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Iskalni niz: "ključne besede" (polyurethane) .

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1.
Influence of ammonium polyphosphates and 2,4,6-triamino-1,3,5-triazine on the mechanical-physical properties of polyurethane and alkali-activated materials
Branka Mušič, Barbara Horvat, 2024, objavljeni znanstveni prispevek na konferenci

Povzetek: In building constructions, the tendency towards an ever-better material directs us to composite materials. In this work, we prepared an organic-organic and organic-inorganic composite material by incorporating fire retardants, ammonium polyphosphates, and 2,4,6-triamino-1,3,5-triazine, into a polyurethane network and an aluminosilicate network (ASN) of alkali-activated material. Polyurethane foams (PUR) are well-known materials that, due to their properties, such as low weight-to-strength ratio, low electrical and thermal conductivity, flexibility, and relatively simple preparation process, are used in various industries, also in the construction industry, e.g., for thermal insulation of windows and doors or fixing and sealing joinery. Opposite, the ASN of alkali-activated metakaolin, successfully paves the way for new applications, such as high-temperature protection. In this paper, these interactive properties of prepared composites are studied using thermal testing and mechanical analysis. It was found that inhibitors significantly increase the fire resistance of PUR systems while they slightly reduce the mechanical properties. Incorporating polymer flame retardant into ASN in building products, such as façade panels , can decrease the mechanical properties but can offer the non-flammable building envelope not get heated from burning surroundings, i.e., not becoming a convection heat source, but rather represent a fire-distinguisher for flammable materials.
Ključne besede: flame retardants, polyurethane, alkali activated material, metakaolin, microwave irradiation, mechanical strength
Objavljeno v DiRROS: 12.03.2024; Ogledov: 67; Prenosov: 31
.pdf Celotno besedilo (2,52 MB)
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2.
Thermal insulation and flammability of composite waste polyurethane foam encapsulated in geopolymer for sustainable building envelope
Barbara Horvat, Nataša Knez, Uroš Hribar, Jakob Koenig, Branka Mušič, 2024, izvirni znanstveni članek

Povzetek: Polyurethane foam (PUR) is a lightweight, thermally insulating, widely used, and highly flammable material that has after its use an adverse effect on the environment, i.e., PUR disposal is considered hazardous. Its flammability can be mitigated using various fire retardants, but they do not change the hazardous nature of waste PUR. Therefore, in the current study, waste PUR with and without flame retardants based on N and P was incorporated into a geopolymer, the alkali-activated material (AAM) based solely on metakaolin, to evaluate the potential recycling route of waste PUR while taking into account its flammability, so it can enter safely into the circular economy through the building industry. To enhance the mechanical properties of the composite, a fresh mixture was irradiated with microwaves. However, the irradiation of geopolymer containing PUR negatively influenced mechanical performance, which led to the evaluation of the behaviour of the complex dielectric constant of PUR and fire retardants. Materials and composites were evaluated regarding their chemistry, mineralogy, microstructure, and porosity to connect the structure with extrinsic properties like geometrical density, thermal conductivity, and fire properties. Nonetheless, positive influences of PUR being encapsulated in the geopolymer were lowered density (from 1.8 to 1.6 kg/l) and improved thermal insulation ability (from 940 to 860 mW/(m·K)) of the composites: with the inclusion of <5 % of PUR, thermal insulation improved by nearly 10 %. However, the contribution of PUR to the composite originated from its skeleton, which has more than 15 times bigger geometrical density (0.81 kg/l) compared to the density of the skeleton (0.047 kg/l). This offers an open field for further advancements of thermal properties, but would also lead to a decrease of the compressive strength, which was already lowered from 90 MPa for 30 % with <5 % of added grated PUR. Furthermore, the flammable nature of PUR and its other drawbacks can be controlled by permanent embedding in the noncombustible structure of geopolymer, making the envelope of sustainable buildings green and safer. Overall, including grated waste PUR in geopolymer represents a promising, easy, cost-effective recycling path with low energy consumption, where the composite cannot develop fire on a scale of pure PUR, even in the worst-case scenario, but only if the composite is designed in a way, that flammable materials cannot join flames during their combustion. This paper gives prospects to other flammable waste materials to be safely used in the circular economy, and to porous materials to shape properties of the composite by their intrinsic and/or extrinsic properties.
Ključne besede: waste polyurethane foam, polymeric flame retardants, alkali activated material, metakaolin, microwave irradiation, thermal-fire behaviour, mechanical strength
Objavljeno v DiRROS: 01.03.2024; Ogledov: 141; Prenosov: 119
.pdf Celotno besedilo (29,74 MB)
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3.
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PUR in geopolymer
Barbara Horvat, Nataša Knez, Uroš Hribar, Jakob Koenig, Branka Mušič, 2024, zaključena znanstvena zbirka raziskovalnih podatkov

Povzetek: The dataset supports the results shown in the tables and figures in the article entitled “Thermal insulation and flammability of composite waste polyurethane foam encapsulated in geopolymer for sustainable building envelope” (doi: 10.1016/j.jclepro.2024.141387). It contains measurements of fire-behaviour characteristics, thermal conductivity, the behaviour of the material in the electromagnetic field in relation to the frequency, mechanical and structural evaluation, as well as chemical and mineralogical analysis.
Ključne besede: measurements, waste polyurethane foam, polymeric flame retardants, alkali activated material, metakaolin, microwave irradiation, thermal-fire behaviour, mechanical strength
Objavljeno v DiRROS: 20.02.2024; Ogledov: 183; Prenosov: 156
.xlsx Raziskovalni podatki (2,51 MB)
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5.
Flexible polymer connections for clt structures
Boris Azinović, Andreja Pondelak, Jaka Gašper Pečnik, Václav Sebera, 2020, objavljeni znanstveni prispevek na konferenci

Povzetek: This paper explores the possibility of using flexible polymer adhesives to dissipate energy in CLT buildings during earthquakes. In the first series of tests, pull-off tests of various polyurethane (PUR) adhesives were performed. The connection was tested in pull-pull configuration using monotonic, tension-only loading. The tests have shown that the adhesive can resist large deformations already in tension loading and with small thicknesses of the bond-line. Based on the pull-off test results, one adhesive has been selected for further testing. Monotonic lap-shear tests were performed with the selected adhesive and thick bond-line (3 mm and 6 mm). The results show, that the standard method for lap-shear testing (EN 205) needs to be adapted for thick glue-line. It was found that the strength of 3 mm glue-line is higher than 6mm one, which is in agreement with adhesion theory. The flexible PUR adhesives could potentially be used in CLT structures for anchoring the CLT wall with “flexible” glued-in rods or as a “flexible” vertical shear connection between the CLT walls. Such systems have a potential to dissipate energy in seismic areas.
Ključne besede: CLT connections, flexible adhesive, polyurethane, energy dissipation, pull-off, lap-shear
Objavljeno v DiRROS: 19.01.2024; Ogledov: 141; Prenosov: 69
.pdf Celotno besedilo (18,89 MB)
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6.
Deformable polyurethane joints and fibre grids for resilient seismic performance of reinforced concrete frames with orthoblock brick infills
Theodoros Rousakis, Alper Ilki, Arkadiusz Kwiecień, Alberto Viskovic, Matija Gams, Petra Triller, Bahman Ghiassi, Andrea Benedetti, Zoran Rakicevic, Camilla Colla, Omer Faruk Halici, BogusŁaw Zając, Łukasz Hojdys, Piotr Krajewski, Fabio Rizzo, Vachan Vanian, Anastasios Sapalidis, Efthimia Papadouli, Aleksandra Bogdanovic, 2020, izvirni znanstveni članek

Povzetek: The behaviour of reinforced concrete frames with masonry wall infills is influenced a lot by the stiffness and strength difference between the frame and the infill, causing early detrimental damage to the infill or to the critical concrete columns. The paper reports the results from shake table seismic tests on a full-scale reinforced concrete (RC) frame building with modified hollow clay block (orthoblock brick) infill walls, within INMASPOL SERA Horizon 2020 project. The building received innovative resilient protection using Polyurethane Flexible Joints (PUFJs) made of polyurethane resin (PU), applied at the frame-infill interface in different schemes. Further, PUs were used for bonding of glass fibre grids to the weak masonry substrate to form Fibre Reinforced Polyurethanes (FRPUs) as an emergency repair intervention. The test results showed enhancement in the in-plane and out-of-plane infill performance under seismic excitations. The results confirmed remarkable delay of significant infill damages at very high RC frame inter-story drifts as a consequence of the use of PUFJs. Further, the PUFJ protection enabled the resilient repair of the infill even after very high inter-story drift of the structure up to 3.7%. The applied glass FRPU system efficiently protected the damaged infills against collapse under out-of-plane excitation while they restored large part of their in-plane stiffness.
Ključne besede: polyurethane, flexible joint, RC column, brick infill, shake table, resilience
Objavljeno v DiRROS: 05.09.2023; Ogledov: 273; Prenosov: 112
.pdf Celotno besedilo (5,77 MB)
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7.
Cyclic response of insulated steel angle brackets used for cross-laminated timber connections
Meta Kržan, Boris Azinović, 2021, izvirni znanstveni članek

Povzetek: In cross-laminated timber (CLT) buildings, in order to reduce the disturbing transmission of sound over the flanking parts, special insulation layers are used between the CLT walls and slabs, together with insulated angle-bracket connections. How-ever, the influence of such CLT connections and insulation layers on the seismic resistance of CLT structures has not yet been studied. In this paper, experimental investigation on CLT panels installed on insulation bedding and fastened to the CLT floor using an innovative, insulated, steel angle bracket, are presented. The novelty of the investigated angle-bracket connection is, in addition to the sound insulation, its resistance to both shear as well as uplift forces as it is intended to be used instead of traditional angle brackets and hold-down connections to simplify the construction. Therefore, monotonic and cyclic tests on the CLT wall-to-floor connections were performed in shear and tensile/compressive load direction. Specimens with and without insulation under the angle bracket and between the CLT panels were studied and compared. Tests of insulated specimens have proved that the insulation has a marginal influence on the load-bearing capacity; however, it significantly influences the stiffness characteristics. In general, the experiments have shown that the connection could also be used for seismic resistant CLT structures, although some minor improvements should be made.
Ključne besede: CLT connection, equivalent viscous damping, experimental shear tests, polyurethane sound-insulation, steel angle bracket
Objavljeno v DiRROS: 19.07.2023; Ogledov: 270; Prenosov: 112
.pdf Celotno besedilo (2,57 MB)
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8.
Flame retardant behaviour and physical-mechanical properties of polymer synergistic systems in rigid polyurethane foams
Branka Mušič, Nataša Knez, Janez Bernard, 2022, izvirni znanstveni članek

Povzetek: In the presented work, the influence of two flame retardants—ammonium polyphosphates and 2,4,6-triamino-1,3,5-triazine on the polyurethane foam (PUR) systems were studied. In this paper, these interactive properties are studied by using the thermal analytical techniques, TGA and DTA, which enable the various thermal transitions and associated volatilization to be studied and enable the connection of the results with thermal and mechanical analysis, as are thermal conductivities, compression and bending behavior, hardness, flammability, and surface morphology. In this way, a greater understanding of what the addition of fire retardants to polyurethane foams means for system flammability itself and, on the other hand, how this addition affects the mechanical properties of PUR may be investigated. It was obtained that retardants significantly increase the fire resistance of the PURs systems while they do not affect the thermal conductivity and only slightly decrease the mechanical properties of the systems. Therefore, the presented systems seem to be applicable as thermal insulation where low heat conductivity coupled with high flame resistance is required.
Ključne besede: flammability, polyurethane polymer, foams, thermal conductivity, mechanical properties, open access
Objavljeno v DiRROS: 08.06.2023; Ogledov: 308; Prenosov: 151
.pdf Celotno besedilo (10,71 MB)
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9.
Mechanical performance of timber connections made of thick flexible polyurethane adhesives
Jaka Gašper Pečnik, Igor Gavrić, Václav Sebera, Meta Kržan, Arkadiusz Kwiecień, BogusŁaw Zając, Boris Azinović, 2021, izvirni znanstveni članek

Povzetek: This study investigates timber connections with flexible polyurethane adhesives, which prove to have the po-tential for timber-adhesive composite structures without mechanical connections for seismic regions. Results of conducted cyclic double lap-shear adhesive timber joints tests were compared with available experimental re-sults on timber connections with standard mechanical dowel-type fasteners and with results of numerical finite element analysis. The study found that the shear strength, elastic stiffness and strength degradation capacity of the flexible adhesive connections were significantly higher compared to mechanical fasteners commonly used in seismic-resistant timber connections. The latter, however, manifested larger ultimate displacements but also yielded at lower displacements.
Ključne besede: flexible adhesive, timber connection, polyurethane, double lap-shear, cyclic loading, energy dissipation, open access
Objavljeno v DiRROS: 19.05.2023; Ogledov: 353; Prenosov: 227
.pdf Celotno besedilo (5,16 MB)
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10.
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