
http://ac.els-cdn.com/S1388248115000272/1-s2.0-S1388248115000272-main.pdf?_tid=90e136ce-ad36-11e4-ad66-00000aacb35d&acdnat=1423141239_d78e48c53d5e786729ad45bf210a6dc3
Language:
English
Typology:
1.01 - Original Scientific Article
Organization:
KI - National Institute of Chemistry
Abstract:
A simple silver particle-modified carbon paste electrode is proposed for the determination of low concentration levels of nitrite ions. The electrode consists of a carbon powder decorated with silver sub-micrometre particles (AgPs) and a hydrophobic ionic liquid trihexyltetradecylphosphonium chloride as a binder. It has been shown that AgPs exhibit a strong electrocatalytic effect on the nitrite oxidation. For optimal electroanalytical performance the electrode was conditioned via silver oxidation/reduction cycle. The electrode revealed a linear square-wave voltammetric response in a wide examined concentration range of 0.05 to 1.0 mmol L− 1, limit of detection (LOD) of 3 μmol L− 1 and excellent repeatability with RSD of 0.3%.
Keywords:
Silver particles
,
Square-wave voltammetry
,
Nitrite
,
Ionic liquid
,
Carbon paste electrode
Publication status:
Published
Year of publishing:
2015
Number of pages:
str. 45-48
Numbering:
Vol.52
PID:
20.500.12556/DiRROS-772
UDC:
620.1/.2
ISSN on article:
1388-2481
DOI:
10.1016/j.elecom.2015.01.017
COBISS.SI-ID:
5639706
Publication date in DiRROS:
16.02.2015
Views:
4910
Downloads:
625
Metadata:
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Record is a part of a journal
Title:
Electrochemistry communications
Shortened title:
Electrochem. commun.
Publisher:
Elsevier
ISSN:
1388-2481
COBISS.SI-ID:
2428442
Secondary language
Language:
Undetermined
Keywords:
elektrokemija
,
materiali
,
elektrode
,
nitrit
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