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Iskalni niz: "ključne besede" (refinement) .

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Non-spherical atom refinement applied in structure determination of ▫$(N_2H_6)(H_3F_4)_2$▫ and crystal structure re-determination of ▫$N_2H_6F_2$▫
Evgeny A. Goreshnik, 2026, izvirni znanstveni članek

Povzetek: Hydrazinium trihydrogen tetrafluoride was synthesized and its structure investigated. Its crystal structure, determined by single-crystal X-ray diffraction, consists of N2H62+ dications and trigonal H3F4– anions interconnected via a complex system of N–H···F hydrogen bonds. The crystal structure of hydrazinium fluoride was redetermined. For more accurate determination of hydrogen atoms positions, non-spherical atom refinement was performed for both structures.
Ključne besede: non-spherical atom refinement
Objavljeno v DiRROS: 24.03.2026; Ogledov: 297; Prenosov: 211
.pdf Celotno besedilo (1,14 MB)
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Microstructure refinement of Nd-Fe-B permanent magnets prepared via spark-plasma sintering
Tomaž Tomše, 2024, izvirni znanstveni članek

Povzetek: Sintered Nd-Fe-B-type permanent magnets are normally manufactured using a conventional powder-metallurgy approach. The limitations of such high-temperature, pressureless sintering methods include restricted control over the microstructure due to grain growth and constraints on the magnet’s geometry. The modern spark-plasma sintering (SPS) technique employs Joule heating and external pressure to offer lower consolidation temperatures and faster heating cycles compared to conventional approaches. As a result, the SPS has the potential for the rapid, low-temperature, net-shape manufacture of magnets. However, the nonequilibrium conditions associated with the SPS can lead to poor grain-boundary wetting and the formation of the soft-magnetic α-iron phase in samples prepared from anisotropic, microcrystalline Nd-Fe-B powders produced by standard procedures, i.e., strip casting, hydrogen decrepitation, and jet-milling. This study revealed that the absence of the Nd-rich grain-boundary film is related to the presence of hydrogen. Degassing the Nd-Fe-B powder before applying the SPS improved the distribution of the grain-boundary phase. Moreover, reducing the electrical currents in the sample during the SPS prevented the decomposition of the RE2Fe14B matrix, ensuring a favorable phase composition. Compared to magnets conventionally sintered at 1070 °C, the mean grain diameter of the SPS samples prepared at ≈880 °C was reduced by ≈33%. This reduction decreased the temperature coefficient of coercivity from -0.65 to -0.58%/°C. The coercivity increase measured for the SPS samples amounted to more than 15%, which was attributed to the combined effect of smaller grain size and reduced texture.
Ključne besede: spark-plasma sintering, microstructure refinement
Objavljeno v DiRROS: 28.03.2025; Ogledov: 1427; Prenosov: 685
.pdf Celotno besedilo (9,55 MB)
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5.
A family of $C^1$ Clough-Tocher spline spaces on $C^0$ piecewise quadratic domain partitions
Jan Grošelj, Marjetka Knez, 2025, izvirni znanstveni članek

Povzetek: The paper addresses the construction of $C^1$ splines on a curved domain that is parametrized by a $C^0$ piecewise geometry mapping composed of quadratic Bézier triangles. The $C^1$ splines are assembled from polynomials of a chosen total degree greater than or equal to four, and their construction is based on the Clough-Tocher splitting technique that ensures locality. In particular, the splines are locally characterized by an interpolation problem described by Hermite data, which resembles the standard macro-element concepts developed for $C^1$ splines on triangulations.
Ključne besede: quadratic triangle, quadratic triangulation, isogeometric functions, Clough-Tocher refinement, spline space, dimension, basis functions
Objavljeno v DiRROS: 24.03.2025; Ogledov: 912; Prenosov: 614
.pdf Celotno besedilo (5,58 MB)
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