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1.
Light control of lasing from liquid-crystal micro-droplet light switch
Uroš Jagodič, Jaka Pišljar, Andreja Jelen, Miha Škarabot, Igor Muševič, Vandna Sharma, Jaka Zaplotnik, Maruša Mur, Urban Mur, Miha Ravnik, 2026, original scientific article

Abstract: The all-optical control of light has been explored in hard matter, but to control light by light in soft matter is a major experimental and conceptual challenge that remains largely unexplored. We propose and verify experimentally and numerically that nanosecond light pulses can be controlled by light pulses using resonant stimulated-emission depletion (STED) in a liquid-crystal optical cavity that acts as a nanosecond optical switch. This light-by-light control is realized in a micrometer-diameter droplet of fluorescent-dye-doped nematic liquid crystal that is submersed in an aqueous solution. A set of laser-printed optical waveguides touches the surface of the droplet and provides flow of light in and out of the droplet. We demonstrate that nanosecond light pulses launched through the waveguides initiate the lasing of whispering gallery modes in the droplet. However, the lasing can be suppressed very efficiently on a nanosecond scale by another, red-shifted light pulse before the lasing takes place. The proposed concept of light control in soft matter using STED in an optical cavity requires fewer production steps because of self-assembly. It could be massively replicated using soft imprint lithography, uses less production energy due to low production temperatures, requires less toxic materials, and could be made entirely biocompatible and flexible.
Keywords: 3D printing, liquid crystals, lasing, whispering gallery models, light control, stimulated emission depletion
Published in DiRROS: 12.03.2026; Views: 299; Downloads: 179
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2.
Mechanical properties of 3D printed concrete : a RILEM 304‑ADC interlaboratory study – flexural and tensile strength
Rob Wolfs, Jelle Versteege, Manu Santhanam, Shantanu Bhattacherjee, Freek Bos, Annika Robens-Radermacher, Shravan Muthukrishnan, Costantino Menna, Katarina Šter, Aljoša Šajna, 2025, original scientific article

Abstract: This paper discusses the flexural and tensile strength properties of 3D printed concrete, based on the results of a RILEM TC 304-ADC interlaboratory study on mechanical properties. These properties are determined using different testing techniques, including 3- and 4-point flexural tests, splitting tests, and uniaxial tension tests, on specimens extracted from large 3D printed elements in accordance with a prescribed study plan. The relationship between compressive and flexural or tensile strengths, cast or printed samples, different types of tests, and different loading orientations, are analysed to understand the influence of 3D printing. As expected, the strength can reduce significantly when the main tensile stress is acting perpendicular to the interface between layers. The role of deviations from the standard study procedure, in terms of the time interval between the placing of subsequent layers, or the adoption of a different curing strategy, are also assessed. While the increased time interval significantly impacts the strength in the critical direction, the use of variable curing conditions does not seem to have a clear-cut effect on the strength ratios of the printed to cast specimens. Additionally, the paper looks at the variability in the results for the printed specimens, in order to emphasize the need for multiple replicates for obtaining a proper result. An extensive insight into the aspects affecting the variability is presented in the paper. Finally, with the limited dataset available for specimens tested at a larger scale, it is difficult to arrive at a clear understanding of the role of specimen size (i.e., greater number of layers).
Keywords: 3D concrete printing, digital fabrication, flexural strength, tensile strength, interlayer bond strength
Published in DiRROS: 12.01.2026; Views: 285; Downloads: 306
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3.
Synergistic effects of marble powder on mechanical properties in 3D printed PLA/PCL hybrid composites
J. Aqil Ahmed, P. Amuthakkannan, 2025, original scientific article

Keywords: polylactic acid, polycaprolactone, marble powder, 3D printing
Published in DiRROS: 08.01.2026; Views: 480; Downloads: 193
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4.
The effect of firing conditions on the characteristics of thick-film resistors for temperature sensors
Barbara Repič, Darko Belavič, Danjela Kuščer, 2024, original scientific article

Abstract: : An integrated miniature electrochemical sensor (ES) that offers rapid, sensitive, and selective detection of chemical and biological contaminants in a variety of samples requires temperature control to work accurately. To address this, one approach is to locate temperature sensor (TS) next to the ES components. However, this integration poses a challenge as different firing processes are required for the sensor components and the TS. Commercially available thick-film materials for the realisation of TS are designed for screen printing on alumina and firing in air at 850 °C for 10 minutes. However, a key component of an ES, a carbon-based working electrode, must be fired in an oxygen-lean atmosphere. In this study, we investigated the influence of the firing atmosphere, i.e., air and argon, on the characteristics of thick-film resistors, including thickness, roughness, phase composition, resistivity, and temperature dependence. For the study, we used two commercially available thick-film pastes, NTC2114 and NTC2113, as TS with nominal sheet resistivities of 10 kΩ/sq and 1 kΩ/sq at 25 °C, respectively. Using X-ray powder diffraction analyses, we detected RuO2 and spinel phases in the samples heated at 850 °C in air. However, when the samples were fired in argon, we detect metallic ruthenium and alloys. As a result of these changes, the resistivity of the NTC2114 and NTC2113 increased significantly. However, despite these changes, the relative resistance and the coefficient of temperature sensitivity did not vary significantly, indicating the suitability of these materials as TS. These findings have important implications for the future integration of TS into various screen-printed ES systems, fostering the design and development of systems with enhanced accuracy and reliability in temperature measurements.
Keywords: NTC, thick film, screen printing, temperature sensors
Published in DiRROS: 23.10.2025; Views: 457; Downloads: 224
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5.
Development of a gold nanoparticle dispersion for plasma jet printing on solid substrates
Lan Kresnik, Peter Majerič, Darja Feizpour, Rebeka Rudolf, 2025, original scientific article

Abstract: Gold nanoparticles (AuNPs) were synthesised using ultrasonic spray pyrolysis (USP) with the addition of polyvinylpyrrolidone (PVP) as a stabilising agent and subsequently dried via lyophilisation. The resulting dried AuNPs were redispersed in ethanol and homogenised to ensure uniform dispersion. This AuNP dispersion was then deposited onto a ceramic substrate - aluminum oxide (Al2O3) - using plasma jet printing. Comprehensive characterisation of the dispersion, AuNPs, and the resulting printed lines was performed using the following methods: inductively coupled plasma optical emission spectroscopy (ICP-OES), scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), scanning transmission electron microscopy (STEM), energy dispersive X-ray spectroscopy (EDS), ultraviolet-visible spectroscopy (UV–Vis), dynamic light scattering (DLS), measurements of dispersion viscosity and printed line roughness. ICP-OES confirmed consistent gold content in the AuNP dispersion, while the SEM and EDS analyses revealed predominantly spherical AuNPs with minimal aggregation and similar size distributions. TEM, SAED, and STEM/EDS confirmed that the crystalline structure and elemental composition of the AuNPs had diverse morphologies and strong gold signals. The UV–VIS, DLS, and zeta potential measurements indicated moderate colloidal stability, and thermogravimetric analysis (TGA) verified the AuNPs dispersion’s composition. The AuNP dispersion exhibited thixotropic behaviour favourable for printing applications, while confocal microscopy confirmed smooth, uniform printed traces, with an average surface line roughness of 1.65 μm. The successful use of plasma printing with the AuNP dispersion highlights its potential for functional material applications in electronics.
Keywords: gold nanoparticles, ultrasonic spray pyrolysis, dispersion, plasma jet printing
Published in DiRROS: 19.06.2025; Views: 829; Downloads: 485
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6.
Establishing benchmark properties for 3D-printed concrete : a study of printability, strength, and durability
Alise Sapata, Maris Šinka, Genadijs Šahmenko, Lidija Korat Bensa, Lucija Hanžič, Katarina Šter, Sandris Rucevskis, Diana Bajare, Fred P. Bosselman, 2025, original scientific article

Abstract: This study investigates the fresh state and hardened state mechanical and durability properties of 3D-printed concrete. The mechanical tests focused on its anisotropic behavior in response to different load orientations. Compressive, flexural, and splitting tensile strengths were evaluated relative to the print layers orientation. Results showed that compressive strength varied significantly, achieving 85% of cast sample strength when the load was applied parallel to the print layers ([u] direction), 71% when the load was applied perpendicular to the print object’s side plane ([v] direction), while only reaching 59% when applied perpendicular to the top plane ([w] direction). Similar trends were observed for flexural strength, with average values reaching 75% of cast sample strength when the load was applied perpendicular to the print layers ([v.u] and [w.u] directions), but decreasing to 53% when the load was applied parallel to print layers ([u.w] direction), underscoring the weaknesses at interlayer interfaces. The splitting tensile strength remained relatively consistent across print orientations, reaching 90% of the cast sample strength. Durability assessment tests revealed that 3D-printed concrete exhibits reduced resistance to environmental factors, particularly at the layer interfaces where the cold joint was formed, which are prone to moisture penetration and crack formation. These findings contribute valuable insights into the mechanical and durability properties of 3D-printed concrete, emphasizing the importance of print orientation and interlayer bonding in its performance. This understanding helps guide the optimal use of 3D-printed elements in real-life applications by aligning load or exposure to environmental factors with the material’s strength and durability characteristics.
Keywords: civil engineering, 3D-printing, concrete, additive manufacturing
Published in DiRROS: 11.02.2025; Views: 3116; Downloads: 664
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7.
Collision milling of oil shale ash as constituent pretreatment in concrete 3D printing
Lucija Hanžič, Mateja Štefančič, Katarina Šter, Vesna Zalar Serjun, Maris Šinka, Alise Sapata, Genadijs Šahmenko, Evaldas Šerelis, Baiba Migliniece, Lidija Korat Bensa, 2025, original scientific article

Abstract: Concrete is an essential construction material, and infrastructures, such as bridges, tunnels, and power plants, consume large quantities of it. Future infrastructure demands and sustainability issues necessitate the adoption of non-conventional supplementary cementitious materials (SCMs). At the same time, global labor shortages are compelling the conservative construction sector to implement autonomous and digital fabrication methods, such as 3D printing. This paper thus investigates the feasibility of using oil shale ash (OSA) as an SCM in concrete suitable for 3D printing, and collision milling is examined as a possible ash pretreatment. OSA from four different sources was collected and analyzed for its physical, chemical, and mineralogical composition. Concrete formulations containing ash were tested for mechanical performance, and the two best-performing formulations were assessed for printability. It was found that ash extracted from flue gases by the novel integrated desulfurizer has the greatest potential as an SCM due to globular particles that contain β-calcium silicate. The 56-day compression strength of concrete containing this type of ash is ~60 MPa, the same as in the reference composition. Overall, collision milling is effective in reducing the size of particles larger than 10 μm but does not seem beneficial for ash extracted from flue gasses. However, milling bottom ash may unlock its potential as an SCM, with the optimal milling frequency being ~100 Hz.
Keywords: digital concrete, 3D printing, oil shale ash, supplementary cementitious material, collision milling
Published in DiRROS: 30.01.2025; Views: 950; Downloads: 791
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8.
Mud from the Sitarjevec mine as a pigment for textile printing
Darja Rant, Mateja Štefančič, Vesna Zalar Serjun, Mateja Golež, 2021, published scientific conference contribution

Abstract: The Sitarjevec mine, located near the town of Litija (Central Slovenia), is recognized by the strong yellow colour of its dripstone structures and mine mud deposits. The mine mud, composed predominantly of goethite, accumulates on the ground of the mine shafts as the result of the interaction between percolating underground water, iron ore minerals and microorganisms. Since the accumulation of limonite mine mud is an ongoing process, larger quantities of mud have been deposited in the mine shafts since its closure. These deposits present a real threat of unleashing a mine mud spill on the town of Litija. Such a scenario has already previously occurred. In order to find new potential routes for recycling larger quantities of this mine mud, the present research work was performed to assess the use of mine mud as a pigment in the dye industry. In the first stage, the chemical (XRF) and microstructural (SEM) characteristics of the mine mud were defined together with the identification of its phase composition (XRD), particle size distribution and specific surface area (BET). Furthermore, the pigment was used to colour textile printing paste on a laboratory scale. To define the most appropriate quality of textile prints the rheological response of the various textile printing paste samples was investigated in terms of their plastic viscosity, indicating their suitability for use in textile printing. Test prints wereconducted, and the properties of leaching and fastness in the prints were assessed.
Keywords: mine mud, recycling, pigment, printing paste, textile, rheology
Published in DiRROS: 25.01.2024; Views: 1639; Downloads: 1096
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9.
Synergistic effect of screen-printed Al(OH)3 nanoparticles and phosphorylated cellulose nanofibrils on the thermophysiological comfort and high-intensive heat protection properties of flame-retardant fabric
Tjaša Kolar, Jelka Geršak, Nataša Knez, Vanja Kokol, 2022, original scientific article

Abstract: Al(OH)3 nanoparticles (ATH NPs) and phosphorylated cellulose nanofibrils (PCNFs) were used as user-friendly and comfortable coating components on flame-retardant fabric to improve its thermophysiological comfort and high-intensive heat protection properties. The effect of the PCNF imprinting and its attachment after the post-printing of a hydrophobic polyacrylate (AP) on the same (back side) or the other (front) side of the fabric, with and without the addition of ATH NPs, was considered, to maintain the front side (facing the wearer) as hydrophilic while keeping the back side (facing the outside) hydrophobic. The amount of coatings applied and their patterning were studied, varied with the ATH NPs’ concentration (1.7, 3.3 and 6.7 wt%) and screen mesh size used (60 and 135), based on the coating’ mass, fabric’s air permeability, thickness and microstructure. The reduced moisture build-up (55%), increased the water vapour (13%) and heat (12%) transfer from the skin, were assessed by applying PCNF under the AP, being more pronounced in the case of using a 135 mesh-sized screen, given the smaller, more densely distributed, thinner and imprinted pattern coatings. These effects were further improved by the addition of nanoporous ATH NPs, which allowed more homogeneous spreading of the moisture and its faster transport. Such a treatment also shifted the fabric’s degradation temperature towards higher values (up to 15°C), retained up to 30% of high-heat flux (21 kW/m2), prolonged the time to ignition by 11 s and reduced the total heat released by up to 60%, thereby providing better protection when exposed to the heat, due to the presence of the phosphorous (PCNF) promoted generation of an Al2O3 char acting as a barrier layer, while also reducing the production of heat and generation of smoke by 75%.
Keywords: flame-retardant textile, Al(OH)3 nanoparticles, phosphorylated cellulose nanofibrils, screen-printing, thermophysiological comfort, heat protection
Published in DiRROS: 28.04.2023; Views: 1567; Downloads: 858
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10.
In-depth rheological characterization of tungsten sol-gel inks for inkjet printing
Urša Opara Krašovec, Tjaša Vidmar, Marta Klanjšek Gunde, Romana Cerc Korošec, Lidija Slemenik Perše, 2022, original scientific article

Keywords: rheology, inkjet printing, tungsten oxide, sol-gel
Published in DiRROS: 11.02.2022; Views: 1990; Downloads: 1442
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