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Title:Towards increased strength and retained ductility of Zn-Mg-(Ag) materials for medical devices by adopting powder metallurgy processing routes
Authors:ID Kubásek, Jiří (Author)
ID Nečas, David (Author)
ID Hybášek, Vojtěch (Author)
ID Jablonská, Eva (Author)
ID Donik, Črtomir (Author)
ID Paulin, Irena (Author)
ID Gogola, Peter (Author)
ID Kusý, Martin (Author)
ID Fojt, Jaroslav (Author)
ID Čavojský, Miroslav (Author)
ID Duchoň, Jan (Author)
ID Čapek, Jaroslav (Author)
Files:.pdf PDF - Presentation file, download (14,67 MB)
MD5: A349BE9E750F149E82ED9AE8DC46D9FD
 
URL URL - Source URL, visit https://www.sciencedirect.com/science/article/pii/S2238785425016072
 
Language:English
Typology:1.01 - Original Scientific Article
Organization:Logo IMT - Institute of Metals and Technology
Abstract:The development of bioabsorbable zinc-based alloys with tailored mechanical properties and biocompatibility holds great promise for advancing medical implant technology. In this study, Zn-Mg and Zn-Mg-Ag alloys were synthesized using mechanical alloying (MA) followed by extrusion to achieve a combination of enhanced strength, ductility, and corrosion resistance. MA for 4 hours produced ultrafine-grained powders incorporating Mg₂Zn₁₁ intermetallic phases and oxide particles, which contributed to microstructure stabilization during subsequent processing. Extrusion consolidated these powders into dense materials with a uniform grain size of ~700 nm, exhibiting ultimate tensile strengths up to 435 MPa and elongation to fracture of ~12%, representing a significant improvement over conventional processing methods. The addition of silver further enhanced the antibacterial properties, demonstrating notable efficacy against Staphylococcus epidermidis, while maintaining non-cytotoxic behavior in vitro. Corrosion rates remained low, with uniform surface degradation and the formation of protective corrosion layers. This work highlights the efficacy of combining powder metallurgy techniques to bioabsorbable zinc-based alloys with exceptional mechanical performance, corrosion behavior and in vitro cytocompatibility, providing a pathway for next-generation biodegradable medical devices.
Keywords:zinc, bioabsorbable materials, mechanical alloying, spark plasma sintering, microstructure
Publication status:Published
Publication version:Version of Record
Publication date:08.07.2025
Publisher:Elsevier B. V.
Year of publishing:2025
Number of pages:str. 4345–4361
Numbering:Vol. 37
Source:Journal of materials research and technology
PID:20.500.12556/DiRROS-23190 New window
UDC:620.1:669.55
ISSN on article:2214-0697
DOI:10.1016/j.jmrt.2025.06.185 New window
COBISS.SI-ID:242216707 New window
Copyright:© 2025 The Authors
Note:Nasl. z nasl. zaslona; Soavtorji: Selase Torkornoo, David Nečas, Ingrid McCarroll, Vojtěch Hybášek, Baptiste Gault, Eva Jablonská, Črtomir Donik, Irena Paulin, Peter Gogola, Martin Kusý, Zdeněk Míchal, Jaroslav Fojt, Miroslav Čavojský, Jan Duchoň, Markéta Jarošová, Jaroslav Čapek; Opis vira z dne 16. 7. 2025;
Publication date in DiRROS:05.08.2025
Views:381
Downloads:237
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Record is a part of a journal

Title:Journal of materials research and technology
Publisher:Brazilian Metallurgical Materials and Mining Association, Elsevier
ISSN:2214-0697
COBISS.SI-ID:56382211 New window

Document is financed by a project

Funder:Czech Science Foundation
Project number:21–11439K

Funder:Other - Other funder or multiple funders
Funding programme:Programme Johannes Amos Comenius, call Excellent Research
Project number:CZ.02.01.01/00/22_008/0004634
Name:"Mechanical Engineering of Biological and Bio-inspired Systems"

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:N2-0182
Name:Razvoj naprednih biorazgradljivih materialov na osnovi Zn s tehnikami metalurgije prahov

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P2-0132
Name:Fizika in kemija površin kovinskih materialov

Funder:Deutsche Forschungsgemeinschaft (DFG)
Funding programme:Baptiste Gault’s Leibniz Award

Funder:Ministry of Education, Science, Research and Sport of the Slovak Republic
Funding programme:Vega
Project number:1/0531/22
Name:Influence of Zn-based alloy stress state on the mechanism and kinetics of their corrosion

Funder:European Cooperation in Science and Technology
Project number:CA22147
Name:European metal-organic framework network: combining research and development to promote technological solutions (EU4MOFs)

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:24.06.2025
Applies to:Text and Data Mining valid from 2025-07-01 Version of Record valid from 2025-06-24

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