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1.
Comparison of elemental composition of surface and subsurface soils on national level and identification of potential natural and anthropogenic processes influencing its composition
Emil Pučko, Gorazd Žibret, Klemen Teran, 2024, original scientific article

Abstract: The elemental composition of soils is governed by geogenic processes and anthropogenic activities. A comprehensive soil study was conducted on a national level, in which the elemental composition of soils from two different layers was compared with the intention to differentiate between natural and anthropogenic sources of elemental enrichments. Topsoil (0–5 cm) and subsoil (20–30 cm) samples were collected from 249 different locations on a national scale (Slovenia). Elemental composition for 55 major, minor, and trace elements (ICP-MS, aqua regia digestion) was determined on the fraction <0.063 mm. By calculating the enrichment ratios in different lithological units, it was determined that levels of Ti are higher in soils overlying metamorphic and igneous rocks, Zr and Ca are more abundant over carbonates, while levels of Ni are higher in soils overlying marlstones. Elevated levels of Hg were detected in subsoils in the historical Hg mining area in Idrija, which indicates the presence of nearby orebodies as a potential source for the geochemical anomaly. Spatial distribution of elements showed that higher levels of Pb, Zn, Cu, and Hg were detected in topsoils of urban areas, indicating that anthropogenic sources could be the potential cause of soil contamination. Pb, Zn, Cu, and Hg levels were up to four times higher in topsoils compared to subsoils sampled at historical mining areas (e.g., Mežica, Idrija, Litija), which shows that historical mining left a significant environmental impact. Although mining and smelting activities ended a few decades ago, soils in some areas are still heavily enriched with various metals. Some other potential anthropogenic sources of elements were identified, such as farming and ironworks. Based on the results of this study, we can conclude that by comparing elemental compositions of soils from different layers, we can recognise the origin of elemental enrichments.
Keywords: smelting, mining, urbanisation, traffic, ironworks, weathering
Published in DiRROS: 18.03.2024; Views: 98; Downloads: 37
.pdf Full text (16,11 MB)

2.
Mining waste in circular economy - legislative aspect
Senko Pličanič, Ana Mladenovič, Alenka Mauko Pranjić, Petra Vrhovnik, 2020, original scientific article

Abstract: One of the common European commitments is a transition towards a green circular economy in which waste is not discarded and considered to be just an environmental problem, but should be recognized as an important potential source of raw materials for industry. In a priority order in waste management activities, introduced by the Waste Directive in 2012, recycling is set just behind the waste prevention and reuse. Many types of waste can be recycled, the most perspective being construction, industrial and mining wastes. The latter are produced and disposed of at mine sites during the excavation and processing of ore and are extremely perspective due to large quantities and remaining of different metals, however still underutilized, with low recycling rate. Many mining wastes are inert and do not releases contaminants into environment, however, some of them are problematic and even require monitoring. Reprocessing of these wastes, which include beneficiation and sequential extraction of valuable metals in the first phase and recycling of residues in both structural and civil engineering in the second phase establishes a zero waste model with several benefits for economy, environment and society. Out of the South-East European countries, North Macedonia has great potential to establish this model. As a consequence of long mining tradition and abundant ore resources, there are many mining and metallurgical tailings, on the other hand vivid economy and numerous sinks for use of recycled materials in construction sector can accommodate these quantities. However, there are open questions in terms of administrative procedures and legislation. What are those obstacles that accompany the smooth establishment of the proposed model from a legislative point of view? This paper deals with the situation in North Macedonia, in terms of opportunities, legislative options and the need to adopt new legislation, taking also into account the current problems in this field in Europe.
Keywords: circular economy, zero-waste approach, mining waste, construction sector, legislation, krožno gospodarstvo, pristop ničelnega odpadka, rudarski odpadki, gradbeništvo, zakonodaja
Published in DiRROS: 04.12.2023; Views: 215; Downloads: 127
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3.
The importance of educating younger generations about raw materials and their uses in our daily life
Kim Mezga, Petra Vrhovnik, Janja Žmavc, Lidia Gullon, 2021, original scientific article

Abstract: Raw materials are of great importance for humankind as they enable the development of technology, drive industry and economy, and overall the lifestyle we know today. The paper is addressing the topic of interactive learning about the mineral raw materials, i.e. metals and non-metals. Due to population growth and consequently in-creased global demand for raw materials, there is a need to educate younger generations about the raw materials and their properties and origin, so they would know from an early age where the mineral products they use come from and how purchase decisions affect the social environments of people who live in countries with resources exploitation.Todayʼs trends in mining are oriented towards more sustainable exploitation and management, taking into account the economic, social and environmental aspects. An example of such is exploitation of secondary raw materials from tail-ings and heaps. But in some countries, mining is stuck in the past, using obsolete technologies causing increased pol-lution and strongly present linear economy approaches of take-use-dispose attitudes or even unethical approaches, such as children being exploited as a cheap workforce, people being abducted, tortured and even killed over minerals (min-erals being exploited in such way are called blood or conflict minerals). Further, due to the potential negative impacts on health and safety, due to the emissions in air, water and surface disturbance, the public perception of mining is still perceived as negative in most cases. School curriculums most often lack description of current situations in the global mining. Therefore, within the EIT RawMaterials BRIEFCASE and 3D BRIEFCASE projects the project partners provide the comprehensive view of the issues of todayʼs mining and use of raw materials. The paper presents the description of both projects and the non-conventional teaching methods - the hands-on and digital tools for pupils and teachers, i.e. the briefcases, the "Briefcase of mineral applications" game, workshops and the supporting materials. The main objective of projects is to raise the pupils awareness about the utility and indispensability of minerals and mining and the consequences of their uses and production systems, which would increasein the long term the awareness about the social and environmental consequences of raw material production.
Keywords: raw materials, mining, pupils and students, non-conventional teaching tools, BRIEFCASE, 3D BRIEFCASE, curricular planning, EIT RawMaterials
Published in DiRROS: 04.12.2023; Views: 226; Downloads: 104
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4.
Evasion of gaseous elemental mercury from forest and urban soils contaminated by historical and modern ore roasting processes (Idrija, Slovenia)
Federico Floreani, Elena Pavoni, Mateja Gosar, Stefano Covelli, 2023, original scientific article

Abstract: Considerable amounts of gaseous elemental mercury (Hg0) can be released into the atmosphere from Hg-enriched substrates, such as those from former mining areas, posing a potential environmental threat. In this work, Hg0 fluxes at the soil–air interface under natural vegetation covers were measured in various locations within the Idrija Hg mining area (Slovenia) and its surroundings. Sites were selected in order to compare Hg0 fluxes from both forest soils heavily impacted by historical ore roasting and urban soils characterised by a different degree of Hg enrichment due to the natural occurrence of Hg in rocks or recent mining and roasting processes. Replicate measurements at each site were conducted using a non-steady state flux chamber coupled with a real-time Hg0 analyser (Lumex RA-915M). Moreover, topsoil samples (0–2 cm) were analysed for Hg total concentration and speciation. Cinnabar was the predominant Hg form in almost all the sites. Despite Hg0 being undetectable in soils using thermo-desorption, substantial emissions were observed (70.7–701.8 ng m−2 h−1). Urban soils in a naturally enriched area showed on average the highest Hg0 fluxes, whereas relatively low emissions were found at the historical roasting site, which is currently forested, despite the significantly high total Hg content in soils (up to 219.0 and 10,400 mg kg−1, respectively). Overall, our findings confirm that shading by trees or litter may effectively limit the amount of Hg0 released into the atmosphere even from extremely enriched soils, thus acting as a natural mitigation.
Keywords: legacy soil contamination, Hg mining, gaseous Hg fluxes, flux chamber, ore roasting, Hg speciation
Published in DiRROS: 30.06.2023; Views: 403; Downloads: 113
.pdf Full text (3,86 MB)

5.
FooDis : a food-disease relation mining pipeline
Gjorgjina Cenikj, Tome Eftimov, Barbara Koroušić-Seljak, 2023, original scientific article

Abstract: Nowadays, it is really important and crucial to follow the new biomedical knowledge that is presented in scientific literature. To this end, Information Extraction pipelines can help to automatically extract meaningful relations from textual data that further require additional checks by domain experts. In the last two decades, a lot of work has been performed for extracting relations between phenotype and health concepts, however, the relations with food entities which are one of the most important environmental concepts have never been explored. In this study, we propose FooDis, a novel Information Extraction pipeline that employs state-of-the-art approaches in Natural Language Processing to mine abstracts of biomedical scientific papers and automatically suggests potential cause or treat relations between food and disease entities in different existing semantic resources. A comparison with already known relations indicates that the relations predicted by our pipeline match for 90% of the food-disease pairs that are common in our results and the NutriChem database, and 93% of the common pairs in the DietRx platform. The comparison also shows that the FooDis pipeline can suggest relations with high precision. The FooDis pipeline can be further used to dynamically discover new relations between food and diseases that should be checked by domain experts and further used to populate some of the existing resources used by NutriChem and DietRx.
Keywords: text mining, relation extraction, named entity recognition, named entity linking, food-disease relations
Published in DiRROS: 25.05.2023; Views: 353; Downloads: 168
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6.
From language models to large-scale food and biomedical knowledge graphs
Gjorgjina Cenikj, Lidija Strojnik, Risto Angelski, Nives Ogrinc, Barbara Koroušić-Seljak, Tome Eftimov, 2023, original scientific article

Abstract: Knowledge about the interactions between dietary and biomedical factors is scattered throughout uncountable research articles in an unstructured form (e.g., text, images, etc.) and requires automatic structuring so that it can be provided to medical professionals in a suitable format. Various biomedical knowledge graphs exist, however, they require further extension with relations between food and biomedical entities. In this study, we evaluate the performance of three state-of-the-art relation-mining pipelines (FooDis, FoodChem and ChemDis) which extract relations between food, chemical and disease entities from textual data. We perform two case studies, where relations were automatically extracted by the pipelines and validated by domain experts. The results show that the pipelines can extract relations with an average precision around 70%, making new discoveries available to domain experts with reduced human effort, since the domain experts should only evaluate the results, instead of finding, and reading all new scientific papers.
Keywords: biomedical knowledge graphs, relation-mining pipelines, relation extraction, validation
Published in DiRROS: 17.05.2023; Views: 380; Downloads: 153
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