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Povzetek: Mineral waste wool represents a significant part of construction and demolition waste (CDW) not yet being successfully re-utilized. In the present study, waste stone wool (SW) and glass wool (GW) in the form received, without removing the binder, were evaluated for their potential use in alkali activation technology. It was confirmed that both can be used in the preparation of alkali-activated materials (AAMs), whether cured at room temperature or at an elevated temperature in order to speed up the reaction. The results show that it is possible to obtain a compressive strength of over 50 MPa using SW or GW as a precursor. A strength of 53 MPa was obtained in AAM based on GW after curing for 3 days at 40 °C, while a similar compressive strength (58 MPa) was achieved after curing the GW mixture for 56 days at room temperature. In general, the mechanical properties of samples based on GW are better than those based on SW. The evolution of mechanical properties and recognition of influential parameters were determined by various microstructural analyses, including XRD, SEM, MIP, and FTIR. The type of activator (solely NaOH or a combination of NaOH and sodium silicate), and the SiO2/Na2O and liquid to solid (L/S) ratios were found to be the significant parameters. A lower SiO2/Na2O ratio and low L/S ratio significantly improve the mechanical strength of AAMs made from both types of mineral wool.
Ključne besede: alkali activation, waste mineral wool, mechanical strength
Objavljeno v DiRROS: 31.07.2023; Ogledov: 135; Prenosov: 141
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Povzetek: Refurbishment is one of the most important measures for reducing the environmental impacts of the construction sector in the near future. According to the life cycle assessment (LCA) methodology for buildings, the environmental impacts of refurbishment measures should be assessed within the whole life cycle of the building and reflected in separate modules. However, in practice, refurbishment is often treated as the beginning of a new building life cycle. This leads to difficulties in correctly assessing the environmental impacts for the components that are reused or recycled after the refurbishment. The division of a building’s life cycle into two separate life cycles indicates that the environmental impacts must be divided between the life cycle before and the life cycle after the refurbishment for a correct assessment of the environmental impacts and a calculation of the residual value. We propose a newly developed methodology for calculating the environmental impacts and the residual value of refurbishment measures that also involves a division between life cycles. The new methodology is a combi-nation of already exiting methodologies that are innovatively combined and consists of four sequential steps. In the first step, the input, output and reuse flows between the life cycles before and after the refurbishment are defined. In the second step, the environmental impacts are assessed using the chosen allocation approach (i.e., the cut-off, cut-off with module D, avoided-burden, 50:50 and the product environmental footprint (PEF)). In the third step, a maintenance scenario is implemented according to the selected reference-service-life (RSL) database. In the fourth step, the residual value is estimated. The methodology was tested on selected building components. A sensitivity analysis for different allocation approaches and RSL databases was performed to show how the choice of these parameters can influence the results. The differences between the selected allocation approaches emerge if materials with recycled content are used or if the materials are being recycled or reused at the end of their life cycle. The developed methodology reliably estimates the environmental impacts as well as the residual value of the life cycle before and after the refurbishment. We expect that this research will stimulate practitioners to avoid the negligence of previous environmental flows, bringing scientific consistency to future assessments of refurbishment measures.
Ključne besede: Life cycle assessment (LCA), refurbishment, allocation approaches, residual value, reference service life (RSL)
Objavljeno v DiRROS: 28.07.2023; Ogledov: 196; Prenosov: 102
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Povzetek: Full and partial restorations in dentistry must replicate the characteristics of the patient’s natural teeth. Materials must have good mechanical properties and be non-toxic and biocompatible. Microbes, which can form biofilms, are constantly in contact with restorations. In this study, we investigate how well Candida albicans adheres to a polymethyl methacrylate (PMMA) resin base with gold (Au) nanoparticles. We synthesized Au nanoparticles and characterized them. The average size of Au nanoparticles embedded in PMMA was 11 nm. The color difference ∆E between PMMA and PMMA/Au composites was 2.7 and was still esthetically acceptable to patients. PMMA/Au surfaces are rougher and more hydrophilic than pure PMMA surfaces, and the isoelectric point of both types of surfaces was 4.3. Above the isoelectric point, PMMA/Au surfaces are more negatively charged than PMMA surfaces. The added Au nanoparticles decreased the tensile strength, while the hardness did not change significantly. Adhesion measurements showed that PMMA surfaces modified with Au nanoparticles reduced the extent of microbial adhesion of Candida albicans.
Ključne besede: fungal adhesión, C. albicans, polymethyl methacrylate resin, Au, surface properties, composites
Objavljeno v DiRROS: 24.07.2023; Ogledov: 208; Prenosov: 84
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Povzetek: In cross-laminated timber (CLT) buildings, in order to reduce the disturbing transmission of sound over the flanking parts, special insulation layers are used between the CLT walls and slabs, together with insulated angle-bracket connections. How-ever, the influence of such CLT connections and insulation layers on the seismic resistance of CLT structures has not yet been studied. In this paper, experimental investigation on CLT panels installed on insulation bedding and fastened to the CLT floor using an innovative, insulated, steel angle bracket, are presented. The novelty of the investigated angle-bracket connection is, in addition to the sound insulation, its resistance to both shear as well as uplift forces as it is intended to be used instead of traditional angle brackets and hold-down connections to simplify the construction. Therefore, monotonic and cyclic tests on the CLT wall-to-floor connections were performed in shear and tensile/compressive load direction. Specimens with and without insulation under the angle bracket and between the CLT panels were studied and compared. Tests of insulated specimens have proved that the insulation has a marginal influence on the load-bearing capacity; however, it significantly influences the stiffness characteristics. In general, the experiments have shown that the connection could also be used for seismic resistant CLT structures, although some minor improvements should be made.
Ključne besede: CLT connection, equivalent viscous damping, experimental shear tests, polyurethane sound-insulation, steel angle bracket
Objavljeno v DiRROS: 19.07.2023; Ogledov: 163; Prenosov: 67
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Povzetek: Bronze surfaces, whether bare or patinated, tend to change when exposed to an outdoor atmosphere. Art made of bronze which is exposed to the outdoors is usually artificially patinated. This patina changes when exposed to rain, especially in polluted rain, where sulphuric, nitric or carbonic acids are present. In order to gain optimal protection of different patinas and consequently reduce the patina changes over the time different protection systems were developed, tested and tailored. Three types of patina (brown, green sulphate, and green persulphate) were prepared, protected and subsequently studied. The protections were based on two coatings (i) fluoropolymer based coating (FA-MS) and (ii) newly developed fluoropolymer based coating with addition of mercaptopropyl groups, named as alternative fluoropolymer coating (FA-MS-SH). Both the pure patinas applied on bronze surfaces as well as the bare bronze were electrochemically tested, first unprotected and then following the application of two different types of protection. After the protection was applied to the pa- tinas, the change in colour was defined. Different techniques were utilised in order to define the morphology and structure of the patinas, as well as the change in colour following application of the coating. It was shown that a fluoropolymer coating (FA-MS) provided the most efficient protection to bare bronze and the sulphate patina, while a newly proposed alternative fluoropolymer coating (FA-MS-SH) offered good protection to bare and brown patinated bronze. A mechanism for the protection of bare and patinated bronze was suggested.
Ključne besede: bronze, patina, protection
Objavljeno v DiRROS: 17.07.2023; Ogledov: 159; Prenosov: 105
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