1. Atmosphere–cryosphere interactions during the last phase of the Last Glacial Maximum (21 ka) in the European AlpsCostanza Del Gobbo, Renato R. Colucci, Giovanni Monegato, Manja Žebre, Filippo Giorgi, 2023, original scientific article Abstract: Evidence that during the Last Glacial Maximum (LGM) glaciers extended well into the piedmont plains is still identifiable in the alpine foreland as a system of well-preserved moraines. Glaciers are strongly controlled by temperature and precipitation, and therefore, they are excellent indicators of climate change. Here, we use a regional climate model (RCM) to investigate some of the physical processes sustaining Alpine glaciers during the last phase of the LGM during Greenland Stadial 2 at 21 ka. We find a predominance of convection during summer and increased southwesterly stratiform precipitation over the southern Alps when compared to pre-industrial (PI) conditions. This precipitation pattern, along with lower temperatures, determined summer snowfall extending to low elevations, with a consequent substantial drop of the equilibrium line altitude (ELA), which is consistent with the estimated LGM glacier extent. Our RCM-based estimates of 21 ka ELA at the LGM yield excellent consistency with Alpine ELA reconstructions, further demonstrating the great potential of this technique for use in palaeoclimate studies.
Keywords: Quaternary, ice age, atmosphere, glaciers, climate change, the Alps
Published in DiRROS: 19.09.2023; Views: 357; Downloads: 124
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2. Electrochemical cycling behaviour and shape changes of Zn electrodes in mildly acidic aqueous electrolytes containing quaternary ammonium saltsBenedetto Bozzini, Marco Boniardi, Tommaso Caielli, Andrea Casaroli, Elisa Emanuele, Lucia Mancini, Nicola Sodini, Jacopo Strada, 2023, original scientific article Abstract: Secondary Zn–based batteries are a valid alternative to Li for stationary storage, but commercial devices are not yet available, chiefly owing to anode shape-change and passivation issues. Mildly acidic aqueous solutions are actively studied, since they seem to limit unstable growth of Zn, with respect to the alkaline ones, customary for primary batteries. Additives can further improve the performance of mildly acidic electrolytes. In this work we focus on the impact of a series of quaternary ammonium salts (TBAB, CTAB, DMDTDAB, BDMPAC, BPPEI, PDADMAC), selected to represent a comprehensive range of molecular functionalities. Electrochemical measurements (cyclic voltammetry, chronopotentiometry and galvanostatic-cycling in split-cells), combined with 2D and 3D imaging techniques (SEM, stereomicroscopy and in situ tomography) were adopted for the assessment Zn behaviour. This multi-technique approach pinpointed TBAB as the single most effective additive for low-current density operation, while at high current densities the additive-free electrolyte allows better cycling performance, coherently with similar results for alkaline electrolytes.
Keywords: battery, electrolyte, electrochemical measurements, quaternary Ammomium salt, X-ray computed microtomography, mobility
Published in DiRROS: 06.07.2023; Views: 365; Downloads: 160
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3. Pan-European phylogeography of the European roe deer (Capreolus capreolus)Kamila Plis, Magdalena Niedziałkowska, Tomasz Borowik, Johannes Lang, Mike Heddergott, Juha Tiainen, Aleksey Bunevich, Nikica Šprem, Ladislav Paule, Aleksey A. Danilkin, Marina Kholodova, Elena Zvychaynaya, Nadezhda Kashinina, Boštjan Pokorny, Katarina Flajšman, 2022, original scientific article Abstract: To provide the most comprehensive picture of species phylogeny and phylogeography of European roe deer (Capreolus capreolus), we analyzed mtDNA control region (610 bp) of 1469 samples of roe deer from Central and Eastern Europe and included into the analyses additional 1541 mtDNA sequences from GenBank from other regions of the continent. We detected two mtDNA lineages of the species: European and Siberian (an introgression of C. pygargus mtDNA into C. capreolus). The Siberian lineage was most frequent in the eastern part of the continent and declined toward Central Europe. The European lineage contained three clades (Central, Eastern, and Western) composed of several haplogroups, many of which were separated in space. The Western clade appeared to have a discontinuous range from Portugal to Russia. Most of the haplogroups in the Central and the Eastern clades were under expansion during the Weichselian glacial period before the Last Glacial Maximum (LGM), while the expansion time of the Western clade overlapped with the Eemian interglacial. The high genetic diversity of extant roe deer is the result of their survival during the LGM probably in a large, contiguous range spanning from the Iberian Peninsula to the Caucasus Mts and in two northern refugia.
Keywords: Capreolus capreolus, expansion, mitochondrial DNA, the Last Glacial Maximum refugia, the Quaternary history, Phylogenetics
Published in DiRROS: 26.05.2022; Views: 609; Downloads: 422
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