91. Toksikološka analiza vsebine vojaških čutar, zakopanih 70 let v kraški jami na Kočevskem, JV SlovenijaJanez Mulec, Sara Skok, Vesna Zalar Serjun, Andrej Mihevc, 2019, original scientific article Abstract: Za odkrivanje ostankov materialnih sledi se na dobro ohranjenih predmetih lahko opravijo forenzične preiskave. V Breznu v Debliških livadah je bilo odkritih večje število predmetov, ki so bili odvrženi v jamo v maju in juniju 1945. Med odkritim materialom so bile tudi vojaške čutare. Nekatere izmed čutar so še vsebovale tekočino, nekatere pa tudi poltrdo, gelasto oborino. Tekočina in oborina iz čutar sta vsebovali kovine, ki so se najverjetneje s časom izlužile iz kovinske posode. Korozija čutar nakazuje prisotnost minerala hematita. Vsebina čutar je nadalje vsebovala nekaj raztopljene organske snovi (celotni organski ogljik – TOC v tekočini 9,22 mg/l, v tekočini ekstrahirane oborine 34,1 mg/l), nekaj mikrobne biomase ter relativno visoke koncentracije nitrata (240 mg/l v tekočini, 55 mg/l v ekstrahirani oborini) in sulfata (18mg/l v tekočini, 836 mg/l v ekstrahirani oborini). Bakterijskih indikatorjev, Escherichia coli in enterokokov, ki bi kazali na fekalno kontaminacijo vsebine, v vzorcih nismo zaznali. Raztopina in oborina sta izkazovali podobno stopnjo toksičnosti, okrog 20%inhibicijo bioluminiscence bakterije Vibrio fischeri. Glede na Pravilnik o pitni vodi tekočina s sedanjimi kemijskimi lastnostmi ni primerna za uživanje. Rezultati ne kažejo nujno na toksičnost izvornih tekočin iz časa, ko so bile čutare odvržene v jamo, ampak bi se toksičnost lahko razvila postopoma zaradi izluževanja kovin iz posode, zlasti aluminija, in (bio)kemijskih reakcij. Navkljub stabilnim jamskim razmeram, ki so jim bile izpostavljene čutare, ugotovljeni parametri ne podpirajo dolgoročne ohranitve stabilne DNA za morebitne nadaljnje forenzične analize.
Keywords: jame, vojaški material, toksičnost
Published in DiRROS: 23.11.2023; Views: 238; Downloads: 134
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92. Patologija malignih tumorjev dojkeJanez Lamovec, 1998, review article Abstract: Merfološka opredelitev tumorjev dojke po načelih moderne kirurške patologije tumorja daje kliniku poleg osnovnih podatkov o naravi tumorja tudi pomembne prognostične informacije. Pri karcinomu dojke so med njimi na vrhu pomembnosti: stanje aksilarnih bezgavk (pozitivne ali negativne bezgavke), stopnja malignosti tumorja, velikost tumorja, verjetno tudi histološki tip. Z razvojem modernih tehnologij lahko tako patolog kot klinik uporabljata še mnoge nove metode, s katerimi opredeljujeta tumor tudi biokemično in molekularno. Zaenkrat pa vse te nove opredelitve še ne dosegajo prognostične veljave klasičnih morfoloških lastnosti. Prav zato pa mora patolog skrbno upoštevati priporočila in pravila o obdelavi kirurškega vzorca, da lahko opredeli vrsto morfoloških lastnosti, ki vsebujejo največ napovedno veljavnih podatkov. V članku govorim o osnovnih morfoloških metodah, o posameznih pomembnejših tumorjih dojke ter o nekaterih novih biokemičnih in molekularnih metodah v diagnostiki raka dojke.
Published in DiRROS: 22.11.2023; Views: 238; Downloads: 74
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93. Smernice za zagotavljanje gozdnega reprodukcijskega materiala : predlog pripravljen v okviru projekta LIFEGENMONKristina Sever, Boris Rantaša, Marijana Vidrih Minić, Natalija Dovč, Janez Kermavnar, Marjana Westergren, Gregor Božič, Matjaž Guček, Andrej Breznikar, Aleš Poljanec, Hojka Kraigher, 2021, treatise, preliminary study, study Keywords: gozdni reprodukcijski material, gozdni semenski objekti, provenienčna območja, vrste, genetska pestrost
Published in DiRROS: 14.11.2023; Views: 400; Downloads: 131
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95. Optimization method based on simplex for surface area improved photocatalytic performance of ▫$g-C_3N_4$▫Matevž Roškarič, Janez Zavašnik, Dániel Dániel Zámbó, Tomaž Kotnik, Sebastijan Kovačič, Gregor Žerjav, Albin Pintar, 2023, original scientific article Abstract: The main objective of the present study was to increase the specific surface area (SBET) of graphitic carbon nitride (g-C3N4) prepared from dicyandiamide by effectively modifying the synthesis procedure using the Simplex optimization method. A remarkable increase in SBET was achieved in only a few steps, with the highest value of 86 m2/g. Compared to the reference material, the improved photocatalyst exhibited enhanced and unique structural, textural, optical, and electronic properties, reflected in the improved ability of the photocatalyst to degrade a variety of organic pollutants dissolved in water. By performing scavenger and spin-trapping experiments, it was confirmed that the major reactive oxygen species formed under visible-light illumination of the enhanced photocatalyst were singlet oxygen (1O2) and superoxide anion radicals (O2–•) with a purposed formation mechanism. The enhanced formation of 1O2 enabled high activity and stability of the optimized materials as well as selective response to degradation of the pharmaceutical compounds studied. By using the simple and fast Simplex optimization algorithm to determine new synthesis parameters, we obtained an improved g-C3N4 that completely degrades bisphenol A under the conditions studied.
Published in DiRROS: 08.11.2023; Views: 264; Downloads: 144
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97. Influence of laser colour marking on the corrosion properties of low alloyed TiTadeja Kosec, Andraž Legat, Janez Kovač, Damjan Klobčar, 2019, original scientific article Abstract: In the field of surface treatment, laser colour marking can be used to produce coloured marks on the surfaces of metals. Laser colour markings can be applied to various materials, but on titanium alloys a wide spectra of vivid colours can be achieved. This study presents an analysis of the corrosion properties of laser treated surfaces that were exposed to aggressive environments. Different samples were prepared with laser light of various power intensities and processing speeds. The samples were prepared on low alloyed Ti. Electrochemical, spectroscopic and microstructural analyses were conducted in order to study the properties of the laser treated surfaces. Corrosion testing showed different effects of laser power and production speed on the properties of the laser treated surfaces. It was shown that a high intensity and slow processing rate affect the surfaces by forming oxides that are relatively stable in a corrosive environment of 0.1 M NaCl. Spectroscopic investigations including scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analyses showed the differences in chemical structure of the surface layer formed after laser treatment. Similarly, microstructural investigations showed different effects on the surface and sub-surface layer of the laser treated samples.
Keywords: Ti alloy, laser treatment, XPS, corrosion
Published in DiRROS: 25.10.2023; Views: 390; Downloads: 159
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100. ToF-SIMS depth profiling of metal, metal oxide, and alloy multilayers in atmospheres of ▫$H_2$▫, ▫$C_2H_2$▫, CO, and ▫$O_2$▫Jernej Ekar, Peter Panjan, Sandra Drev, Janez Kovač, 2022, original scientific article Keywords: Ions, Layers, Mass spectrometry, Metals, Oxides, SIMS depth profiling H2 C2H2 CO and O2 atmosphere gas flooding cluster secondary ions matrix effect
Published in DiRROS: 18.10.2023; Views: 356; Downloads: 155
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