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Iskalni niz: "ključne besede" (protection) .

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1.
Cost-benefit analysis of fire protection in buildings : application of a present net value approach
Thomas Gernay, Shuna Ni, David Unobe, Andrea Lucherini, Ranjit Kumar Chaudhary, Ruben Van Coile, 2023, izvirni znanstveni članek

Povzetek: In fire safety engineering, cost–benefit analysis provides a systematic method to assess whether the projected benefits from a fire safety measure outweigh its costs. However, there remains a wide discrepancy between methods used in the field for cost–benefit analysis, as well as a lack of quantitative data on the costs and economic impact of fire protection in buildings. In a recent research project, a reference methodology was proposed based on Present Net Value evaluation and on a combination of specialized construction database, fire statistics, and numerical modeling for estimation of the cost components. This paper presents the application of the methodology to four case studies. The case studies allow describing the methodology, the collection of data, fire statistics, and loss estimation, as well as illustrating how the methodology can support decision-making when multiple alternatives are compared. Under the assumptions adopted for the single-family house and the residential timber building case studies, it is found that for every 1\$, invested in sprinklers, \$1.06 is saved. This benefit–cost ratio increases with increasing valuation of indirect losses and statistical value of life. Sensitivity analyses are provided to explore the robustness of the investment recommendations. The results of evaluations, adapted from the presented case studies with project-specific inputs, can support decision making for policy makers, insurance companies, and individual building owners.
Ključne besede: fire safety, cost-benefit analysis, fire protection, fire statistics, sprinklers, compartmentation
Objavljeno v DiRROS: 29.11.2023; Ogledov: 224; Prenosov: 30
.pdf Celotno besedilo (758,66 KB)
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2.
Efficiency of novel photocatalytic coating and consolidants for protection of valuable mineral substrates
Andreja Pondelak, Sabina Dolenec, Jonjaua Ranogajec, Luka Škrlep, Snezana B. Vučetić, Vilma Ducman, Andrijana Sever Škapin, 2019, izvirni znanstveni članek

Povzetek: In the process of protection and consolidation of valuable materials, the efficiency is the crucial property that needs to be considered. TiO2/ZnAl layered double hydroxide (LDH) coating and silicate- and carbonate-based consolidants were synthesized and proposed to be used for protection and consolidation of four porous mineral substrates: brick, stone, render and mortar. The photocatalytic efficiency of TiO2/ZnAl LDH coating, as well as consolidation efficiency of two consolidants, both applied on model substrates, were studied. The photocatalytic coating showed significant activity and performed well after the durability tests involving rinsing and freezing/thawing procedures. After treatment with both consolidants, a serious enhancement of consolidation of the used substrates was found. On the other hand, the application of TiO2/ZnAl LDH, as well as consolidants, caused negligible changes in the water vapour permeability values and in appearance of the porous mineral substrates, indicating a high level of compatibility.
Ključne besede: photocatalytic coating, consolidant, protection, conservation, porous substrate, cultural heritage
Objavljeno v DiRROS: 21.11.2023; Ogledov: 208; Prenosov: 152
.pdf Celotno besedilo (2,55 MB)
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Corrosion protection of brown and green patinated bronze
Tadeja Kosec, Živa Novak, Erika Švara Fabjan, Luka Škrlep, Andrijana Sever Škapin, Polonca Ropret, 2021, izvirni znanstveni članek

Povzetek: Bronze surfaces, whether bare or patinated, tend to change when exposed to an outdoor atmosphere. Art made of bronze which is exposed to the outdoors is usually artificially patinated. This patina changes when exposed to rain, especially in polluted rain, where sulphuric, nitric or carbonic acids are present. In order to gain optimal protection of different patinas and consequently reduce the patina changes over the time different protection systems were developed, tested and tailored. Three types of patina (brown, green sulphate, and green persulphate) were prepared, protected and subsequently studied. The protections were based on two coatings (i) fluoropolymer based coating (FA-MS) and (ii) newly developed fluoropolymer based coating with addition of mercaptopropyl groups, named as alternative fluoropolymer coating (FA-MS-SH). Both the pure patinas applied on bronze surfaces as well as the bare bronze were electrochemically tested, first unprotected and then following the application of two different types of protection. After the protection was applied to the pa- tinas, the change in colour was defined. Different techniques were utilised in order to define the morphology and structure of the patinas, as well as the change in colour following application of the coating. It was shown that a fluoropolymer coating (FA-MS) provided the most efficient protection to bare bronze and the sulphate patina, while a newly proposed alternative fluoropolymer coating (FA-MS-SH) offered good protection to bare and brown patinated bronze. A mechanism for the protection of bare and patinated bronze was suggested.
Ključne besede: bronze, patina, protection
Objavljeno v DiRROS: 17.07.2023; Ogledov: 279; Prenosov: 159
.pdf Celotno besedilo (5,46 MB)
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5.
Environmentally friendly protection of European beech against fire and fungal decay using a combination of thermal modification and mineralisation
Rožle Repič, Andreja Pondelak, Davor Kržišnik, Miha Humar, Nataša Knez, Friderik Knez, Andrijana Sever Škapin, 2024, izvirni znanstveni članek

Povzetek: The demand for construction timber is continuously increasing, due to its favourable characteristics. However, the adequate protection of wood is key to its successful use, as it is flammable and susceptible to biodegradation. Given that thermal modification enhances the durability of wood, and mineralisation with CaCO3 considerably improves its fire properties, it is worth considering the combined effects of the two methods. European beech (Fagus sylvatica) was selected to determine the effects of a) thermal modification, b) mineralisation through the in-situ formation of CaCO3, and c) a combination of the two procedures, on resistance to decay fungi, reaction to fire and the mechanical properties of the wood. Microscopic analysis and comparisons of the samples before and after exposure to fungi were also conducted. Mineralised wood generally had a slightly alkaline pH value and higher equilibrium moisture content, while thermal modification lowered the equilibrium moisture content. The present study demonstrated the combined effect of thermal modification and mineralisation: the best response to fire as well as resistance to fungi was achieved when the two treatments were combined. Results from the Brinell hardness and three-point bending tests indicate that both modification procedures can slightly impair the mechanical properties of the wood.
Ključne besede: wood, protection, durability, mechanical properties
Objavljeno v DiRROS: 12.07.2023; Ogledov: 304; Prenosov: 214
.pdf Celotno besedilo (3,26 MB)
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6.
Exploring the protection mechanism of a combined fluoropolymer coating on sulphide patinated bronze
Tadeja Kosec, Živa Novak, Erika Švara Fabjan, Luka Škrlep, Matjaž Finšgar, 2022, izvirni znanstveni članek

Povzetek: When bronze or artificially patinated bronze is exposed to an outdoor environment that contains aggressive ions such as sulphates, nitrates, and carbonates, the surface of the bronze changes its appearance due to the formation of corrosion products on the surface. Research is being conducted on versatile protective measures that can be used to protect the surface from these changes. A recently synthesised fluoropolymer-based coating with mercaptopropyl groups, i.e. a 3-component fluoropolymer coating FA-MS-SH (silane-modified poly methylmethacrylate (MS) with added mercaptopropyltrimethoxy silane (SH) and a fluoroacrylate (FA)) was explored in detail in this work where its protective mechanism on sulphide patinated bronze was investigated. Electrochemical tests were conducted on the sulphide patinated bronze with and without the 3-component coating FA-MS-SH. Furthermore, FA, MS and SH alone and various combinations and concentrations of FA-MS were studied in order to determine the protective effect and properties of each component. Colour change and contact angle measurements were also defined. FIB-SEM measurements and GCIB-XPS depth profiles were carried out to study surface bonding with the sulphide patina in detail. A mechanism for the protection of sulphide patinated bronze was presented through the use of a multianalytical tool approach. It was shown that FA physisorbed on the patinated surface, while MS and blends of the components chemisorbed on the layer of sulphide patinated bronze, also resulting in the surface being efficiently protected from corrosion processes.
Ključne besede: bronze, protection, brown patina, fluoropolymer coating
Objavljeno v DiRROS: 31.05.2023; Ogledov: 301; Prenosov: 174
.pdf Celotno besedilo (7,67 MB)
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7.
Experimental study of the fire dynamics in a semi-enclosure formed by photovoltaic (PV) installations on flat roof constructions
Jens Steemann Kristensen, Benjamin Jacobs, Grunde Jomaas, 2022, izvirni znanstveni članek

Povzetek: Flame spread experiments upon a BROOF(t4) compliant flat roof mock-up located below a vertical barrier were carried out for variations in gap height, inclination, subjacent insulation material, and the barrier type (stainless-steel board or photovoltaic (PV) module). A binary flame spread scenario was identified, where re-radiation from the flame facilitated self-sustained flame spread if the gap height to the horizontal panel was below 10 cm for the stainless-steel board and 11 cm for PV modules. These were defined as the critical gap heights. Inclination of the PV modules increased the critical gap height and caused a 25% faster flame spread rate (FSR) than the FSR below horizontal modules with the same gap height at the location of ignition. The faster FSR for inclined modules caused a 40% reduction of the maximum temperature measured at a depth of 70 mm in the insulation materials (242°C). Based on temperatures measured in the insulation materials, the 60 mm polyisocyanurate (PIR) insulation performed slightly better than the 50 mm mineral wool insulation. However, it is expected that the mineral wool would outperform the PIR insulation if tested with the same thickness, as it insulates significantly better at high temperatures. Finally, no sustained flame spread was observed on the back side polymer sheet of the PV modules, but one of the three PV module brands produced burning droplets. Based on the experiments, it can be concluded that the current standards are inadequate as the introduction of a PV system on a compliant roof construction enables flame spread.
Ključne besede: photovoltaic (PV) installations, flame spread, fire dynamics, property protection, open access
Objavljeno v DiRROS: 31.05.2023; Ogledov: 290; Prenosov: 222
.pdf Celotno besedilo (2,92 MB)
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8.
Properties of the fluoroacrylate and methacryloxypropyl-trimethoxysilane applied to a layer of Cu2O on bronze as either single or multi-component coatings
Luka Škrlep, Tadeja Kosec, Matjaž Finšgar, Andrijana Sever Škapin, Erika Švara Fabjan, 2023, izvirni znanstveni članek

Povzetek: Various coatings have been developed and explored to protect bronze surfaces against the uncontrolled formation of different corrosion products when exposed to outdoor environments. In this research, the surfaces of artificially-formed oxidized bronze patinas (OB), consisting of Cu2O, were covered with either a single-component (fluoroacrylate, FA or methacryloxypropyl-trimethoxysilane, MS) or multi-component (a mixture of FA and MS, FA-MS) fluoropolymer coating and investigated. Variations in the concentration of each component in the coating were studied. Electrochemical tests were performed to determine the corrosion protection efficiency, followed by detailed surface analyses of the OBs, both uncoated and covered with single and multi-component coatings. A variety of investigative methods were used, including focused ion beam scanning electron microscopy (FIB-SEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The coating made from a combination of FA and MS resulted in a very high protection efficiency. Despite the increased hydrophilicity of the single MS component, however, it was shown to efficiently protect the oxidized bronze surface. The FA-MS systems showed high hydrophobicity, but no improvement was measured in the efficiency of the corrosion protection when it was compared to the coating that contained 10% MS. According to XPS and ToF-SIMS imaging, the FA component of the FA-MS coating was not present only on the uppermost surface of the coating but throughout the whole coating, which could affect its corrosion protection efficiency.
Ključne besede: bronze, Cu2O layer on bronze, fluoropolymer coating, protection efficiency, surface spectroscopy
Objavljeno v DiRROS: 30.05.2023; Ogledov: 297; Prenosov: 159
.pdf Celotno besedilo (8,49 MB)
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9.
Sustainable biocarbon/tung oil coatings with hydrophobic and UV-shielding properties for outdoor wood substrates
Laetitia Sarah Jennifer Marrot, Mariem Zouari, Matthew Schwarzkopf, David Brian DeVallance, 2023, izvirni znanstveni članek

Povzetek: With wood regaining substantial interest as a construction material due to sustainability concerns and aesthetics trends, efficient and safe protection methods are needed to prevent the discouloration and the loss of mechanical properties of this renewable and UV-sensitive material. In this study, sustainable coatings comprising 0 to 20 wt % biocarbon (BC) dispersed in tung oil were developed for wood protection. BC particles were added as ultraviolet (UV) absorbers and were produced by various carbonization routes. The BC powders were characterized in terms of particle size and surface functional groups by Fourier-Transform infrared, and the UV and visible absorbance of dispersed BC powders in water solutions were related to these characteristics. Two wooden substrates (beech and oak) were coated with the developed coatings and the samples underwent six months of onsite weathering. While the total colour change of uncoated samples and tung oil-coated substrates without BC kept increasing over time and resulted in a clear alteration of the wood surface aesthetics, an increased BC content in the coatings led to enhanced colour stability, with alteration of the colour close to 2 for both wood species after six months of weathering for 10 and 20 wt% BC. Coating with tung oil made the wooden substrates, initially hydrophilic, become hydrophobic, and the further introduction of biocarbon increased hydrophobicity. However, the increase in BC content was not correlated with an increase in water repellence, the highest water contact angle being observed for 5 % BC, and no further improvement in hydrophobicity was observed with higher BC content. The weathering negatively affected the water repellence of all the samples (i.e., reference samples and coated samples with various BC content). However, the introduction of 20 % BC best protected the decrease in water repellence induced by the onsite weathering.
Ključne besede: biocarbon, biochar, coating, wood protection, hydrophobic coating, wettability
Objavljeno v DiRROS: 30.05.2023; Ogledov: 299; Prenosov: 371
.pdf Celotno besedilo (6,19 MB)
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10.
Synergistic effect of screen-printed Al(OH)3 nanoparticles and phosphorylated cellulose nanofibrils on the thermophysiological comfort and high-intensive heat protection properties of flame-retardant fabric
Tjaša Kolar, Jelka Geršak, Nataša Knez, Vanja Kokol, 2022, izvirni znanstveni članek

Povzetek: Al(OH)3 nanoparticles (ATH NPs) and phosphorylated cellulose nanofibrils (PCNFs) were used as user-friendly and comfortable coating components on flame-retardant fabric to improve its thermophysiological comfort and high-intensive heat protection properties. The effect of the PCNF imprinting and its attachment after the post-printing of a hydrophobic polyacrylate (AP) on the same (back side) or the other (front) side of the fabric, with and without the addition of ATH NPs, was considered, to maintain the front side (facing the wearer) as hydrophilic while keeping the back side (facing the outside) hydrophobic. The amount of coatings applied and their patterning were studied, varied with the ATH NPs’ concentration (1.7, 3.3 and 6.7 wt%) and screen mesh size used (60 and 135), based on the coating’ mass, fabric’s air permeability, thickness and microstructure. The reduced moisture build-up (55%), increased the water vapour (13%) and heat (12%) transfer from the skin, were assessed by applying PCNF under the AP, being more pronounced in the case of using a 135 mesh-sized screen, given the smaller, more densely distributed, thinner and imprinted pattern coatings. These effects were further improved by the addition of nanoporous ATH NPs, which allowed more homogeneous spreading of the moisture and its faster transport. Such a treatment also shifted the fabric’s degradation temperature towards higher values (up to 15°C), retained up to 30% of high-heat flux (21 kW/m2), prolonged the time to ignition by 11 s and reduced the total heat released by up to 60%, thereby providing better protection when exposed to the heat, due to the presence of the phosphorous (PCNF) promoted generation of an Al2O3 char acting as a barrier layer, while also reducing the production of heat and generation of smoke by 75%.
Ključne besede: flame-retardant textile, Al(OH)3 nanoparticles, phosphorylated cellulose nanofibrils, screen-printing, thermophysiological comfort, heat protection
Objavljeno v DiRROS: 28.04.2023; Ogledov: 409; Prenosov: 107
.pdf Celotno besedilo (2,91 MB)
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