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11 - 20 / 2000
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11.
Rapid immobilisation of chemical reactions in alkali-activated materials using solely microwave irradiation
Anže Tesovnik, Barbara Horvat, 2024, original scientific article

Abstract: Efflorescence, a time-dependent and water-driven phenomenon, is a major concern inalkali-activated materials (AAMs), impacting their practical use and preservation in a time-frozen state for post-characterisation. Although a method for stopping chemical reactions in conventional cements exists, it is time-consuming and not chemical-free. Therefore, this study explored the effects of low-power microwave-induced dehydration on efflorescence, mechanical performance, and structural integrity in AAMs, to create an alternative and more “user-friendly” dehydration method. For this purpose, several mixtures based on secondary raw (slag, fly ash, glass wool, and rock wool) and non-waste (metakaolin) materials were activated with a commercial Na-silicate solution in ratios that promoted or prevented efflorescence. Characterisation techniques, including Fourier-transform infrared spectroscopy and X-ray diffraction, showed that microwave dehydration effectively removed water without altering crystallinity, while mercury intrusion porosimetry and compressive strength tests confirmed increased porosity. In addition to being an efficient, time-saving, and solvent-free manner of stopping the reactions in AAMs, microwave irradiation emerged as an innovative, chemical-free method for evaluating curing finalisation and engineering foams in a stage when all other existing methods fail. However, the artificially provoked efflorescence in aged dehydrated AAMs connected the slipperiness of AAM with the instant extraction of Na, which raised the need for further research into alternative alkali replacements to evaluate the practical use of AAM.
Keywords: materials chemistry, alkali-activated materials, geopolymers, slag, fly ash, rock wool, glass wool, metakaolin, microwave irradiation, dehydration, stopping chemical reactions, efflorescence
Published in DiRROS: 23.12.2024; Views: 101; Downloads: 41
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12.
Investigating the synergistic impact of freeze-thaw cycles and deicing salts on the properties of cementitious composites incorporating natural fibers and fly ash
Ildikó Merta, Vesna Zalar Serjun, Alenka Mauko Pranjić, Aljoša Šajna, Mateja Štefančič, Bojan Poletanovic, Farshad Ameri, Ana Mladenović, 2025, original scientific article

Abstract: In cold climates, concrete structures confront durability challenges due to harsh conditions. This study evaluates the effects of incorporating natural fibers, such as hemp and flax fibers (at 1 vol%), and partially replacing cement with fly ash (at 25 and 50 wt%) on the properties of cementitious composites subjected to accelerated aging under freeze-thaw cycles and deicing salts. Findings reveal that natural fibers enhance the freeze-thaw resistance, reducing deterioration (scaling) to 5-8% after 56 cycles. When mortars were subjected to accelerated freeze-thaw cycles, the compressive strength of plain mortar significantly decreased (up to 57%). However, adding natural fibers to the matrix substantially reduced its compressive strength loss. In the case of flexural strength, plain mortars experienced 33% loss, while hemp, flax, and polypropylene fiber mortars showed only 13%, 23%, and 10% losses, respectively. Furthermore, mortars experience a notable enhancement in their energy absorption capacity when reinforced with natural fibers, particularly with hemp fibers (up to 348% higher than plain mortar). Under harsh conditions, hemp and flax-reinforced mortars, with 25wt% fly ash replacement, lose the compressive strength significantly however still demonstrate an alternative to synthetic fibers in terms of flexural strength. Even with 25wt% of fly ash, mortars with natural fiber reinforcement display significantly superior energy absorption capacities compared to plain mortars (up to 48%).
Keywords: cementitious composites, natural fibers, freeze-thaw cycles, mechanical properties, mass loss, fly ash
Published in DiRROS: 23.12.2024; Views: 95; Downloads: 30
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13.
Strategic decisions : how good does it fit the decision-making process into the strategic management process?
Edvard Kolar, Matej Tušak, Petra Robnik, Roberto Biloslavo, 2024, original scientific article

Abstract: The complicated dance between the decision-making (hereinafter: DM) process, which is shaped by the individual psychological constructs and internal cognitive processes, and the methodological process of strategic management (hereinafter: SMP), which can be understood as a framework that defines decision context, raises pertinent questions about their coherence. The purpose of this study is to propose an integrative model of the strategic decision-making process (hereinafter: SDM), which links the cognitive processes of decision-makers with the rigour of strategic management and identifies and mitigates potential risks at each stage of the holistic process. To design the research, we used the "model paper" approach which seeks to build a theoretical framework that predicts relationships between research concepts. The developed comprehensive model connects four independent concepts, creating a holistic framework for SDM in organizations. The comprehensive model reveals a high degree of consistency between the SMP, knowable decision-making cycle and cognitive processes. Throughout the entire process, decision-makers need to be mindful of the interplay between System 1 and System 2 thinking. While System 1 thinking may provide quick insights and initiate creative thinking, it is important to complement it with the deliberate and analytical reasoning of System 2 thinking, which can be supported by a proper application of different strategic management tools and methods.
Keywords: strategic management process, decision making process, integrative concept, strategic decision making, system 1 and 2 thinking
Published in DiRROS: 23.12.2024; Views: 97; Downloads: 29
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Sedem desetletij metasekvoje (Metasequoia glyptostroboides Hu et Cheng) v Sloveniji
Iza Petek, Gregor Božič, Dušan Jurc, Kristjan Jarni, Robert Brus, 2024, review article

Abstract: Metasekvoja (Metasequoia glyptostroboides Hu et Cheng) je ena najpozneje odkritih drevesnih vrst na Zemlji in hkrati zelo stara vrsta, ki se morfološko skozi milijone let skoraj ni spremenila. Odkrita je bila šele sredi 20. stoletja na Kitajskem, le nekaj let za tem, ko so znanstveniki odkrili njene fosilne ostanke in predvidevali, da gre za izumrlo vrsto. Po odkritju se je o metasekvoji veliko govorilo in pisalo, sadili so jo po vsem svetu z namenom preučevanja, saj je bilo odkritje živih osebkov senzacija za ves botanični svet. Danes se je v luči podnebnih sprememb in ob iskanju novih možnosti za večjo odpornost gozda metasekvoja kot potencialno uporabna vrsta zopet znašla pod drobnogledom. Njeno močno užlebljeno deblo in obstojnost odmrlih vej lahko predstavljajo težavo pri obdelavi njenega proti glivam sicer zelo odpornega lesa, hkrati pa zaradi edinstvenega videza deluje izredno estetsko predvsem v urbanem okolju. Kot gospodarsko vrsto jo uporabljajo ponekod na Kitajskem, v Evropi jo sadijo predvsem v testnih nasadih in v urbanem okolju. V preglednem prispevku je po sedmih desetletjih prisotnosti metasekvoje v Sloveniji podrobneje predstavljena zgodovina njenega odkrivanja, dosedanja uporaba in ocenjen je njen prihodnji potencial.
Keywords: Slovenija, Metasequoia glyptostroboides, zgodovina, odkritje, lastnosti, drevesne vrste
Published in DiRROS: 22.12.2024; Views: 192; Downloads: 31
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16.
Unveiling the potential of ▫$(CoFeNiMnCr)_3O_4$▫ high-entropy oxide synthesized from CoFeNiMnCr high-entropy alloy for efficient oxygen-evolution reaction
Barbara Ljubec Božiček, Jitka Hreščak, Monika Kušter, Janez Kovač, Iztok Naglič, Boštjan Markoli, Barbara Šetina, Martin Šala, Sandra Drev, Živa Marinko, Miran Čeh, Belisa Alcantara Marinho, 2024, original scientific article

Abstract: Electrochemical water-splitting is a promising green technology for the production of hydrogen. One of the bottlenecks, however, is the oxygen evolution half-reaction (OER), which could be overcome with the development of a suitable electrocatalyst. Recently, non-noble metal, high-entropy oxides (HEO) have been investigated as potential OER electrocatalysts, but complex synthesis approaches that usually produce the material in powder form limit their wider utilization. Here, an innovative synthesis strategy of formulating a nanostructured (CoFeNiMnCr)3O4 HEO thin film on a CoFeNiMnCr high entropy alloy (HEA) using facile electrochemical and thermal treatment methods is presented. The CoFeNiMnCr HEA serves as exceptional support to be electrochemically treated in an ethylene glycol electrolyte with ammonium fluoride to form a rough and microporous structure with nanopits. The electrochemically treated CoFeNiMnCr HEA surface is more prone to oxidation during a low-temperature thermal treatment, leading to the growth of a spinel (CoFeNiMnCr)3O4 HEO thin film. The (CoFeNiMnCr)3O4 HEO exhibits a superior overpotential of 341 mV at 10 mA cm−2 and a Tafel slope of 50 mV dec−1 along with remarkable long-term stability in alkaline media. The excellent catalytic activity and stability for the OER can serve as a promising platform for the practical utilization of (CoFeNiMnCr)3O4 HEO.
Keywords: electrochemical water-spliting, electrocatalysts
Published in DiRROS: 20.12.2024; Views: 88; Downloads: 32
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Influence of surface preparation of aluminum alloy AW-5754 and stainless steel X5CRNI18-10 on the properties of bonded joints
Nataša Zdravković, Damjan Klobčar, Dragan Milčić, Matevž Zupančič, Borut Žužek, Miodrag Milčić, Aleksija Ðurić, 2024, original scientific article

Abstract: Adhesive bonding has proven to be a reliable method of joining materials, and the development of new adhesives has made it possible to use bonding in a variety of applications. This article addresses the challenges of bonding metals such as the aluminum alloy EN AW-5754 and the stainless steel X5CrNi18-10. In this study, the effects of laser cleaning and texturing on the surface properties and strength of two bonded joints were investigated and compared with mechanical preparation (hand sanding with Scotch-Brite and P180 sandpaper). The bonded joints were tested with three different epoxy adhesives. During the tests, the adhesion properties of the bonded surface were determined by measuring the contact angle and assessing the wettability, the surface roughness parameters for the different surface preparations, and the mechanical properties (tensile lap-shear strength). Based on the strength test results, it was found that bonded joints made of stainless steel had 16% to 40% higher strength than aluminum alloys when using the same adhesive and surface preparation. Laser cleaning resulted in maximum shear strength of the aluminum alloy bond, while the most suitable surface preparation for both materials was preparation with P180 sandpaper for all adhesives.
Keywords: adhesive bonding, surface preparation, aluminum alloy AW-5754, stainless steel X5CrNi18-10, epoxy adhesives
Published in DiRROS: 20.12.2024; Views: 81; Downloads: 38
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