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1.
Evolution of surface functional groups and aromatic ring degradation upon treatment of polystyrene with hydroxyl radicals
Alenka Vesel, Rok Zaplotnik, Gregor Primc, Miran Mozetič, 2023, izvirni znanstveni članek

Povzetek: The surface properties of hydrocarbon polymers are inadequate for numerous applications. Hence, they require alteration via functionalisation with desired functional groups. Hydroxyl groups are often preferred, since they enable appropriate polarity for the irreversible grafting of desired molecules. In this study, the surface kinetics resulting from the treatment of polystyrene with hydroxyl (OH) radicals from the gas phase was fundamentally investigated through a precisely-designed experiment. Polystyrene samples were exposed to various known fluences of OH radicals, and the evolution of surface functional groups versus the OH fluence was monitored using high-resolution X-ray photoelectron spectroscopy (XPS). The fluences of OH radicals varied between 1 × 1018 and 4 × 1023 m−2 in the process of finding a threshold fluence for the formation of specific groups. The surface concentration of carbonyl (C=O) groups could be measured using XPS at a fluence of approximately 5 × 1020 m−2. The C=O groups became measurable at a fluence of approximately 1.5 × 1021 m−2, and carboxyl (COOH)/ester groups at approximately 4 × 1021 m−2. As deduced from the XPS, a concentration of C=O groups at approximately 5 % occurred before the degradation of the aromatic ring. The formation of other oxygen-functional groups required opening of the aromatic ring. The results have been explained using a two-step process, considering available theories vis-a-vis initial stages in the functionalisation of PS with polar functional groups.
Ključne besede: polistiren, kinetika površinske funkcionalizacije, OH radikali, vpliv doze radikalov, časovni razvoj, polystyrene, surface functionalisation kinetics, OH radicals
Objavljeno v DiRROS: 09.11.2023; Ogledov: 287; Prenosov: 120
URL Povezava na datoteko

2.
Novel thermal insulation with gas-filled cavities - assessment of thermal performance of different designs based on numerical simulations of heat transfer
Miha Jukić, Sabina Jordan, Danijel Lisičić, 2019, izvirni znanstveni članek

Povzetek: Not only is the energy efficiency of buildings nowadays becoming more and more important; the legislative requirements, the people’s awareness of the environmental questions and their thermal comfort expectations are also on a much higher level. All of these issues can be addressed by making the building envelope more thermally resistant. However, with the traditional thermal insulation materials the thickness of thermal insulation layers is already at the viable limits. Therefore, the development of new, more efficient thermal insulation products with a higher thermal resistance is highly promoted. Preliminary research results can be applied to models to develop and confirm the conceptual designs of such new materials. In this paper, an analysis of thermal performance is presented for a novel thermal insulation consisting of graphite polystyrene (GPS) matrix with cavities filled with an insulative gas, and a protective sheath to prevent it from leaking. Bearing in mind the suitability for later production, different configurations of the assembly were considered, regarding the matrix geometry, the type of the gas filling, and the surface emissivity of the cavities. A range of numerical simulations of heat transfer was conducted to determine the efficiency of different designs in reducing the conductive, the convective, and the radiative heat transfer. Advantages, limitations and some detailed parameters of the proposed design concepts were determined, which were then used for optimisation. The analysis of the results indicates that the equivalent thermal conductance of a GPS panel can be significantly reduced by the introduction of gas-filled cavities. The reduction is highly dependent on the type of the gas filling (thermal conductivity, viscosity, specific heat, etc.), the size of the cavities, and the cavity surface emissivity.
Ključne besede: gas-filled cavities, graphite polystyrene, numerical simulation, thermal insulation
Objavljeno v DiRROS: 15.09.2023; Ogledov: 262; Prenosov: 122
.pdf Celotno besedilo (1,21 MB)
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