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Recent progress in the development of advanced support materials for electrocatalysis
Milutin Smiljanić, Irina Srejić, Jelena P. Georgijević, Aleksandar Maksić, Marjan Bele, Nejc Hodnik, 2023, pregledni znanstveni članek

Objavljeno v DiRROS: 18.12.2023; Ogledov: 591; Prenosov: 281
.pdf Celotno besedilo (1,34 MB)
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A review of multiscale modelling approaches for understanding catalytic ammonia synthesis and decomposition
Luka Skubic, Sašo Gyergyek, Matej Huš, Blaž Likozar, 2024, pregledni znanstveni članek

Objavljeno v DiRROS: 18.12.2023; Ogledov: 610; Prenosov: 310
.pdf Celotno besedilo (1,68 MB)
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107.
Simultaneous determination of free biliverdin and free bilirubin in serum : a comprehensive LC-MS approach
Alen Albreht, Mitja Martelanc, Lovro Žiberna, 2024, izvirni znanstveni članek

Objavljeno v DiRROS: 18.12.2023; Ogledov: 581; Prenosov: 223
.pdf Celotno besedilo (1,74 MB)
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108.
Selective glucose oxidation to glucaric acid using bimetallic catalysts : lattice expansion or electronic structure effect?
Žan Lavrič, Janvit Teržan, Ana Kroflič, Janez Zavašnik, Joanna E. Olszówka, Štefan Vajda, Matej Huš, Miha Grilc, Blaž Likozar, 2024, izvirni znanstveni članek

Povzetek: Our study presents a comprehensive approach for the selective oxidation of glucose to glucaric acid (GA) by heterogeneous catalysis. We have synthesized and characterized Au/ZrO2, AuCu/ZrO2 and AuPt/ZrO2 catalysts using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and oxygen pulse chemisorption (OPS) techniques. Combining experimental observations with in-depth density functional theory (DFT) studies, we found that bimetallic catalysts form alloys, which exhibit different characteristics than monometallic counterparts for the given reaction. We performed batch reactions, varying temperature and oxygen pressure, and used the data to construct a predictive microkinetic model. As it turned out, AuPt/ZrO2 showed the highest selectivity, yielding 32 % of GA at 100 °C and 30 barg O2. Our results provide valuable insights for the developing of efficient catalysts and point out the bottlenecks for the oxidation of glucose to GA.
Ključne besede: glucaric acid, glucose oxidation, catalyst characterization, density functional theory, microkinetic modelling
Objavljeno v DiRROS: 06.12.2023; Ogledov: 650; Prenosov: 282
.pdf Celotno besedilo (2,73 MB)
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NLRP3 is its own gatekeeper : a group hug of NLRP3 monomers controls inflammation
Iva Hafner Bratkovič, 2022, drugi znanstveni članki

Objavljeno v DiRROS: 28.11.2023; Ogledov: 485; Prenosov: 327
.pdf Celotno besedilo (846,97 KB)
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