11. Dynamic properties of lightweight foamed glass and their effect on railway vibrationStanislav Lenart, Amir M. Kaynia, 2019, izvirni znanstveni članek Povzetek: Deformation properties of lightweight coarse grained material from recycled foamed glass have been determined from large-scale triaxial tests on prismatic specimens with dimensions 40 cm x 40 cm x 80 cm. Deformations were measured locally using vertical and horizontal local deformation transducers. Monotonic and cyclic loading at small to medium strain range were conducted. Three load sequences representing the expected conditions of use of lightweight material as vibration-reducing material in railway geotechnics have been used. Results indicate strong effect of brittle cellular structure of tested material as well as confining pressure dependency of elastic threshold shear strain and damping ratio. The results were used to assess the applicability of empirical formulas for shear modulus of granular materials to lightweight foamed glass. The parameters determined from the laboratory tests were further used in numerical analysis of railway dynamic response. The results of the numerical simulations show that replacement of fill in track embankment by lightweight material could improve the dynamic response of the track in reducing the vibration. Ključne besede: lightweight material, recycled foamed glass, railway vibration, shear modulus, damping Objavljeno v DiRROS: 16.11.2023; Ogledov: 70; Prenosov: 97
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12. Corrosion properties of aluminized 16Mo3 steelBlaž Karpe, Klara Prijatelj, Milan Bizjak, Tadeja Kosec, 2023, izvirni znanstveni članek Povzetek: Chromium-molybdenum steel (16Mo3) is widely used in petroleum, gas, automotive, and construction industries due to its good oxidation resistance and mechanical properties at moderately elevated temperatures. The aim of the research was to evaluate the corrosion susceptibility of 16Mo3 steel in hot rolled and aluminized states. Aluminization was performed by diffusion pack aluminization process at 900°C/2h and 730°C/4h, respectively. Electrochemical corrosion testing included measuring open circuit potential (EOCP), linear polarization resistance (LPR), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) in potassium phosphate buffer (KH2PO4, pH = 7). Optical microscopy (OM), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS) were used for surface layer microstructure characterization before and after corrosion tests. It was demonstrated that corrosion resistance of aluminized steel increased substantially. Corrosion properties were related to the structure and properties of intermetallic phase (FeAl, FeAl2 and Fe2Al5) that formed on the surface of 16Mo3 steel. Ključne besede: aluminide coatings, aluminized steel, aluminizing, electrochemical corrosion investigation, 16Mo3 steel Objavljeno v DiRROS: 16.11.2023; Ogledov: 55; Prenosov: 27
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13. Monitoring the galvanic corrosion of copper–steel coupling in bentonite slurry during the early oxic phase using coupled multielectrode arraysTadeja Kosec, Miha Hren, Klara Prijatelj, Bojan Zajec, Nina Gartner, Andraž Legat, 2023, izvirni znanstveni članek Povzetek: In the case of a two-part container for spent nuclear fuel, consisting of an iron-based inner structure with a copper coating, the potential perforation of copper through minor damage may result in intensive galvanic corrosion between copper and steel. The present work focuses on the corrosion of steel galvanically coupled to copper and exposed to a slightly saline environment under oxic conditions. The electrochemical processes on individual electrodes were monitored by coupled multielectrode arrays (CMEAs). The CMEAs were either in contact with groundwater saturated with bentonite or immersed in groundwater only. Very high galvanic corrosion currents were detected between carbon steel and pure copper in the early oxic phase. Additionally, the use of CMEAs further made it possible to monitor the distribution of cathodic currents around the steel electrode, which behaved anodically. Various microscopy and spectroscopy techniques were applied to identify the modes of corrosion and the type of corrosion products present at the end of the period of exposure. Ključne besede: copper, steel, bentonite, Aspö groundwater, coupled multi electrode array, electrochemical properties, Raman analysis, corrosion Objavljeno v DiRROS: 16.11.2023; Ogledov: 56; Prenosov: 8
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14. Photocatalytic CO2 reduction over mesoporous TiO2 photocatalystsMartin Reli, Peter Nadrah, Miroslava Filip Edelmannová, Rudolf Ricka, Andrijana Sever Škapin, Urška Lavrenčič Štangar, Kamila Kočí, 2024, izvirni znanstveni članek Povzetek: In this study, we investigated different synthesis methods (template-free and template-based) using copolymers of poly(ethylene oxide) and poly(propylene oxide) to enhance the CO2 reduction activity of mesoporous TiO2. Our main goal was to identify key factors affecting photocatalyst efficiency and selectivity. We compared the newly synthesized TiO2 photocatalysts with the commercial photocatalyst P25. Among the materials studied, TiO2-P123 in its pure anatase form demonstrated the highest photoreduction efficiency and CO2 selectivity. In contrast, TiO2-EG, TiO2-F127, and P25, which contained both rutile and anatase phases, exhibited decreased photoactivity due to the formation of a type II heterojunction between the phases and higher oxygen adsorption on rutile's surface. Additionally, we observed that the choice of chemicals for photocatalyst preparation significantly influenced the specific surface area. TiO2-P123, the most active photocatalyst, had the highest specific surface area, providing more reactive sites for improved light absorption efficiency and prolonged electron-hole pair lifetimes, resulting in enhanced photocatalytic activity. We also calculated apparent quantum yields to support our findings. Ključne besede: CO2 reduction, TiO2, photocatalysis, mesoporous material, Sol-gel method Objavljeno v DiRROS: 14.11.2023; Ogledov: 63; Prenosov: 9
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15. UV light causes structural changes in microplastics exposed in bio-solidsS. S. Alavian Petroody, Seyed Hossein Hashemi, Luka Škrlep, Branka Mušič, Cornelis A. M. van Gestel, Andrijana Sever Škapin, 2023, izvirni znanstveni članek Povzetek: Bio-solids (biological sludge) from wastewater treatment plants are a significant source of the emission of microplastics (MPs) into the environment. Weakening the structure of MPs before they enter the environment may accelerate their degradation and reduce the environmental exposure time. Therefore, we studied the effect of UV-A and UV-C, applied at 70 °C, on three types of MPs, polypropylene (PP), polyethylene (PE), and polyethylene terephthalate (PET), that are commonly found in sewage sludge, using three shapes (fibers, lines, granules). The MPs were exposed to UV radiation in bio-solid suspensions, and to air and water as control. The structural changes in and degradation of the MPs were investigated using Attenuated Total Reflectance–Fourier Transform Infrared Spectrometry (ATR-FTIR) and surface morphology was performed with SEM analysis. UV exposure led to the emergence of carbonyl and hydroxyl groups in all of the PP samples. In PE and PET, these groups were formed only in the bio-solid suspensions. The presence of carbonyl and hydroxyl groups increased with an increasing exposure time. Overall, UV radiation had the greatest impact on the MPs in the bio-solids suspension. Due to the surface-to-volume ratio of the tested samples, which influences the degradation rate, the fibers were more degraded than the other two plastic shapes. UV-A was slightly more effective at degrading the MPs than UV-C. These findings show that ultraviolet radiation in combination with an elevated temperature affects the structure of polymers in wastewater bio-solids, which can accelerate their degradation. Ključne besede: microplastics, degradation, hydroxyl, carbonyl, ultraviolet light Objavljeno v DiRROS: 14.11.2023; Ogledov: 58; Prenosov: 41
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16. Strižna trdnost spojev z ribjim klejem lepljenega lesa ovrednotena z metodo ABESMatic Sitar, Andreja Pondelak, Samo Grbec, Milan Šernek, 2023, izvirni znanstveni članek Povzetek: V prispevku smo s pomočjo sistema za avtomatizirano vrednotenje zlepljenosti (ABES) ugotavljali razvoj strižne trdnosti ribjega kleja pri lepljenju lesa. Uporabili smo bukov (Fagus sylvatica L.) furnir, ki smo ga lepili pri konstantnem tlaku 12 barov, medtem ko smo spreminjali temperaturo in čas stiskanja. Temperatura je znašala med25 °C in 100 °C, z intervalom 25 °C, čas stiskanja pa od 1 minute do 60 minut. Dosežena maksimalna strižna trdnost je znašala okoli 10 N/mm², dosegli smo jo pri vseh štirih proučevanih temperaturah stiskanja. Na podlagi rezultatov študije smo ugotovili, da strižna trdnost ribjega kleja pri različnih temperaturah segrevanja neenakomerno narašča. Pri višjih temperaturah segrevanja hitreje dosežemo maksimalne strižne trdnosti. Strižne trdnosti spoja lepila iz ribjega kleja smo ugotavljali tudi po standardih EN 204 in EN 205. Ključne besede: wood Objavljeno v DiRROS: 14.11.2023; Ogledov: 57; Prenosov: 40
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17. Closing data gaps and paving the way for pan-European fire safety efforts : Terminology of fire statistical variablesMartina Manes, Ana Sauca, Mohamad El Houssami, Petra Andersson, Colin McIntyre, Richard Campbell, David Rush, Anja Hofmann, Peter Wagner, Sergei Sokolov, Mindel Leene, Margrethe Kobes, Dirk Oberhagemann, Nicola Rupp, Grunde Jomaas, Friedrich Grone, Eric Guillaume, 2023, izvirni znanstveni članek Povzetek: A well-defined terminology of fire-related variables is important for correct analyses and supporting knowledge-based decisions regarding the evaluation of building fires at the European level. After developing an overview of current practices for fire statistics in Part I, the terminology used and the data collected by the EU Member States and eight other countries regarding fire incidents, property damage and human losses were mapped to increase awareness of their practice and support a comprehensive assessment of several fire statistical datasets. A questionnaire was distributed to relevant authorities responsible for the collection, elaboration/analysis, and fire statistical data publications to define and select the essential variables for an appropriate fire assessment and fire incident description. Based on the results of the questionnaire able to identify the essential fire statistical variables and a detailed analysis of current definitions adopted in the fire statistics of the EU Member States and other countries, a common terminology is proposed to collect the necessary data in the EU Member States and obtain meaningful datasets based on standardised terms and definitions. The results will generate essential outputs to move towards harmonised fire statistics at the EU level and contribute to an appropriate analysis able to improve fire prevention and fire mitigation in building fires. Ključne besede: fire statistics, fire incidents, building fires, fire statistical variables, terminology Objavljeno v DiRROS: 13.11.2023; Ogledov: 75; Prenosov: 42
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18. Defining the fire decay and the cooling phase of post-flashover compartment firesAndrea Lucherini, Jose L. Torero, 2023, izvirni znanstveni članek Povzetek: The current research study discusses and characterises the fire decay and cooling phase of post-flashover compartment fires, as they are often mixed up despite their important heat transfer differences. The two pha- ses are defined according to the fire heat release rate time-history. The fire decay represents the phase in which the fire heat release rate decreases from the ventilation- or fuel-limited steady-state value of the fully-developed phase to fire extinguishment. This phase is highly influenced by the fuel characteristics, ranging from fast decays for hydrocarbon and liquid fuels to slow decays for charring cellulosic fuels (wood). Once the fuel is consumed, the compartment volume enters the cooling phase, where the cooling in the gas-phase and solid-phase happens with significantly different modes and characteristic times. The thermal boundary conditions at the structural elements are then defined according to physical characteristics and dynamics within the compartment. The research study also underlines how the existing performance-based methodologies lack explicit definitions of the decay and cooling phases and the corresponding thermal boundary conditions for the design of fire-safe struc- tural elements under realistic fire conditions. Ključne besede: razpadanje ognja, hlajenje, izgorevanje, naravna izpostavljenost ognju, dinamika požara, požari v oddelkih, požarno inženirstvo, učinkovitost, požarna varnost, fire decay, cooling, burnout, natural fire exposure, fire dynamics, compartment fires, structural fire engineering, performance-based, fire safety Objavljeno v DiRROS: 13.11.2023; Ogledov: 78; Prenosov: 29
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19. A historical overview of experimental solid combustion research in microgravityWilson Ulises Rojas Alva, Grunde Jomaas, 2022, izvirni znanstveni članek Povzetek: Studying solid combustion phenomena in microgravity environments can be complex, and this is furthered by many limitations and constraints in the available microgravity research platforms. Consequently, fire safety in spacecraft is also a complex subject. The main limitations found in the field are related to the microgravity quality, the duration of microgravity conditions, the rig capabilities in volume and size, time scales, length scales and the diagnostic systems, and these are therefore the focus in the current investigation. The laboratory capacity of ground-based platforms has remained somewhat stalled since 1990s, some drop towers have recently been upgraded to extend their performance. New space-based platforms have been or are being established and could extend the windows-of-opportunity to perform research. In addition, a discussion is provided on the implications of the fact that the phenomena studied in the experimental investigations and the type of material employed covers both programmatic and scientific needs. It is found that a handful of materials are most widely studied to quantify and characterise some of the phenomena, while some materials have been employed even in single experimental efforts. The current literature review provides a very comprehensive overview of previous experimental studies and the experimental methodologies utilised. Thus, this study can become an aid to planning for future studies. Ključne besede: Microgravity, research platforms, solid combustion, fire safety, spacecraft Objavljeno v DiRROS: 13.11.2023; Ogledov: 77; Prenosov: 10
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20. Flame spread behaviour of Polydimethylsiloxane (PDMS) membranes in 1 g and µg environmentsWilson Ulises Rojas Alva, Frederik Møller-Poulsen, Sze Lok Man, Cameron Creamer, David Hanna, Grunde Jomaas, 2022, izvirni znanstveni članek Povzetek: Diffusion flame behaviour and silica ash (SiO2) production were experimentally studied for various Polydimethylsiloxane (PDMS) membrane thicknesses (0.125 mm to 1.0 mm) in normal gravity and during microgravity flight experiments. The flames were established on vertical samples (300 mm in length) and subjected to either opposed or concurrent forced flows (both laminar and turbulent), assimilating the NASA Test 1 that is in use for spacecraft material selection. The opposed flame spread rate was observed to be steady and could be estimated using classical theory. Under concurrent flow, the flame spread rate was only steady for very high forced flows. The opposed flame-spread rate ranged from 0.5 to 1.5 mm/s, while the concurrent case ranged between 0.1 and 12 mm/s. The transport of silica ash (SiO2) was found to affect the heat balance of the concurrent flame spread in a manner that resulted in unsteady flame spread. For opposed flame spread, on the other hand, the transport of silica ash showed to be irrelevant. The extinction behaviour for the concurrent flame spread was heavily dominated by the transport of silica-ash, while for opposed flames, extinction was due to kinetics (at high forced flows). In microgravity environments, the transport and deposition of silica ash is anticipated to dominate flame spread and near-limit as well. These results suggest that silica-based products might be less flammable in microgravity than other similar materials such as common thermoplastics (PP or PE) used as wire jackets. Ključne besede: silicone burning, spacecraft fire safety, flame spread, near-limit, silica-ash Objavljeno v DiRROS: 13.11.2023; Ogledov: 87; Prenosov: 11
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