41. The impact of urban rain on the changes of bare and artificially patinated bronze during 9-year exposureTadeja Kosec, Mirjam Bajt Leban, Polonca Ropret, Matjaž Finšgar, 2024, izvirni znanstveni članek Povzetek: Atmospheric pollutants in the air form acid rain which interacts with bronze surfaces exposed in urban outdoor environment. In this study, different types of patinas on bronze were investigated during and after 9 years of exposure to urban environment in moderately polluted continental city. Natural bronze patina and artificial brown sulphide, green chloride, and green–blue nitrate patinas were investigated. Visual assessment was carried out at defined periods. After 9 years of exposure, an electrochemical study was performed to investigate the electrochemical activity of the patinas in artificial urban rain. Additionally, the patinas were characterised using a variety of techniques, including metallographic examination, scanning electron microscopy/energy dispersive X-ray spectroscopy, Raman spectroscopy, X-ray diffraction analysis, X-ray-photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry to analyse the surface morphology, chemical composition, and stratigraphic features of the patinas. Evolution of the patinas was shown to be a result of both, the composition of the acid rain and the hydrophobicity of the patinated surfaces. Ključne besede: bronze, bronze, corrosion, patina characterization Objavljeno v DiRROS: 29.04.2024; Ogledov: 468; Prenosov: 1276 Celotno besedilo (5,67 MB) Gradivo ima več datotek! Več... |
42. State of the art methodologies for the estimation of fire costs in buildings to support cost–benefit analysisIkwulono David Unobe, Andrea Lucherini, Shuna Ni, Thomas Gernay, Ranjit Kumar Chaudhary, Ruben Van Coile, 2024, pregledni znanstveni članek Povzetek: Fires can lead to costly building damage as well as loss of lives and injuries. Installed to protect buildings from fire, or to limit the damage from such outbreaks, fire protection measures are a common feature in buildings. However, these features come at a cost. Although quite ubiquitous in buildings, the value of these features to private individuals and to society is not fully understood. To understand their value, a cost benefit analysis detailing the costs and benefits of fire protection measures is needed. Carrying out such an analysis requires methods for computing both the cost of these fire protection measures, and losses from fires (including both direct and indirect losses). This study outlines methodologies for evaluating those costs and losses. An exhaustive collection of available data necessary for estimating both costs and losses is presented. Several limitations in current methodologies and data constraints were identified, with recommendations proposed to address these shortcomings. Relevant sections of a study by the authors that refines fire protection cost estimation at national and sub-national levels are emphasized, including updated building categories, guidance on computing multipliers, and detailed cost calculation methods for installation and maintenance costs. The calculation uses regularly updated U.S. Census Bureau construction data, ensuring timely multiplier updates. The insights and suggestions presented in this study will ultimately refine the process of selecting fire protection strategies that maximize the net benefit of fire protection measures for both private stakeholders and society at large. Ključne besede: fire protection measures, cost of fire protection, losses from fire, cost benefit analysis, installation costs, maintenance costs Objavljeno v DiRROS: 18.04.2024; Ogledov: 466; Prenosov: 91 Celotno besedilo (879,08 KB) Gradivo ima več datotek! Več... |
43. Why are the Early Gothic murals in St. Jacob’s Church in Ormož, Slovenia, almost entirely black?Anabelle Križnar, Katja Kavkler, Sabina Dolenec, 2024, izvirni znanstveni članek Povzetek: In St. Jacob’s parish church in Ormož, Slovenia, mural paintings from around 1350–1370 are partially conserved in the northeastern corner of the main nave. They are almost completely black, indicating a large-scale pigment degradation. They were studied as a part of a larger research project aiming to identify materials applied and their possible degradation. First, they were studied in situ, and next, extracted samples of plaster, pigments, and colour layers were analysed by optical microscopy, Raman spectroscopy, FTIR spectroscopy, SEM-EDS, and XRD. Haematite, green earth, malachite, azurite, and tenorite were identified, showing that azurite and perhaps also malachite degraded to black tenorite, probably due to their fine grinding and their application directly on the fresh plaster. The plaster is made with small and large amounts of aggregate with mostly quartz with some impurities, which makes it fragile. The original appearance of these murals was of bright blue and green colours. Ključne besede: mural painting, medieval painting, Gothic art, St. Jacob's Church, Ormož, Slovenia, pigments, chemical structure, colour degradation, optical microscopy, Raman microspectroscopy, FTIR, XRD Objavljeno v DiRROS: 17.04.2024; Ogledov: 403; Prenosov: 358 Celotno besedilo (81,04 MB) Gradivo ima več datotek! Več... |
44. Model uncertainty in a parametric fire curve approach : a stochastic correction factor for the compartment fire load densityFlorian Put, Andrea Lucherini, Bart Merci, Ruben Van Coile, 2024, izvirni znanstveni članek Povzetek: A commonly used approach to represent the thermal load in a compartment fire is the Eurocode Parametric Fire Curve (EPFC), which specifies gas temperatures (or rather adiabatic surface temperatures). Recognizing the significant deviations between real fires and the EPFC framework, the concept of model uncertainty is explored. This study does not aim to assess or improve the EPFC, but introduces a model uncertainty, allowing for reliability-based structural fire engineering (SFE). It presents a stochastic correction factor for the fire load density, based on the maximum temperature in steel sections. The focus is on the fire load density, but in general other parameters can be jointly taken into account as well. This correction factor considers protected and un- protected sections, incorporating variations in section factor and protection thickness. The findings reveal that the fire load density within the EPFC framework can be modified to better represent the severity of fire ex- periments. This approach ensures physical consistency of the obtained compartment gas temperatures, as opposed to alternative approaches for addressing the EPFC model uncertainty. While promising results are evident in this proof of concept, exploration for other types of structural elements and evaluation for structural systems is necessary before integration into design practices. Ključne besede: structural fire engineering, compartment fires, fire load density, steel structures, reliability, probability of failure Objavljeno v DiRROS: 17.04.2024; Ogledov: 428; Prenosov: 87 Celotno besedilo (1,16 MB) Gradivo ima več datotek! Več... |
45. Modelling intumescent coatings for the fire protection of structural systems : a reviewAndrea Lucherini, Donatella de Silva, 2024, pregledni znanstveni članek Povzetek: Purpose
Intumescent coatings are nowadays a dominant passive system used to protect structural materials in case of fire. Due to their reactive swelling behaviour, intumescent coatings are particularly complex materials to be modelled and predicted, which can be extremely useful especially for performance-based fire safety designs. In addition, many parameters influence their performance, and this challenges the definition and quantification of their material properties. Several approaches and models of various complexities are proposed in the literature, and they are reviewed and analysed in a critical literature review.
Design/methodology/approach
Analytical, finite-difference and finite-element methods for modelling intumescent coatings are compared, followed by the definition and quantification of the main physical, thermal, and optical properties of intumescent coatings: swelled thickness, thermal conductivity and resistance, density, specific heat capacity, and emissivity/absorptivity.
Findings
The study highlights the scarce consideration of key influencing factors on the material properties, and the tendency to simplify the problem into effective thermo-physical properties, such as effective thermal conductivity. As a conclusion, the literature review underlines the lack of homogenisation of modelling approaches and material properties, as well as the need for a universal modelling method that can generally simulate the performance of intumescent coatings, combine the large amount of published experimental data, and reliably produce fire-safe performance-based designs.
Research limitations/implications
Due to their limited applicability, high complexity and little comparability, the presented literature review does not focus on analysing and comparing different multi-component models, constituted of many model-specific input parameters. On the contrary, the presented literature review compares various approaches, models and thermo-physical properties which primarily focusses on solving the heat transfer problem through swelling intumescent systems.
Originality/value
The presented literature review analyses and discusses the various modelling approaches to describe and predict the behaviour of swelling intumescent coatings as fire protection for structural materials. Due to the vast variety of available commercial products and potential testing conditions, these data are rarely compared and combined to achieve an overall understanding on the response of intumescent coatings as fire protection measure. The study highlights the lack of information and homogenisation of various modelling approaches, and it underlines the research needs about several aspects related to the intumescent coating behaviour modelling, also providing some useful suggestions for future studies. Ključne besede: intumescent coatings, fire protection, modelling, structural fire engineering, fire safety, performance-based design Objavljeno v DiRROS: 17.04.2024; Ogledov: 469; Prenosov: 254 Celotno besedilo (720,31 KB) Gradivo ima več datotek! Več... |
46. Experimental investigation of the shear force capacity of prismatic cross laminated timber beamsHenrik Danielsson, Tomaž Pazlar, Erik Serrano, Boris Azinović, 2024, izvirni znanstveni članek Povzetek: Experimental tests of Cross Laminated Timber (CLT) under in-plane beam loading conditions are presented. The influence of the element layup, the individual lamination width, and the beam overhang at the supports on the shear force capacity was investigated. All the CLT beams had the same gross cross section, and a 4-point-bending test setup was used. The experimentally determined load-bearing capacities are compared with the load-bearing capacities resulting from analytical methods proposed for structural design, focusing on shear failure in the crossing areas of flatwise bonded laminations (shear failure mode III). The test results indicate no or very small influence of the element layup and the lamination width on the shear force capacity. These results partly contradict the predictions of the proposed design methods. Of the three studied beam geometry parameters, the beam overhang at the support had the greatest influence on the load-bearing capacity. Ključne besede: cross laminated timber, CLT, beam, shear testing, shear capacity, design methods Objavljeno v DiRROS: 15.04.2024; Ogledov: 507; Prenosov: 270 Celotno besedilo (3,32 MB) Gradivo ima več datotek! Več... |
47. Thermal characterisation of the cooling phase of post-flashover compartment firesAndrea Lucherini, Balša Jovanović, Jose L. Torero, Ruben Van Coile, Bart Merci, 2024, izvirni znanstveni članek Povzetek: The main characteristics of the cooling phase of post-flashover compartment fires are studied using a simplified first-principles heat transfer approach to establish key limitations of more traditional methodologies (e.g., Eurocode). To this purpose, the boundary conditions during cooling are analysed. To illustrate the importance of a first-principles approach, a detailed review of the literature is presented followed by the presentation of a simplified numerical model. The model is constructed to calculate first-order thermal conditions during the cooling phase. The model is not intended to provide a precise calculation method but rather baseline estimates that incorporate all key thermal inputs and outputs. First, the thermal boundary conditions in the heating phase are approximated with a single (gas) temperature and the Eurocode parametric fire curves, to provide a consistent initial condition for the cooling phase and to be able to compare the traditional approach to the first- principles approach. After fuel burnout, the compartment gases become optically thin and temperatures decay to ambient values, while the compartment solid elements slowly cool down. For simplicity, convective cooling of the compartment linings is estimated using a constant convective heat transfer coefficient and all linings surfaces are assumed to have the same temperature (no net radiative heat exchange). All structural elements are assumed to be thermally thick. While these simplifications introduce quantitative errors, they enable an analytical solution for transient heat conduction in a semi-infinite solid that captures all key heat transfer processes. Comparisons between the results obtained using both approaches highlight how, even when considering the same fire energy input, the thermal boundary conditions according to the Eurocode parametric fire curves lead to an increase energy accumulated in the solid after fuel burnout and a delay in the onset of cooling. This is not physically correct, and it may lead to misrepresentation of the impact of post-flashover fires on structural behaviour. Ključne besede: cooling phase, fire decay, fire dynamics, compartment fires, structural fire engineering, fire safety Objavljeno v DiRROS: 15.04.2024; Ogledov: 550; Prenosov: 248 Celotno besedilo (6,40 MB) Gradivo ima več datotek! Več... |
48. An experimental apparatus for bench-scale fire testing using electrical heating padsAleksandra Seweryn, Andrea Lucherini, Jean-Marc Franssen, 2024, izvirni znanstveni članek Povzetek: This research study concerns an experimental, budget-friendly, electricity- powered apparatus for bench-scale fire testing. The apparatus consists of various elements, of which the most important are ceramic heating pads, used to impose heat fluxes on exposed surfaces of specimens. The test method allows to control the heating pads’ temperature and to adjust the distance between the heating pads and the specimen to obtain well-defined heat fluxes up to 50–60 kW/m2. Higher heat fluxes and temperatures can be obtained by setting the heating pads in full power mode, with or without the use of a thermal shield, which can lead to heat fluxes up to 150 kW/m2. The heating and thermal boundary conditions imposed by the apparatus are characterised and discussed, and the thickness of the convective boundary layer at the heating pads’ surface is estimated significantly lower than in the case of gas- fired radiant panels. The performance of the apparatus is analysed for various conditions: controlling the temperature of the heating pads, in an open environment or with the presence of thermal shields, and in full power mode. A few examples of application of the apparatus to fire test typical construction materials (steel and glass) are also presented. These results emphasise the well-defined heating conditions in temperature-controlled mode. The study finally discusses the advantages and limitations of the apparatus, as well as many possibilities of future applications and improvement for future research studies. Ključne besede: radiant panels, fire testing, heat transfer, heat flux, electrical heating pads, thermal boundary conditions Objavljeno v DiRROS: 15.04.2024; Ogledov: 475; Prenosov: 849 Celotno besedilo (3,11 MB) Gradivo ima več datotek! Več... |
49. Influence of test methodology on the characterization of the parallel-to-grain timber embedment strength and foundation modulus of dowelsCaroline D. Aquino, Rodrigues Leonardo G., Michael Schweigler, Meta Kržan, Zheng Li, Jorge M. Branco, 2024, izvirni znanstveni članek Povzetek: A reliable determination of the embedment strength and foundation modulus of timber elements is critical for the design and safety assessment of joints in timber structures. However, the existence of various test configurations for characterising the embedding properties of large diameter steel fasteners in timber elements poses challenges in directly comparing and utilising available test data. This paper aims to provide an insight into the influence of embedment property test methods, comparing experimental results from different test setups within the guidelines of the EN 383 and ASTM D 5764-97a standards for European softwood species, Scots pine wood (Pinus sylvestris) and Norway spruce (Picea abies). In addition to the test guidelines, the thickness of the specimen and the application of the load was evaluated within the protocols. A comprehensive statistical analysis was performed to identify statistically significant differences between the groups evaluated. The results of the analysis revealed disagreement between the standards in the evaluation of the strength of the embedding, highlighting the potential bias inserted by the experimental setup and protocol. Furthermore, it was proven that the thickness of the specimens influences both the embedding strength and the foundation modulus of the wood species tested. Finally, no distinctions were observed between tensile and compressive loading within the guidelines of the EN 383 standard. Ključne besede: embedment strength, foundation modulus, dowel-type connections, test methods Objavljeno v DiRROS: 15.04.2024; Ogledov: 424; Prenosov: 229 Celotno besedilo (3,96 MB) Gradivo ima več datotek! Več... |
50. Why geopolymers and alkali-activated materials are key components of a sustainable world : a perspective contributionWaltraud M. Kriven, Cristina Leonelli, John L. Provis, Aldo R. Boccaccini, Cyril Attwell, Vilma Ducman, Claudio Ferone, Sylvie Rossignol, Tero Luukkonen, Jannie S. J. Van Deventer, José V. Emiliano, Jérôme E. Lombardi, 2024, izvirni znanstveni članek Povzetek: This perspective article delves into the transformative potential of alkali-activated materials, acid-activated materials, and geopolymers in mitigating climate change and market challenges. To harness the benefits of these materials, a comprehensive strategy is proposed. This strategy aims to integrate these materials into existing construction regulations, facilitate certification, and promote market access. Emphasizing research and innovation, the article advocates for, increased funding to refine the chemistry and production of these materials, prioritizing low-cost alternatives and local waste materials. Collaboration between academia and industry is encouraged to expedite technological advances and broaden applications. This article also underscores the need to develop economic and business models emphasizing the long-term benefits of these materials, including lower life-cycle costs and reduced environmental impact. Incentivizing adoption through financial mechanisms like tax credits and subsidies is suggested. The strategy also includes scaling up production technology, fostering industrial collaboration for commercial viability, and developing global supply chains. Educational programs for professionals and regulators are recommended to enhance awareness and adoption. Additionally, comprehensive life-cycle assessments are proposed to demonstrate environmental benefits. The strategy culminates in expanding the applications of these materials beyond construction, fostering international collaboration for knowledge sharing, and thus positioning these materials as essential for sustainable construction and climate change mitigation. Ključne besede: geopolymers, alkali activated materials, perspective Objavljeno v DiRROS: 15.04.2024; Ogledov: 458; Prenosov: 483 Celotno besedilo (1,63 MB) Gradivo ima več datotek! Več... |