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Iskalni niz: "ključne besede" (relative humidity) .

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1.
The role of relative humidity on crystallization of calcium carbonate from calcium acetoacetate precursor
Andreja Pondelak, Francesca Rosi, Celeste Maurich, Costanza Miliani, Srečo D. Škapin, Andrijana Sever Škapin, 2019, izvirni znanstveni članek

Povzetek: Calcium acetoacetate, Ca(OAcAc)2, was exposed 7, 30 and 365 days to different values of relative humidity (33%, 48%, 75% and 96%) at 40 °C in order to study its transformation to CaCO3. The resulting Ca(OAcAc)2 decomposition and the time dependence of the phase transformations were monitored and critically evaluated by Fourier transform infrared spectroscopy, field emission scanning electron microscopy and X-ray powder diffraction. The impact of relative humidity on CaCO3 polymorph formation was thoroughly assessed. In all of the conditions used and for all ageing periods, the formed crystal structure is found to be vaterite. At the lowest relative humidity (33%), the amorphous CaCO3 remains more or less almost untransformed even after one year of exposure. It is proposed that the reason for the stability of amorphous CaCO3 is due to the limited amount of physisorbed water on the surfaces of the particles, which is considered the driving force for its transformation. However, the carbonation process is faster in the case of the highest humidity (96%). The findings are not only important for better solutions in the field of cultural heritage, but also shed new light on the fundamental mechanism of CaCO3 crystallization.
Ključne besede: calcium acetoacetate, relative humidity, carbonation, amorphous carbonate, vaterite, mechanism
Objavljeno v DiRROS: 22.11.2023; Ogledov: 259; Prenosov: 122
.pdf Celotno besedilo (6,55 MB)
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2.
Colorimetric cutoff indication of relative humidity based on selectively functionalized mesoporous silica
Erika Švara Fabjan, Peter Nadrah, Anja Ajdovec, Matija Tomšič, Goran Dražić, Matjaž Mazaj, Nataša Zabukovec Logar, Andrijana Sever Škapin, 2020, izvirni znanstveni članek

Povzetek: We present a novel % cutoff concept of colorimetric indication of relative humidity based on dye dissolution in condensed water in capillaries of selectively functionalized mesoporours host SiO2 material. Consistently high levels of indoor air humidity induces mold and algae growth which represent a potential risks for human health and have deteriorating effect on walls as well. Simple localized humidity detection of high humidity with naked eye especially at places with low air circulation, where growth of mold usually starts first, is therefore highly desirable. The reporting dye was integrated in the non-functionalized mesoporous silica matrix with different pore diameters and selective-functionalized mesoporous silica material. After exposure to the environment of different air humidities the dye dissolved in water causing color change of adsorbent. With the use of adsorbents with different mesopore diameters high ability to tune the value of relative humidity when complete capillary condensation occurred was achieved. Materials with pore diameters of 3.0%nm, 3.5%nm and 7.0%nm exhibit gradual color change when reaching relative humidity up to 55, 79 and 88 RH% respectively. After selective methylation of the material with 7.0%nm pore diameter, non-gradual cutoff color change was achieved. Sample exhibited color change at narrow range of relative humidity (cutoff color change). Due to selective functionalized outer surface the dye dissolution occur only in condensed water in pores and therefore provide colorimetric indication only in this range. Selectively modified silica material has a great potential for a straightforward detection of high humid environment.
Ključne besede: turn-on colorimetric probe, selective functionalization, mesoporous silica, relative humidity, capillary condensation
Objavljeno v DiRROS: 05.09.2023; Ogledov: 263; Prenosov: 194
.pdf Celotno besedilo (7,18 MB)
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3.
Effects of various cutting treatments and topographic factors on microclimatic conditions in Dinaric fir-beech forests
Janez Kermavnar, Mitja Ferlan, Aleksander Marinšek, Klemen Eler, Andrej Kobler, Lado Kutnar, 2020, izvirni znanstveni članek

Povzetek: Forest microclimate is strongly affected by local topography and management activities, as these directly alter overstory structure. In the present work we analysed the dependence of observed patterns of spatio-temporal microclimatic variations on topographic, canopy- and management-related factors. A forestry experiment was conducted in managed fir-beech forests in the Dinaric Mountains (Slovenia), which are characterized by rugged karstic terrain with numerous sinkholes. In 2012, cutting treatments representing a range in the intensity of overstory removal were performed: uncut controls (CON), 50% cut of stand growing stock (intermediate management intensity % IMI) and 100% cut (high management intensity % HMI) creating 0.4 ha canopy gaps. Fine-scale variation in aspect and slope and its effects on microclimate was assessed by comparing central, south-facing and north-facing within-sinkhole positions. We measured microclimatic variables (air temperature % T, relative humidity % RH) 0.5 m above the ground over three consecutive post-treatment growing seasons. Microclimatic variables showed an increase (T and vapour pressure deficit % VPD) or decrease (RH) with management intensity. Daily Tmax and VPDmax in HMI treatment were up to 5.9°C (on average 3.5°C) and up to 1.4 kPa (on average 0.6 kPa) higher than those in CON treatment, respectively, whereas daily RHmin was up to 22.7 (on average 13.0) percentage points lower. Regarding intra-seasonal patterns, microclimatic differences between treatments were largest during the summer. South-facing plots in the HMI treatment overall exhibited the most extreme conditions, i.e. the highest Tmax and lowest RHmin. Differences in microclimate between treatments were strongly modulated by canopy cover. The results also suggest that overstory removal increases topography-mediated variation in microclimate, as evidenced by significant differences in T, RH and VPD along the fine-scale topographic gradient within the created canopy gaps.
Ključne besede: tree cutting, air temperature, relative humidity, vapour pressure deficit, karst topography, canopy cover
Objavljeno v DiRROS: 08.10.2020; Ogledov: 1274; Prenosov: 524
.pdf Celotno besedilo (1,59 MB)
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