461. Influence of ammonium polyphosphates and 2,4,6-triamino-1,3,5-triazine on the mechanical-physical properties of polyurethane and alkali-activated materialsBranka Mušič, Barbara Horvat, 2024, published scientific conference contribution Abstract: In building constructions, the tendency towards an ever-better material directs us to composite materials. In this work, we prepared an organic-organic and organic-inorganic composite material by incorporating fire retardants, ammonium polyphosphates, and 2,4,6-triamino-1,3,5-triazine, into a polyurethane network and an aluminosilicate network (ASN) of alkali-activated material. Polyurethane foams (PUR) are well-known materials that, due to their properties, such as low weight-to-strength ratio, low electrical and thermal conductivity, flexibility, and relatively simple preparation process, are used in various industries, also in the construction industry, e.g., for thermal insulation of windows and doors or fixing and sealing joinery. Opposite, the ASN of alkali-activated metakaolin, successfully paves the way for new applications, such as high-temperature protection. In this paper, these interactive properties of prepared composites are studied using thermal testing and mechanical analysis. It was found that inhibitors significantly increase the fire resistance of PUR systems while they slightly reduce the mechanical properties. Incorporating polymer flame retardant into ASN in building products, such as façade panels , can decrease the mechanical properties but can offer the non-flammable building envelope not get heated from burning surroundings, i.e., not becoming a convection heat source, but rather represent a fire-distinguisher for flammable materials.
Keywords: flame retardants, polyurethane, alkali activated material, metakaolin, microwave irradiation, mechanical strength
Published in DiRROS: 12.03.2024; Views: 94; Downloads: 46
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462. Waste rubber incorporated in the alkali-activated metakaolin’s aluminosilicate network enhanced by microwave irradiationBarbara Horvat, Branka Mušič, 2024, published scientific conference contribution Abstract: Building materials represent the possibility of prolonging the life of waste materials. The key is to ensure that the products are suitable for their function. So we activated metakaolin with the alkaline Na-silicate solution in the ratio that ensures the prevention of efflorescence and high mechanical strength (Horvat and Ducman, 2019). As the waste material (to be incorporated in the aluminosilicate network (ASN) of the alkali-activated metakaolin) ground waste rubber from electric cables was used in the preselected mass ratios. Its inclusion in products, like paving stones, can reduce stiffness, improve durability, dampen vibrations, and reduce road noise. The mechanical strengths of test samples with rubber present on the active surface or slightly below were higher compared to samples where rubber was encapsulated throughout the volume. Compressive strength was higher when samples were irradiated with low powers of microwaves while irradiation with higher powers led to the foaming of alkali-activated slurry. The encapsulation quality of the ground rubber was evaluated by SEM while the chemical influence on ASN was determined by EDS, FTIR, and XRD. Slipperiness change on the active surface of pavement stones proved that the addition of the ground rubber enhanced the walking safety of the product.
Keywords: secondary raw material, alkali activated material, waste rubber, metakaolin, encapsulation of organic in inorganic material, microwave irradiation, mechanical strength
Published in DiRROS: 12.03.2024; Views: 100; Downloads: 47
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463. European genetic resources conservation in a rapidly changing world : three existential challenges for the crop, forest and animal domains in the 21st centuryFrançois Lefévre, Danijela Bojkovski, Magda Bou Dagher Kharrat, Michele Bozzano, Eléonore Charvolin-Lemaire, Sipke Joost Hiemstra, Hojka Kraigher, Denis Laloë, Gwendal Restoux, Suzanne Sharrock, Enrico Sturaro, Theo J. L. van Hintum, Marjana Westergren, Nigel Maxted, 2024, original scientific article Abstract: Even though genetic resources represent a fundamental reservoir of options to achieve sustainable development goals in a changing world, they are overlooked in the policy agenda and severely threatened. The conservation of genetic resources relies on complementary in situ and ex situ approaches appropriately designed for each type of organism. Environmental and socioeconomic changes raise new challenges and opportunities for sustainable use and conservation of genetic resources. Aiming at a more integrated and adaptive approach, European scientists and genetic resources managers with long experience in the agricultural crop, animal and forestry domains joined their expertise to address three critical challenges: (1) how to adapt genetic resources conservation strategies to climate change, (2) how to promote in situ conservation strategies and (3) how can genetic resources conservation contribute to and benefit from agroecological systems. We present here 31 evidence-based statements and 88 key recommendations elaborated around these questions for policymakers, conservation actors and the scientific community. We anticipate that stakeholders in other genetic resources domains and biodiversity conservation actors across the globe will have interest in these crosscutting and multi-actor recommendations, which support several biodiversity conservation policies and practices.
Keywords: agroecology, climate change, in situ conservation, multi-actor engagement, policy
Published in DiRROS: 11.03.2024; Views: 152; Downloads: 64
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465. Harmonised statistics and maps of forest biomass and increment in EuropeValerio Avitabile, Roberto Pilli, Mirco Migliavacca, Bogdan Grégory Henry E. Duveiller, Andrea Camia, Viorel Blujdea, Radim Adolt, Iciar Alberdi, Susana Barreiro, Susann Bender, Mitja Skudnik, 2024, original scientific article Abstract: Forest biomass is an essential resource in relation to the green transition and its assessment is key for the sustainable management of forest resources. Here, we present a forest biomass dataset for Europe based on the best available inventory and satellite data, with a higher level of harmonisation and spatial resolution than other existing data. This database provides statistics and maps of the forest area, biomass stock and their share available for wood supply in the year 2020, and statistics on gross and net volume increment in 2010–2020, for 38 European countries. The statistics of most countries are available at a sub-national scale and are derived from National Forest Inventory data, harmonised using common reference definitions and estimation methodology, and updated to a common year using a modelling approach. For those counties without harmonised statistics, data were derived from the State of Europe’s Forest 2020 Report at the national scale. The maps are coherent with the statistics and depict the spatial distribution of the forest variables at 100 m resolution.
Keywords: harmonised statistics, harmonised maps, forest biomass, gorest increment, Europe
Published in DiRROS: 11.03.2024; Views: 110; Downloads: 54
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470. Analysis of alkali-activated mineral wool-slag binders : evaluating the differences between one-part and two-part variationsElijah Adesanya, Rawia Dabbebi, Christine Rößler, Majda Pavlin, Zhenming Li, Tero Luukkonen, Juho Yliniemi, Mirja Illikainen, 2024, original scientific article Abstract: Two synthesis pathways (one- and two-part) in alkali-activated binders were compared using ground granulated blast furnace slag (GGBFS), mineral wool (MW) activated using dry and liquid alkali activators with similar Na2O/SiO2 modulus. The effect of activator type on reaction kinetics, strength development, setting times, and durability shows that one-part synthesis does not only improve early strength, but also provide better durability properties. While the highest compressive strength (56 MPa, 90 days) was achieved for the one-part mix (DM), the reaction products (presence of Mg–Al layered double hydroxide and C–S–H-like phases) observed for both mortar mixes were similar. The DM mortars showed better resistance to sulfate attack than two-part mix (WM) mortars and sets faster. The results highlight the significance of the one-part pathways in the synthesis of alkali-activated materials.
Keywords: recycling, alkali activated material, mineral wool
Published in DiRROS: 11.03.2024; Views: 107; Downloads: 76
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